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Received September 10, 2013
Accepted October 11, 2013
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The influence of calcination temperature on catalytic activities in a Co based catalyst for CO2 dry reforming
Sang-Hoon Song1 2
Ju-Hee Son1 3
Anatta Wahyu Budiman1 3
Myoung-Jae Choi1
Tae-Sun Chang1†
Chae-Ho Shin2†
1Research Center for Environmental Resources & Processes, Korea Research Institute of Chemical Technology, Daejeon 305-600, Korea 2Department of Chemical Engineering, Chungbuk National University, Chungbuk 361-763, Korea 3Department of Green Chemistry and Environmental Biotechnology, University of Science and Technology, Daejoen 305-600, Korea
tschang@krict.re.kr
Korean Journal of Chemical Engineering, February 2014, 31(2), 224-229(6), 10.1007/s11814-013-0211-8
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Abstract
The carbon dioxide dry reforming of methane (CDR) reaction could be thermodynamically favored in the range of 800 to 1,000 ℃. However, the catalyst in this reaction should be avoided at the calcination temperature over 800 ℃ since strong metal support interaction (SMSI) in this temperature range can decrease activity due to loss of active sites. Therefore, we focused on optimizing the temperature of pretreatment and a comparison of surface characterization results for CDR. Results related to metal sintering over support, re-dispersion by changing of particle size of metal-support, and strong metal support interaction were observed and confirmed in this work. In our conclusion, optimum calcination temperature for a preparation of catalyst was proposed that 400 ℃ showed a higher and more stable catalytic activity without changing of support characteristics.
Keywords
References
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Ruckenstein E, Wang HY, Appl. Catal. A: Gen., 204(2), 257 (2000)
Ferreira-Aparicio P, Guerrero-Ruiz A, Rodriguez-Ramos I, Appl. Catal. A: Gen., 170(1), 177 (1998)
Song SH, Lee SB, Bae JW, Prasad PSS, Jun KW, Shul YG, Catal. Lett., 129(1-2), 233 (2009)
Wang SB, Lu GQ, Millar GJ, Energy Fuels, 10(4), 896 (1996)
Song SH, Lee SB, Bae JW, Sai Prasad PS, Jun KW, Catal. Commun., 9, 2282 (2008)
Fan MS, Abdullah AZ, Bhatia S, ChemCatChem, 1, 192 (2009)
Reuel RC, Bartholomew CH, J. Catal., 85, 63 (1984)
Kogelbauer A, Weber JC, Goodwin JG, Catal. Lett., 34(3-4), 259 (1995)
Jozwiak WK, Szubiakiewicz E, Goralski J, Klonkowski A, Paryjczak T, Kinet. Catal., 45, 247 (2004)
Vansteen E, Sewell GS, Makhothe RA, Micklethwaite C, Manstein H, Delange M, Oconnor CT, J. Catal., 162(2), 220 (1996)
Chin RL, Hercules DM, J. Phys. Chem., 86, 360 (1982)
Riva R, Miessner H, Vitali R, Del Piero G, Appl. Catal. A: Gen., 196(1), 111 (2000)
Lapidus A, Krylova A, Kazanskii V, Borovkov V, Zaitsev A, Rathousky J, Zukal A, Jancalkova M, Appl. Catal., 73, 65 (1991)
Lapidus A, Krylova A, Rathousky J, Zukal A, Jancalkova M, Appl. Catal., 80, 1 (1992)
Lira E, Lopez CM, Oropeza F, Bartolini M, Alvarez J, Goldwasser M, Linares FL, Lamonier JF, Zurita MJP, J. Mol. Catal. A-Chem., 281(1-2), 146 (2008)
Jablonski JM, Okal J, Potoczna-Petru D, Krajczyk L, J. Catal., 220(1), 146 (2003)
Ernst B, Bensaddik A, Hilaire L, Chaumette P, Kiennemann A, Catal. Today, 39(4), 329 (1998)
Potoczna-Petru D, Jablonski JM, Okal J, Krajczyk L, Appl. Catal. A: Gen., 175(1-2), 113 (1998)
Petitto SC, Langell MA, J. Vac. Sci. Technol. A, 22(4), 1690 (2004)
Bradford MC, Vannice MA, Appl. Catal. A: Gen., 142(1), 73 (1996)
Cotton FA, Wilkinson G, Advanced Inorganic Chemistry, Fifth Ed., A Wiley-Interscience, New York (1988)
Budiman AW, Song SH, Chang TS, Shin CH, Choi MJ, Catal. Surv. Asia, 16, 183 (2012)
