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Received August 13, 2013
Accepted October 11, 2013
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A new electrode reactor with in-built recirculation mode for the enhancement of methylene blue dye removal from the aqueous solution: Comparison of adsorption, electrolysis and combined effect
Ponnusamy Senthil Kumar†
Maria Jacob Stani Raja
Mahathevan Kumaresan
Dinesh Kumar Loganathan
Prabhakaran Chandrasekaran
Department of Chemical Engineering, SSN College of Engineering, Chennai 603 110, India
senthilchem8582@gmail.com
Korean Journal of Chemical Engineering, February 2014, 31(2), 276-283(8), 10.1007/s11814-013-0209-2
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Abstract
The removal of basic dye such as methylene blue (MB) dye from the synthetic wastewater was experimentally investigated using an electrolytic cell (EC), adsorption and the combined effect of EC and adsorption technology called a three-phase three-dimensional electrode reactor(TPTDER). The performance of the each technology was checked on the basis of the efficiency of the systems. The experimental results are expressed in terms of the removal efficiency of the dye molecules. The results show that the TPTDER could efficiently remove the dye molecules from the aqueous solutions when compared with the EC and adsorption process. The removal efficiency reached as high as about 99% for an initial MB dye concentration in the range of 100-1,000 mg/L by TPTDER for 10 min at 12 V cell voltage and at specific airflow conditions. It was also observed that the removal of dye molecules depends upon the initial solution pH, applied cell voltage, contact time, and initial dye concentration. The recyclability of the particle electrodes in the TPTDER process was also checked. These findings suggest that TPTDER is a promising technology for the removal of dyes from the aqueous solution, and can be applied to the removal of dyes from the industrial effluents.
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References
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Kumar PS, Ramalingam S, Sathishkumar K, Korean J. Chem. Eng., 28(1), 149 (2011)
Senthamarai C, Kumar PS, Priyadharshini M, Vijayalakshmi P, Kumar VV, Baskaralingam P, Thiruvenkadaravi KV, Sivanesan S, Environ. Prog. Sustain. Energy, DOI:10.1002/ep (2012)
Kumar PS, Palaniyappan M, Priyadharshini M, Vignesh AM, Thanjiappan A, Fernando PSA, Ahmed RT, Srinath R, Environ. Prog. Sustain. Energy, DOI:10.1002/ep (2013)
Kumar PS, Sivaranjanee R, Vinothini U, Raghavi M, Rajasekar K, Ramakrishnan K, Desalin. Water Treat., DOI: 10.1080/19443994.2013.792016 (2013)
Ertas M, Acemioglu B, Alma MH, Usta M, J. Hazard. Mater., 183(1-3), 421 (2010)
Xu L, Zhao H, Shi S, Zhang G, Ni J, Dyes Pigm., 77, 158 (2008)
Coughlin MF, Kinkle BK, Bishop PL, Chemosphere, 46, 11 (2002)
Wu TX, Lin T, Zhao JC, Hidaka H, Serpone N, Environ. Sci. Technol., 33, 1379 (1999)
Ghoreishi SM, Haghighi R, Chem. Eng. J., 95(1-3), 163 (2003)
Shu HY, Huang CR, Chang MC, Chemosphere, 29, 2597 (1994)
Xiong Y, He C, An T, Zhu XH, Karlsson HT, Water Air Soil Pollut., 144, 67 (2003)
Chu W, Ma CW, Water Res., 34, 3153 (2000)
Chiang LC, Change JE, Tseng SC, Water Sci. Technol., 36, 123 (1997)
Fockedy E, Lierde AV, Water Res., 36, 4169 (2002)
Brown CJ, Pletcher D, Walsh FC, Hammond JK, Robinson D, J. Appl. Electrochem., 24(2), 95 (1994)
Rajeshwar K, Ibanez JG, Swain GM, J. Appl. Electrochem., 24(11), 1077 (1994)
Tissot P, Fragniere M, J. Appl. Electrochem., 24(6), 509 (1994)
Bockris JO, Kim J, J. Appl. Electrochem., 27(8), 890 (1997)
Pasquini F, Tissot P, J. Appl. Electrochem., 26(2), 211 (1996)
Scott LL, Winnick J, Kohl PA, Bottomley LA, J. Electrochem. Soc., 145(12), 4062 (1998)
Dieckmann GR, Langer SH, J. Appl. Electrochem., 27(1), 1 (1997)
Xiong Y, Karlsson HT, Adv. Environ. Res., 7, 139 (2002)
El-Ghaoui EA, Jansson REW, Moreland C, J. Appl. Electrochem., 12, 69 (1982)
Xiong Y, He C, An T, Karlsson HT, Zhu XH, Chemosphere, 50, 131 (2003)
Polcaro AM, Palmas S, Renoldi F, Mascia M, Electrochim. Acta, 46(2-3), 389 (2000)
Tennakoon CL, Bhardwaj RC, Bockris JO, J. Appl. Electrochem., 26(1), 18 (1996)
An TC, Zhu XH, Xiong Y, Chemosphere, 46, 897 (2002)
Boye B, Dieng MM, Brillas E, Environ. Sci. Technol., 36, 3030 (2002)
Oturan MA, Peiroten J, Chartrin P, Acher AJ, Environ. Sci. Technol., 34, 3474 (2000)
Neyens E, Baeyens J, J. Hazard. Mater., 98(1-3), 33 (2003)
Brillas E, Boye B, Sires I, Garrido JA, Rodriguez RM, Arias C, Cabot PL, Comninellis C, Electrochim. Acta, 49(25), 4487 (2004)
Lagergren S, Kungliga Svenska Vetensk Handl., 24, 1 (1898)
Ho YS, McKay G, Proc. Biochem., 34, 451 (1999)
Weber WJ, Morris JC, J. Sanit. Eng. Div. Am. Soc. Civ. Eng., 89, 31 (1963)
