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Received April 19, 2013
Accepted October 27, 2013
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Synthesis of polymer membranes of different porosity and their application for phenol removal from liquid phase
Faculty of Chemistry, Adam Mickiewicz University in Poznan, Umultowska 89b, 61-614 Pozna , Poland
pietrob@amu.edu.pl
Korean Journal of Chemical Engineering, February 2014, 31(2), 304-309(6), 10.1007/s11814-013-0227-0
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Abstract
Preparation of polymeric membranes based on polyethersulfone (PES) modified by adding different amounts of a pore-forming agent (PVP) is presented, and potential application of the membranes obtained for removal of phenol from the liquid phase is examined. The addition of various amounts of PVP has been shown to bring about changes in the content of the surface oxygen groups, but has no significant effect on the chemical character of the groups and acidic groups dominate. Filtration by phenol solution leads to significant changes in the total content of surface oxides; however, the acidic groups remain dominant. Membranes characterized by higher porosity exhibited more stable and higher rejection ratio for phenol removal. Although all the membranes were characterized by similar rejection ratios for phenol removal, the cake resistance (Rc) and pore resistance (Rp) values were found to depend significantly on the structure and porosity of the membrane applied for filtration.
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