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- In relation to this article, we declare that there is no conflict of interest.
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Received March 12, 2014
Accepted May 21, 2014
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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One-pot synthesis of 5-hydroxymethylfurfural directly from cottonseed hull biomass using chromium (III) chloride in ionic liquid
Beijing Key Laboratory of Membrane Science and Technology, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Korean Journal of Chemical Engineering, December 2014, 31(12), 2286-2290(5), 10.1007/s11814-014-0143-y
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Abstract
We studied the direct synthesis of 5-hydroxymethylfurfural (5-HMF) from cottonseed hull biomass under acid condition in one-pot. The influence of HCl dosage, reaction temperature and time, CrCl3·6H2O amount, and cottonseed hull loading on the yield of 5-HMF was investigated. As a result, a 5-HMF yield up to 51% was obtained using 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) catalyzed with chromium (III) chloride at 130 ℃ for 2 h. The [Bmim]Cl/_x000D_
CrCl3·6H2O/HCl system was found to have high activity and selectivity for the dehydration of cellulose into 5-hydroxymethylfurfural. This work provides a low cost, environment-friendly and energy-efficient process to directly convert raw biomass into bio-fuels and chemicals.
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