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Received August 7, 2013
Accepted November 19, 2013
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Poly(ethyleneimine) functionalized organic-inorganic hybrid silica by hydrothermalassisted surface grafting method for removal of nickel(II)
College of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, China
lnkdxhb@163.com
Korean Journal of Chemical Engineering, February 2014, 31(2), 343-349(7), 10.1007/s11814-013-0244-z
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Abstract
Poly(ethyleneimine)-functionalized organic-inorganic hybrid silica adsorbent was synthesized by hydrothermal-assisted surface grafting technique for the removal of Ni(II) ions from aqueous solution, and was characterized by FT-IR, nitrogen adsorption and the static adsorption-desorption experiment method. The results indicated that the maximum static adsorption capacity of Ni(II) on poly(ethyleneimine)-functionalized hybrid silica adsorbent by hydrothermal heating method was 1.6 times as much as the conventional heating method. The poly(ethyleneimine)-_x000D_
functionalized hybrid silica adsorbent offered a fast kinetics for the adsorption of Ni(II), had a substantial binding capacity in the range of pH 4-8 and could be used repeatedly. The Langmuir adsorption model was more favorable than the Freundlich and Dubinin-Radushkevich adsorption models. The adsorption followed a pseudo-second-order model compared with pseudo-first-order model. Various thermodynamic parameters such as ΔG°, ΔH° and ΔS° indicated that the adsorption process was spontaneous and endothermic. The results showed that poly(ethyleneimine)-functionalized hybrid silica adsorbent could be employed as an effective material for the removal of Ni(II) ions from aqueous solution.
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Rengaraj S, Yeon KH, Moon SH, J. Radioanal. Nucl. Chem., 253, 241 (2002)
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Njau KN, Janssen LJ, J. Appl. Electrochem., 25(10), 982 (1995)
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Kandah MI, Meunier JL, J. Hazard. Mater., 146(1-2), 283 (2007)
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Hoffmann F, Cornelius M, Morell J, Froba M, Angew. Chem. Int. Ed., 45, 3216 (2006)
Jal PK, Patel S, Mishra BK, Talanta, 62, 1005 (2004)
Kislenko VN, Oliynyk LP, J. Polym. Sci. A: Polym. Chem., 40(7), 914 (2002)
Say R, Tuncel A, Denizli A, J. Appl. Polym. Sci., 83(11), 2467 (2002)
Deng S, Ting YP, Water Res., 39, 2167 (2005)
Byrappa K, Adschiri T, Prog. Cryst. Growth Charact. Mater., 53, 117 (2007)
Hayashi H, Hakuta Y, Materials, 3, 3794 (2010)
Gao B, Jiang P, Lei H, Mater. Lett., 60, 3398 (2006)
Sela M, Berger A, J. Am. Chem. Soc., 77, 1893 (1955)
Peters MA, Belu AM, Linton RW, Dupray L, Meyer TJ, Desimone JM, J. Am. Chem. Soc., 117(12), 3380 (1995)
Gao B, Wang X, Shen Y, Biochem. Eng. J., 28, 140 (2006)
Hannachi Y, Shapovalov NA, Hannachi A, Korean J. Chem. Eng., 27(1), 152 (2010)
Kwak IS, Won SW, Choi SB, Mao J, Kim S, Chung BW, Yun YS, Korean J. Chem. Eng., 28(3), 927 (2011)
Bhatnagara A, Minocha AK, Colloids Surf. B, 76, 544 (2010)
Satapathy D, Natarajan GS, Adsorption, 12, 147 (2006)
Ho YS, McKay G, Adsorption, 5, 409 (1999)
Rao PS, Reddy KVNS, Kalyani S, Krishnaiah A, Wood Sci. Technol., 41, 427 (2007)
Lagergren S, Kungliga Svenska Vetensk. Handl., 24, 1 (1898)
Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
Mobasherpour I, Salahi E, Ebrahimi M, Res. Chem. Intermed., 38, 2205 (2012)
Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
Freundlich HMF, Z. Phys. Chem., 57, 385 (1906)
Hobson JP, J. Phys. Chem., 73, 2720 (1969)
Foo KY, Hameed BH, Chem. Eng. J., 156(1), 2 (2010)
Weber WJ, Morris JC, J. Sanit. Eng. Div. Am. Soc. Civ. Eng., 89, 31 (1963)
Allen SJ, McKay G, Khader KYH, Environ. Pollut., 56, 39 (1989)
Lisha KP, Maliyekkal SM, Pradeep T, Chem. Eng. J., 160(2), 432 (2010)
Fan HT, Wu JB, Fan XL, Zhang DS, Su ZJ, Yan F, Sun T, Chem. Eng. J., 198-199, 355 (2012)
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Fan HT, Su ZJ, Fan XL, Guo MM, Wang J, Gao S, Sun T, J. Sol-Gel Sci. Technol., 64, 418 (2012)
