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Received January 10, 2014
Accepted June 24, 2014
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Coffee waste as potential adsorbent for the removal of basic dyes from aqueous solution
Laboratory of Wastewater Treatment, CERTE, BP 273, Soliman 8020, Tunisia 1School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia
amor.hafiane@certe.rnrt.tn
Korean Journal of Chemical Engineering, December 2014, 31(12), 2198-2206(9), 10.1007/s11814-014-0171-7
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Abstract
We evaluated the adsorption performance of coffee waste (CW), collected from coffee shops, for the removal of two basic dyes, toluidine blue (TB) and crystal violet (CV), from aqueous solutions. Batch adsorption experiments were conducted under different conditions including contact time, initial concentration of dye, pH, sorbent dosage and temperature. The Langmuir, Freundlich, Temkin and Dubinin-Radushkevich (D-R) isotherms were tested to examine_x000D_
the adsorption behavior. The equilibrium data were well fitted by Langmuir isotherm model. The kinetic study indicates that adsorption follows the pseudo second-order model. The maximum adsorption capacity was found to be as high as 142.5 mg/g for TB and 125 mg/g for CV, which makes CW a prospective adsorbent for the removal of basic dyes from aqueous solution.
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References
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Sauer T, CesconetoNeto G, Jose HJ, Mureira RFPM, J. Photochem. Photobiol. A, 149, 147 (2002)
Jain AK, Gupta VK, Bhatnagar A, Suhas, Sep. Sci. Technol., 38(2), 463 (2003)
Reffas A, Bernardet V, David B, Reinert L, Lehocine MB, Dubois M, Batisse N, Duclaux L, J. Hazard. Mater., 175(1-3), 779 (2010)
Namane A, Mekarzia A, Benrachedi K, Belhaneche-Bensemra N, Hellal A, J. Hazard. Mater., 119(1-3), 189 (2005)
Crini G, Bioresour. Technol., 97(9), 1061 (2006)
Gupta VK, J. Environ. Manage., 90, 2313 (2009)
Mussatto SI, Machado EMS, Carneiro LM, Teixeira JA, Appl. Energy, 92, 763 (2012)
Oliveira LS, Franca AS, Camargos RRS, Ferraz VP, Bioresour. Technol., 99(8), 3244 (2008)
Azouaou N, Sadaoui Z, Djaafri A, Mokaddem H, J. Hazard. Mater., 184(1-3), 126 (2010)
Oliveira WE, Franca AS, Oliveira LS, Rocha SD, J. Hazard. Mater., 152(3), 1073 (2008)
Kyzas GZ, Lazaridis NK, Mitropoulos AC, Chem. Eng. J., 148, 189 (2012)
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Franca AS, Oliveira LS, Ferreira ME, Desalination, 249(1), 267 (2009)
Kyzas GZ, Materials, 5, 1826 (2012)
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Boehm HP, Adv. Catal., 16, 179 (1966)
Valdes H, Sanchez-Polo M, Rivera-Utrilla J, Zaror CA, Langmuir, 1, 2111 (2002)
Hameed BH, El-Khaiary MI, J. Hazard. Mater., 159(2-3), 574 (2008)
Hameed BH, J. Hazard. Mater., 161(2-3), 753 (2009)
Kumar R, Ahmad R, Desalination, 265(1-3), 112 (2011)
Jain S, Jayaram RV, Desalination, 250(3), 921 (2010)
Saeed A, Sharif M, Iqbal M, J. Hazard. Mater., 179(1-3), 564 (2010)
Cho SY, Park SS, Kim SJ, Kim TY, Korean J. Chem. Eng., 23(4), 638 (2006)
Aksu Z, Kabasakal E, Sep. Purif. Technol., 35(3), 223 (2004)
Cardoso LP, Valim JB, J. Phys. Chem. Solids, 67, 987 (2006)
Gonga R, Dingb Y, Lic M, Yanga C, Liua H, Suna Y, Dyes Pigm., 64, 187 (2005)
Sari A, Tuzen M, Soylak M, J. Hazard. Mater., 144(1-2), 41 (2007)
Langmuir I, J. Am. Chem. Soc., 38, 2221 (1916)
Hall KR, Eagleton LC, Acrivos A, Vermeulen T, Ind. Eng. Chem. Fundam., 5, 212 (1966)
Freundlich HMF, J. Phys. Chem., 57 (1906)
Temkin MJ, Pyzhev V, Acta Physiochem., USSR, 12, 217 (1940)
Dubinin MM, Radushkevich LV, Proc. Acad. Sci. U.S.S.R. Phys. Chem. Sect., 55, 331 (1947)
Nasuha N, Hameed BH, Din ATM, J. Hazard. Mater., 175(1-3), 126 (2010)
Uddin MT, Islam MA, Mahmud S, Rukanuzzaman M, J. Hazard. Mater., 164(1), 53 (2009)
Lagergren S, Sven K, Vetenskapsakad. Handl., 24, 1 (1898)
Ho YS, McKay G, Chem. Eng. J., 70(2), 115 (1998)
Azizian S, J. Colloid Interface Sci., 276(1), 47 (2004)
Siboni MH, Jafari SJ, Farrokhi M, Yang JK, Environ. Eng. Res., 18, 247 (2013)
Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
Iqbal M, Saeed A, Zafar SI, J. Hazard. Mater., 164(1), 161 (2009)
Gnanasambandam R, Protor A, Food Chem., 68, 327 (2000)
Kaikake K, Hoaki K, Sunada H, Dhakal RP, Baba Y, Bioresour. Technol., 98(15), 2787 (2007)
Ahmad R, Kumar R, J. Environ. Manage., 91, 1032 (2010)
