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Received October 2, 2013
Accepted May 21, 2014
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Role of copper pyrovanadate as heterogeneous photo-Fenton like catalyst for the degradation of neutral red and azure-B : An eco-friendly approach
Sangeeta Kalal
Narendra Pal Singh Chauhan1
Noopur Ameta
Rakshit Ameta2
Sudhish Kumar3
Pinki Bala Punjabi†
Photochemistry Laboratory, Department of Chemistry, M. L. Sukhadia University, Udaipur - 313001, Rajasthan, India 1Department of Chemistry, B. N. P. G. College, Udaipur - 313001, Rajasthan, India 2Department of Chemistry, Pacific College of Basic & Applied Sciences, PAHER University, Udaipur - 313024, Rajasthan, India 3Department of Physics, University College of Science, M. L. Sukhadia University, Udaipur - 313001, Rajasthan, India
Korean Journal of Chemical Engineering, December 2014, 31(12), 2183-2191(9), 10.1007/s11814-014-0142-z
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Abstract
The heterogeneous photo-Fenton like process is a green chemical pathway. It has an edge over conventional Fenton and photo-Fenton processes as it does not require the removal of ferrous/ferric ions in the form of sludge. We prepeared copper pyrovanadate or Volborthite (Cu3V2(OH)2O7·2H2O) composite photocatalyst by wet chemical method. The photocatalyst was characterized by SEM, XRD, IR, TGA/DSC, EDX and BET. Experiments demonstrated that catalyst could effectively catalyze degradation of neutral red and azure-B in presence of H2O2 in visible light. Moreover, the photo-Fenton-like catalytic activity of Cu3V2(OH)2O7·2H2O was much higher than CuO and V2O5, when used alone as photocatalyst. The effect of variation of different parameters, i.e., pH, amount of photocatalyst, concentration of dye, amount of H2O2 and light intensity was also investigated. The degradation was well fitted under pseudo-first-order reaction with a rate constant of 2.081×10^(-4) sec-1 and 3.876×10^(-4) sec-1 for neutral red and azure-B,_x000D_
respectively. Quality parameters of dye solutions before and after photo-Fenton degradation were also determined. A tentative mechanism involving ·OH radical as an oxidant has been proposed. The high catalytic activity may be due to the Cu3V2(OH)2O7·2H2O shell, which not only increased the surface hydroxyl groups, but also enhanced the interfacial electron transfer. The catalyst has been found to possess good recyclability.
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Zhu N, Gu L, Yuan H, Lou Z, Wang L, Zhang X, Water Res., 46, 3859 (2012)
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Pignatello J, Oliveros E, MacKay A, Crit. Rev. Environ. Sci. Technol., 36, 1 (2006)
Hong SH, Kwon BH, Lee JK, Kim IK, Korean J. Chem. Eng., 25(1), 46 (2008)
Vaishnave P, Kumar A, Ameta R, Punjabi PB, Ameta SC, Arab. J. Chem. In Press (2012)
Chen JX, Zhu LZ, Chemosphere, 65, 1249 (2006)
Molina CB, Casas JA, Zazo JA, Rodriguez JJ, Chem. Eng. J., 118(1-2), 29 (2006)
Parida KM, Pradhan AC, Ind. Eng. Chem. Res., 49(18), 8310 (2010)
Parra S, Nadtotechenko V, Albers P, Kiwi J, J. Phys. Chem. B, 108(14), 4439 (2004)
Chanderia K, Kumar S, Sharma J, Ameta R, Punjabi PB, Arab. J. Chem., In Press (2012)
Kumar BN, Anjaneyulu Y, Himabindu V, J. Chem. Pharm. Res., 3, 718 (2011)
Sharma J, Ameta R, Sharma VK, Punjabi PB, Bull. Catal. Soc. India, 9, 99 (2010)
Ameta N, Sharma J, Sharma S, Kumar S, Punjabi PB, Ind. J. Chem., 51, 943 (2012)
Iurascu B, Siminiceanu I, Vione D, Vicente MA, Gil A, Water Res., 43, 1313 (2009)
Mamedov EA, Corberan VC, Appl. Catal. A: Gen., 127(1-2), 1 (1995)
Magalhaes F, Pereira MC, Botrel SEC, Fabris JD, Macedo WA, Mendonca R, Lago RM, Oliveira LCA, Appl. Catal. A: Gen., 332(1), 115 (2007)
Zhang Y, Dou X, Liu H, Yang M, Zhang L, Kamagata Y, Catal. Today, 126(3-4), 387 (2007)
Costa RCC, Lelis MFF, Oliveira LCA, Fabris JD, Ardisson JD, Rios RRVA, Silva CN, Lago RM, J. Hazard. Mater., 129(1-3), 171 (2006)
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Yin CX, Finke RG, J. Am. Chem. Soc., 127(40), 13988 (2005)
Kasai J, Nakagawa Y, Uchida S, Yamaguchi K, Mizuno N, Chem. Eur. J., 12, 4176 (2006)
Khaliullin RZ, Bell AT, Head-Gordon M, J. Phys. Chem. B, 109(38), 17984 (2005)
Zavalij PY, Zhano F, Whitingham MS, Acta Cryst., 53, 1738 (1997)
Machida M, Miyazaki Y, Matsunaga Y, Ikeue K, Chem. Commun., 47, 9591 (2011)
Kaur P, Khant A, Khandelwal RC, Int. J. Chem. Sci., 9, 980 (2011)
Sharma D, Bansal A, Ameta R, Sharma HS, Int. J. Chem. Technol. Res., 3, 1008 (2011)
Pare B, Singh V, Jonnalagadda SB, Ind. J. Chem., 50, 1061 (2011)
Rosales E, Pazos M, Sanroman MA, Tavares T, Desalination, 284, 150 (2012)
Jhala Y, Chittora AK, Ameta KL, Punjabi PB, Int. J. Chem. Sci., 8, 1389 (2010)
Pare B, Singh P, Jonnalagadda SB, Indian J. Chem. Technol., 17(5), 391 (2010)
Ameta N, Kalal S, Ameta R, Chittora AK, Punjabi PB, Int. J. Chem., 1, 337 (2012)
Zhang T, Li CJ, Ma J, Tian H, Qiang ZM, Appl. Catal. B: Environ., 82(1-2), 131 (2008)
Xing S, Hu C, Qu J, He H, Yang M, Environ. Sci. Technol., 42, 3363 (2008)
Zeng YE, Zhang HS, Chen ZH, Handbook of Organic Reagents, Chemical Industry Press, Beijing, 4, 793 (1989)
Tuite E, Kelly JM, Biopolymers, 35, 419 (1995)
Kasprzyk-Hordern B, Ziolek M, Nawrocki J, Appl. Catal. B: Environ., 46(4), 639 (2003)
Lafontaine MA, Le Bail A, Ferey G, J. Solid State Chem., 85, 220 (1990)
Klauson D, Preis S, Portjanskaja E, Kachina A, Krichevskaya M, Kallas J, Environ. Technol., 26, 653 (2005)
Munoz MJL, Aguado J, Ruperez B, Res. Chem. Intermed., 33, 377 (2007)
He C, Ya X, Zhu XH, Li XZ, Appl. Catal. A: Gen., 275(1-2), 55 (2004)
