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Received February 7, 2014
Accepted May 13, 2014
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Catalytic conversion of cellulose into 5-hydroxymethylfurfural over chromium trichloride in ionic liquid
Beijing Key Laboratory of Membrane Science and Technology, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China
jdwang2013@163.com
Korean Journal of Chemical Engineering, October 2014, 31(10), 1786-1791(6), 10.1007/s11814-014-0138-8
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Abstract
An efficient method for converting cellulose into 5-hydroxymethylfurfural (5-HMF) using an inexpensive ionic liquid tetrabutylammonium chloride (TBAC) and relatively low-toxicity catalyst of chromium (III) trichloride (CrCl3·6H2O) was developed. The effects of hydrochloric acid loading, catalyst dosage, reaction temperature and time on the yield of 5-HMF were surveyed to achieve optimal reaction conditions. A 5-HMF yield of 43.7% was obtained within 90 min at 140 ℃using oil-bath heating. Glucose and starch were also investigated as feedstock to produce 5-_x000D_
HMF in TBAC/CrCl3·6H2O system, in which the 5-HMF yield was considerable. After 5-HMF was extracted, TBAC/CrCl3·6H2O could be used for several runs.
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