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Received August 9, 2013
Accepted October 27, 2013
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Direct synthesis of bi-modal porous structure MCM-41 and its application in CO2 capturing through amine-grafting
Department of Chemical Engineering, College of Engineering, University of Isfahan, P. O. Box 81746-73441, Isfahan, Iran
Korean Journal of Chemical Engineering, February 2014, 31(2), 322-326(5), 10.1007/s11814-013-0230-5
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Abstract
A bi-modal porous structure MCM-41 (BPS-MCM-41) was synthesized and functionalized by 3-[2-(2-Aminoethylamino)ethylamino]propyltrimethoxysilane (TRI); also, its performance in amine grafting and CO2 capturing was compared with that of pore-expanded MCM-41 [1]. To create larger pores beside the mesoporous structure of MCM-41, carbon black nanoparticles were used as the solid template. Characterizing the BPS-MCM-41 using the BET and BJH techniques resulted in the surface reduction of 29.3 percent and volume increase of 68.46 percent. The pore size distribution showed two peaks: a narrow peak at 2.24 nm diameter, which belonged to micelles, and a wide one at about 50 nm due to the presence of used nanoparticles. The functionalization confirmed that BPS-MCM-41 is capable of accommodating a large quantity of amine groups. The CO2 adsorption measurement indicated that internal volume of the adsorbent was a critical factor affecting the adsorption capacity of the amine grafted adsorbents.
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Konduru N, Lindner P, Assaf-Anad NM, AIChE J., 53(12), 3137 (2007)
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Wang Y, LeVan MD, J. Chem. Eng. Data, 55, 3189 (2009)
Li G, Xiao P, Webley PA, Zhang J, Singh R, Energy Procedia, 1, 1123 (2009)
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Tlili N, Grevillot G, Vallieres C, Int. J. Greenhouse Gas Control, 3, 519 (2009)
Wang Y, Levan MD, J. Chem. Eng. Data, 55(9), 3189 (2010)
Hogendoorn JA, Vanswaaij WP, Versteeg GF, Chem. Eng. Sci., 49(20), 3421 (1994)
Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu CTW, Olson DH, Sheppard EW, J. Am. Chem. Soc., 114, 10834 (1992)
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Loganathan S, Tikmani M, Ghoshal AK, Langmuir, 29(10), 3491 (2013)
Jana S, Mochizuki A, Namba S, Catal. Surv. Asia, 8, 1 (2004)
Hornacek M, Hudec P, Smieskova A, Chem. Pap., 63, 689 (2009)
Kierys A, Buda W, Goworek J, J. Porous Mater., 17, 669 (2010)
Mizutani M, Yamada Y, Yano K, Chem. Commun., 1172 (2007)
Stein A, Micropor. Mesopor. Mater., 44-45, 227 (2001)
Danumah C, Vaudreuil S, Bonneviot L, Bousmina M, Giasson S, Kaliaguine S, Micropor. Mesopor. Mater., 44-45, 241 (2001)
Chen C, Yang ST, Ahn WS, Ryoo R, Chem. Commun., 3627 (2009)
Du J, Lai X, Yang N, Zhai J, Kisailus D, Su F, Wang D, Jiang L, ACS Nano, 5, 590 (2011)
Yang XY, Li Y, Lemaire A, Yu JG, Su BL, Pure Appl. Chem., 81, 2265 (2009)
Lei Q, Zhao T, Li F, Wang Y, Hou L, J. Porous Mater., 15, 643 (2008)
Franchi RS, Harlick PJE, Sayari A, Ind. Eng. Chem. Res., 44(21), 8007 (2005)
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Franchi R, Harlick PJE, Sayari A, Abdelhamid S, Mietek J, in “Studies in Surface Science and Catalysis”, Elsevier, 156, 879 (2005)
Serna-Guerrero R, Belmabkhout Y, Sayari A, Chem. Eng. Sci., 65(14), 4166 (2010)
Heydari-Gorji A, Belmabkhout Y, Sayari A, Langmuir, 27, 124111 (2010)
Serna-Guerrero R, Belmabkhout Y, Sayari A, Adsorption, 16, 567 (2010)
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Vartuli JC, Roth WJ, Beck JS, McCullen SB, Kresge CT, in “Synthesis”, Springer Berlin Heidelberg, 1, 97 (1998)
Wang Y, Levan MD, J. Chem. Eng. Data, 54(10), 2839 (2009)
