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Received October 20, 2012
Accepted October 25, 2013
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Heterogeneous photocatalytic degradation of 4-chlorophenol by immobilization of cobalt tetrasulphophthalocyanine onto MCM-41
1Faculty of Fouman, College of Engineering, University of Tehran, P. O. Box 43515-1155, Fouman 43516-66456, Iran 2Department of Chemistry, Faculty of Science, University of Guilan, P. O. Box 1914, Rasht 41335, Iran
aebrahimian@ut.ac.ir
Korean Journal of Chemical Engineering, February 2014, 31(2), 218-223(6), 10.1007/s11814-013-0223-4
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Abstract
The photocatalytic activity of cobalt tetrasulphophthalocyanine immobilized onto MCM-41 was investigated for photocatalytic degradation of 4-chlorophenol (4-CP) in aqueous solutions. Immobilization of cobalt tetrasulphophthalocyanine complex to the walls of MCM-41 was performed by pre-anchorage of 3-(aminopropyl)-triethoxysilane (APTES) onto MCM-41 via post-synthesis method. X-ray diffraction, nitrogen physisorption, diffuse reflectance spectroscopy,_x000D_
energy-dispersive X-ray and FT-IR methods were used to characterize the product. Photocatalytic efficiency of the prepared photocatalyst for degradation of 4-CP was tested under illumination of UV-A and visible light. The reaction intermediates were identified by gas chromatography-mass spectrometry (GC-MS) technique.
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Bahnemann D, Cunningham J, Fox MA, Pelizzetti E, Pichat P, Serpone N, Aqua. Surf. Photochem., 261 (1994)
Sakthivel S, Kisch H, Chem. Phys. Chem., 4, 487 (2003)
Kisch H, Macyk W, Nachricht. Chem., 50, 1078 (2002)
Kisch H, Weiss H, Adv. Funct. Mater., 12(8), 483 (2002)
Kisch H, Macyk W, Chem. Phys. Chem., 3, 399 (2002)
Alvaro M, Carbonell E, Espla M, Garcia H, Appl. Catal. B: Environ., 57(1), 37 (2005)
Ozoemena K, Kuznetsova N, Nyokong T, J. Mol. Catal. A-Chem., 176(1-2), 29 (2001)
Sun L, Von Gersdorff J, Sobek J, Kurreck H, Tetrahedron, 51, 3535 (1995)
Harriman A, Energy Resour. Photochem. Catal., 163 (1983)
Czaplicka M, Science of the Total Environ., 322, 21 (2004)
Weber JH, Bush DH, Inorg. Chem., 4, 469 (1965)
Zanjanchi MA, Asgari S, Solid State Ion., 171(3-4), 277 (2004)
Moller K, Bein T, Chem. Mater., 10, 2950 (1998)
Pirouzmand M, Amini MM, Safari N, J. Colloid Interface Sci., 319(1), 199 (2008)
Ernst S, Selle M, Micropor. Mesopore. Mater, 27, 355 (1999)
Law KY, Chem. Rev., 93, 449 (1993)
Ozoemena K, Kuznetsova N, Nyokong T, J. Photochem. Photobiol. A, 39, 217 (2001)
Liu CJ, Li SG, Pang WQ, Che CM, Chem. Commun., 65 (1997)
Gao R, Stark J, Bahnemann DW, Rabani J, J. Photochem. Photobiol. A: Chem., 148, 387 (2002)
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Nash T, Biochem. J., 55, 416 (1953)
Chaliha S, Bhattacharyya KG, Catal. Today, 141, 225 (2009)
Chaliha S, Bhattacharyya KG, Paul P, Clean, 36, 448 (2008)
Bian WJ, Song XH, Liu DQ, Zhang J, Chen XH, J. Hazard. Mater., 192(3), 1330 (2011)
Wu L, Li AM, Gao GD, Fei ZH, Xu SR, Zhang QX, J. Mol. Catal. A-Chem., 269(1-2), 183 (2007)
Rao NN, Dubey AK, Mohanty S, Khare P, Jain R, Kau SN, J. Hazard. Mater., 101(3), 301 (2003)
Konstantinou IK, Sakkas VA, Albanis TA, Appl. Catal. B: Environ., 34(3), 227 (2001)
Serpone N, Lawless D, Terzian R, Meisel D, in: R. A. Mackay, J. Texter (Eds.), Electrochemistry in Colloids and Dispersions, VCH, New York, NY, 399 (1992)
