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Received February 19, 2014
Accepted August 4, 2014
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Periodic mesoporous organosilica (PMO) for catalytic applications
Department of Polymer Science and Engineering, Pusan National University, Busan 609-735, Korea
csha@pnu.edu
Korean Journal of Chemical Engineering, October 2014, 31(10), 1707-1719(13), 10.1007/s11814-014-0221-1
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Abstract
Surfactant-templated binuclear alkoxysilane precursors or cyclic silsesquioxane precursors have led to a new class of nanocomposites with bridging organic groups (R) inside the channel walls, known as periodic mesoporous organosilica (PMO). These PMO materials facilitate chemistry of the channels and provide new opportunities for controlling the chemical, physical, mechanical, and dielectric properties of the materials. This review provides an overview of recent papers on the synthesis of PMOs and their applications as catalysts published after the year 2000.
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