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Received January 15, 2014
Accepted June 27, 2014
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Adsorption of vanadium(V) from acidic solutions by using octylamine functionalized magnetite nanoparticles as a novel adsorbent
Mineral Processing Engineering Department, School of Mining Engineering, University College of Engineering, University of Tehran, Tehran, Iran 1NFCRS, Nuclear Science and Technology Research Institute, P. O. Box 11365-8486, Tehran, Iran
noparast@ut.ac.ir
Korean Journal of Chemical Engineering, December 2014, 31(12), 2237-2244(8), 10.1007/s11814-014-0179-z
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Abstract
Adsorption of vanadium(V) from acidic solutions was investigated by using octylamine functionalized magnetite nanoparticles as a novel adsorbent of vanadium. Batch experiments were conducted to determine the effects of initial pH, nanoparticles to octylamine weight ratio, amount of adsorbent, stirring time and initial vanadium(V) concentration in aqueous solution on adsorption efficiency. The adsorption was highly pH dependent, and the optimal pH was 3.2. The weight ratio of magnetite nanoparticles to octylamine was studied in optimum pH, and the best result was 3 : 2. More than 88% of vanadium(V) in solution was removed by 38.4 mg of adsorbent. In kinetics studies, the adsorption equilibrium could be achieved within 10 minutes, and the experimental data were well fitted by the pseudosecond-order model. Comparison of Langmuir and Freundlich isotherm models indicated a better fit of Langmuir model to the adsorption of vanadium(V) and the mono-layer adsorption capacity for vanadium(V) was 25.707 mg g-1.
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Shaibu BS, Reddy MLP, Bhattacharyya A, Manchanda VK, J. Magn. Magn. Mater., 301, 312 (2006)
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Nunez L, Kaminski MD, J. Magn. Magn. Mater., 194, 102 (1999)
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Zhao YB, Qiu ZM, Huang JY, Chin. J. Chem. Eng., 16(3), 451 (2008)
Cullity BD, Stock SR, Elements of X-ray diffraction, Prentice Hall, Upper Saddle River (2001)
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Stuart B, Infrared spectroscopy: Fundamentals and applications, John Wiley & Sons, Ltd. (2004)
Luo L, Miyazaki T, Shibayama A, Yen W, Fujita T, Miner. Eng., 16, 665 (2003)
Zeng L, Li Q, Xiao L, Zhang Q, Hydrometallurgy, 105, 176 (2010)
Olazabal MA, Orive MM, Fernandez LA, Madariaga JM, Solvent Extr. Ion Exch., 10(4), 623 (1992)
Tangri SK, Suri AK, Gupta CK, Transactions of the Indian Institute of Metals, 51(1), 27 (1998)
Laurent S, Forge D, Port M, Roch A, Robic C, Elst LV, Muller RN, Chem. Rev., 108(6), 2064 (2008)
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Ho YS, J. Hazard. Mater., 136(3), 681 (2006)
Liang S, Guo XY, Feng NC, Tian QH, J. Hazard. Mater., 174(1-3), 756 (2010)
