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Received July 9, 2013
Accepted October 11, 2013
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Effect of pH, ionic strength, foreign ions, humic acid and temperature on Zn(II) sorption onto γ-Al2O3
Department of Chemistry, Qinghai Normal University, Xining, Qinghai 810008, P. R. China 1Education Training Center, Ningxia Electric Power Company, Yinchuan, Ningxia 750011, P. R. China
Korean Journal of Chemical Engineering, February 2014, 31(2), 253-261(9), 10.1007/s11814-013-0207-4
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Abstract
The sorption of Zn(II) on γ-alumina was investigated as a function of contact time, pH, ionic strength, foreign ions, solid amount, humic acid (HA) and temperature by using batch technique. The results indicated that the sorption of Zn(II) onto γ-alumina was strongly dependent on pH and ionic strength. The sorption of Zn(II) increased slowly with increasing pH at pH 2-5, then increased sharply with pH increasing from 5 to 8.5, and at last maintained a maximum value at pH>8.5. A positive effect of HA on Zn(II) sorption was found at pH<7, whereas a negative effect_x000D_
was observed at pH>7. The thermodynamic data (ΔG°, ΔS°, ΔH°) were calculated from the temperature-dependent sorption isotherms, and the results suggested that the sorption of Zn(II) on γ-alumina was endothermic and spontaneous. The sorption results revealed that the γ-alumina can be as a cost-effective sorbent for pre-concentration of Zn(II) from large volumes of aqueous solutions in environmental pollution cleanup.
Keywords
References
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Tan X, Wang X, Chen C, Sun A, Appl. Radiat. Isot., 65, 375 (2007)
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Zhang Y, Li Y, Zheng X, Sci. Total Environ., 409, 625 (2011)
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Xu D, Chen C, Tan X, Hu J, Wang X, Appl. Geochem., 22, 2892 (2007)
Sheng G, Yang S, Sheng J, Hu J, Tan X, Wang X, Environ. Sci. Technol., 45, 7718 (2011)
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Al-Qunaibit MH, Mekhemer WK, Zaghloul AA, J. Colloid Interface Sci., 283(2), 316 (2005)
Ho Y, Wase D, Forster C, Environ. Technol., 17, 71 (1996)
Mckay G, Poots V, J. Chem. Technol. Biotechnol., 30, 279 (1980)
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Yang ST, Sheng GD, Montavon G, Guo ZQ, Tan XL, Grambow B, Wang XK, Geochim. Cosmochim. Acta, 121, 84 (2013)
Yang S, Hu J, Chen C, Shao D, Wang X, Environ. Sci. Technol., 45, 3621 (2011)
Sheng GD, Yang ST, Sheng J, Zhao DL, Wang XK, Chem. Eng. J., 168(1), 178 (2011)
Sheng G, Sheng J, Yang S, Hu J, Wang X, J. Radioanal. Nucl. Chem., 289, 129 (2011)
Sun Y, Shao D, Chen C, Yang S, Wang X, Environm. Sci Technol., 47, 9904 (2013)
Partey F, Norman D, Ndur S, Nartey R, J. Colloid Interface Sci., 321(2), 493 (2008)
Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
Tan X, Chen CL, Yu SM, Wang X, Appl. Geochem., 23, 2767 (2008)
Tan X, Wang X, Fang M, Chen C, Colloid Surf. A, 296, 109 (2007)
Sheng G, Hu J, Jin H, Yang S, Ren X, Li J, Chen Y, Wang X, Radiochim. Acta, 98, 291 (2010)
Zhao GX, Jiang L, He YD, Li JX, Dong HL, Wang XK, Hu WP, Adv. Mater., 23(34), 3959 (2011)
Wu X, Wang L, Chen C, Xu A, Wang X, J. Mater. Chem., 21, 17353 (2011)
Hu J, Shao DD, Chen CL, Sheng GD, Li JX, Wang XK, Nagatsu M, J. Phys. Chem. B, 114(20), 6779 (2010)