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Received October 19, 2013
Accepted June 2, 2014
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Adsorption of methyl orange using self-assembled porous microspheres of poly(o-chloroaniline)
Muhammad Naveed Anjum1 2
Khalid Mahmood Zia1
Lihua Zhu2
Haroon-ur-Rashid2 3
Mirza Nadeem Ahmad1
Mohammad Zuber1†
Heqing Tang4
1Institute of Chemistry, Government College University, Faisalabad 38030, Pakistan 2College of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. China 3Institute of Chemical Sciences, University of Peshawar, Peshawar, Pakistan 4Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission and Ministry of Education, College of Chemistry and Materials Science, South-Central University for Nationalities, Wuhan 430074, China
mohammadzuber@gmail.com
Korean Journal of Chemical Engineering, December 2014, 31(12), 2192-2197(6), 10.1007/s11814-014-0152-x
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Abstract
Self-assembled hollow microspheres poly(o-chloroaniline) (POC) have been synthesized by simple oxidative polymerization of o-chloroaniline using camphor-sulfonic acid (CSA) as dopant acid and ammonium persulfate (APS) as oxidant. The POC microspheres were characterized by means of FTIR, XRD and SEM analysis. Adsorption characteristics of POC spheres were studied by using methyl orange (MO) as adsorbate. It was found that adsorption of MO by POC was better described by pseudo-second-order kinetics than any other kinetic model, such as the pseudofirst-order and intra-particle diffusion models. Langmuir adsorption isotherm model was the best to fit experimental data. The results showed that hollow microspheres of POC can be used as novel and low-cost adsorbent for removal of organic dye from waste water.
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Virji S, Huang J, Kaner RB, BH, Nano Lett., 4, 491 (2004)
Lee BM, Kim JE, Fang FF, Choi HJ, Feller JF, Macromol. Chem. Phys., 212, 2300 (2011)
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Yang LL, Yang ZH, Cao WX, J. Colloid Interface Sci., 292(2), 503 (2005)
Hao L, Zhu C, Chen C, Kang P, Hu Y, Fan W, Chen Z, Synth. Met., 139, 391 (2003)
Zhang L, Peng H, Kilmartin PA, Soeller C, Tilley R, Travas-Seidic J, Macromol. Rapid Commun., 29(7), 598 (2008)
Han J, Song GP, Guo R, Adv. Mater., 18(23), 3140 (2006)
Zhang LJ, Wang M, Wei Y, Macromol. Rapid Commun., 27(11), 888 (2006)
Wei ZX, Wan MX, Adv. Mater., 14(18), 1314 (2002)
Zhang L, Peng H, Kilmartin PA, Soellar C, Travas-Sejdic J, J. Phys. Chem. C., 113, 9128 (2009)
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Vandevivere PC, Bianchi R, Verstraete W, J. Chem. Technol. Biotechnol., 72(4), 289 (1998)
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Luo W, Chen Z, Zhu L, Chen F, Wang L, Tang HQ, Anal. Chim. Acta, 588, 117 (2007)
Chiou MS, Chuang GS, Chemosphere, 62, 731 (2006)
Annadurai G, Chellapandian G, Krishnan MRV, Environ. Monit., 59, 111 (1999)
Annadurai G, Juang RS, Lee DJ, J. Hazard. Mater., 92(3), 263 (2002)
Singh KP, Mohan D, Sinha S, Tondon GS, Gosh D, Ind. Eng. Chem. Res., 42(9), 1965 (2003)
Sharma A, Bhattacharyya KG, Indian J. Chem. Technol., 12(3), 285 (2005)
Ayar A, Gezici O, Kucukosmanoglu M, J. Hazard. Mater., 147, 186 (2007)
Grag VK, Amita M, Kumar R, Gupta R, Dyes Pigm., 63, 243 (2004)
Gupta VK, Ali I, Suhas, Mohan D, J. Colloid Interface Sci., 265(2), 257 (2003)
Chowdhury AN, Jasmeen SR, Hosain MM, Polym. Adv. Technol., 15, 633 (2004)
Ayad MM, Ahmad AE, J. Phys. Chem. C., 114, 14377 (2010)
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Ai LH, Jiang J, Zhang R, Synth. Met., 160, 762 (2010)
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Anjum MN, PhD Thesis, Library, Huazhong University of Science and Technology, P. R. China (2012)
Majidi MR, Kane-Maguire LAP, Wallace GG, Polymer, 36, 3113 (1994)
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Chiang CJ, MacDiarmid AG, Synth. Met., 13, 193 (1986)
Sahin Y, Percin S, Sahin M, Ozkan G, J. App. Polym. Sci., 19, 2302 (2004)
Anjum MN, Zhu LH, Luo ZH, Yan JC, Tang HQ, Polymer, 52(25), 5795 (2011)
