Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received August 27, 2013
Accepted November 21, 2013
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Spectroscopic study on the intermolecular interaction of SO2 absorption in poly-ethylene glycol+H2O systems
College of Chemical Engineering, Inner Mongolia University of Technology, Huhhot 010051, China
liujr@imut.edu.cn
Korean Journal of Chemical Engineering, March 2014, 31(3), 514-521(8), 10.1007/s11814-013-0249-7
Download PDF
Abstract
Poly-Ethylene Glycol (PEG) 300+H2O solutions (PEGWs) has been used as a promising medium for the absorption of SO2. We investigated the UV, FTIR, 1H-NMR, and fluorescence spectra in the absorption processes of SO2 in PEGWs to present an important absorption mechanism. Based on the spectral results, the possibility of intermolecular hydrogen bond formation by hydroxyl oxygen atom in the PEG molecule with hydrogen atom in H2O and S…O interaction formation by the oxygen atoms in PEG with the sulfur atom in SO2 are discussed. This shows that the spectral changes may be due to the formation of -CH2CH2O(H)…HOH… and -CH2-CH2-O(CH2-CH2-)…HOH… in PEGWs and the formation of -CH2CH2OH…OSO…, and intermolecular S…O interaction between PEG and SO2 as the formation of -CH2CH2OCH2CH2O(H)…(O)S(O)… and -CH2-CH2-O(CH2-CH2-)…(O)S(O)…. The existence of these bonds benefits the absorption and desorption processes of SO2 in PEGWs.
References
Jin MJ, Hou YC, Wu WZ, Ren SH, Tian SD, Xiao L, Lei ZG, J. Phys. Chem. B, 115(20), 6585 (2011)
Srivastava RK, Jozewicz W, Singer C, Environ. Prog., 20, 219 (2001)
Werther J, J. Hazard. Mater., 144(3), 604 (2007)
Dahlan I, Lee KT, Kamaruddin AH, Mohamed AR, Environ. Sci. Technol., 40, 6032 (2006)
Wang CM, Cui GK, Luo XY, Xu YJ, Li HR, Dai S, J. Am. Chem. Soc., 133(31), 11916 (2011)
Sun ZG, Zhao Y, Gao HY, Hu GX, Energy Fuels, 24, 1013 (2010)
Maneeintr K, Idem RO, Tontiwachwuthikul P, Wee AGH, Energy Procedia, 1, 1327 (2009)
C. N. Schubert, W. I. Echter, The method of polymer ethylene glycol for removal of pollution from gases, CN. Patent 1364096A (2002)
Wei XH, Zhang JB, Zhang PY, Zhang LW, Li XB, Wan MJ, Removal of SOx from flue gas by ethylene glycol, CN. Patent 101053746 (2007)
Wei XH, Desulfurization & decarburization solution activities, CN. Patent 02130605 (2002)
Zhang JB, Zhang PY, Chen GH, Han F, Wei XH, J. Chem. Eng. Data, 53(7), 1479 (2008)
Zhang JB, Zhang PY, Han F, Chen GH, Zhang LW, Wei XH, Ind. Eng. Chem. Res., 48(3), 1287 (2009)
Zhang JB, Han F, Zhang PY, Chen GH, Wei XH, J. Chem. Eng. Data, 55(2), 959 (2010)
Zhang JB, Chen GH, Zhang PY, Han F, Wang JF, Wei XH, J. Chem. Eng. Data, 55, 1446 (2010)
Zhang JB, Han F, Wei XH, Shui LK, Gong H, Zhang PY, Ind. Eng. Chem. Res., 49, 2025 (2010)
Zhang JB, Xiao JB, Liu YX, Wei XH, J. Chem. Eng. Data, 55(11), 5350 (2010)
Zhang JB, Li QA, Guo ZH, Li KX, Xu MD, Zhang N, Zhang T, Wei XH, Ind. Eng. Chem. Res., 50(2), 674 (2011)
Zhang JB, Liu LH, Huo TR, Liu ZY, Zhang T, Wei XH, J. Chem. Thermodyn., 43(10), 1463 (2011)
Zhang N, Zhang JB, Zhang YF, Bai J, Huo TR, Wei XH, Fluid Phase Equilib., 313, 7 (2012)
Zhang N, Zhang JB, Zhang YF, Fluid Phase Equilib., 348, 9 (2013)
Ivopoulos P, Sotiropoulou M, Bokias G, Staikos G, Langmuir, 22(22), 9181 (2006)
Schofield DP, Lane JR, Kjaergaard HG, J. Phys. Chem. A, 111(4), 567 (2007)
Lasgabaster A, Abad MJ, Barral L, Ares A, Eur. Polym. J., 42, 3121 (2006)
Dharmalingam K, Ramachandran KP, Physica. B, 4, 1 (2006)
Palombo F, Paolantoni M, Sassi P, Morresi A, Cataliotti RS, J. Mol. Liq., 125, 139 (2006)
Yuan B, Dou XM, Spectrosc Spect. Anal. (In Chinese), 11, 1319 (2004)
Wang W, Jin Y, Su ZH, J. Phys. Chem. B, 113(48), 15742 (2009)
Srivastava RK, Jozewicz W, Singer C, Environ. Prog., 20, 219 (2001)
Werther J, J. Hazard. Mater., 144(3), 604 (2007)
Dahlan I, Lee KT, Kamaruddin AH, Mohamed AR, Environ. Sci. Technol., 40, 6032 (2006)
Wang CM, Cui GK, Luo XY, Xu YJ, Li HR, Dai S, J. Am. Chem. Soc., 133(31), 11916 (2011)
Sun ZG, Zhao Y, Gao HY, Hu GX, Energy Fuels, 24, 1013 (2010)
Maneeintr K, Idem RO, Tontiwachwuthikul P, Wee AGH, Energy Procedia, 1, 1327 (2009)
C. N. Schubert, W. I. Echter, The method of polymer ethylene glycol for removal of pollution from gases, CN. Patent 1364096A (2002)
Wei XH, Zhang JB, Zhang PY, Zhang LW, Li XB, Wan MJ, Removal of SOx from flue gas by ethylene glycol, CN. Patent 101053746 (2007)
Wei XH, Desulfurization & decarburization solution activities, CN. Patent 02130605 (2002)
Zhang JB, Zhang PY, Chen GH, Han F, Wei XH, J. Chem. Eng. Data, 53(7), 1479 (2008)
Zhang JB, Zhang PY, Han F, Chen GH, Zhang LW, Wei XH, Ind. Eng. Chem. Res., 48(3), 1287 (2009)
Zhang JB, Han F, Zhang PY, Chen GH, Wei XH, J. Chem. Eng. Data, 55(2), 959 (2010)
Zhang JB, Chen GH, Zhang PY, Han F, Wang JF, Wei XH, J. Chem. Eng. Data, 55, 1446 (2010)
Zhang JB, Han F, Wei XH, Shui LK, Gong H, Zhang PY, Ind. Eng. Chem. Res., 49, 2025 (2010)
Zhang JB, Xiao JB, Liu YX, Wei XH, J. Chem. Eng. Data, 55(11), 5350 (2010)
Zhang JB, Li QA, Guo ZH, Li KX, Xu MD, Zhang N, Zhang T, Wei XH, Ind. Eng. Chem. Res., 50(2), 674 (2011)
Zhang JB, Liu LH, Huo TR, Liu ZY, Zhang T, Wei XH, J. Chem. Thermodyn., 43(10), 1463 (2011)
Zhang N, Zhang JB, Zhang YF, Bai J, Huo TR, Wei XH, Fluid Phase Equilib., 313, 7 (2012)
Zhang N, Zhang JB, Zhang YF, Fluid Phase Equilib., 348, 9 (2013)
Ivopoulos P, Sotiropoulou M, Bokias G, Staikos G, Langmuir, 22(22), 9181 (2006)
Schofield DP, Lane JR, Kjaergaard HG, J. Phys. Chem. A, 111(4), 567 (2007)
Lasgabaster A, Abad MJ, Barral L, Ares A, Eur. Polym. J., 42, 3121 (2006)
Dharmalingam K, Ramachandran KP, Physica. B, 4, 1 (2006)
Palombo F, Paolantoni M, Sassi P, Morresi A, Cataliotti RS, J. Mol. Liq., 125, 139 (2006)
Yuan B, Dou XM, Spectrosc Spect. Anal. (In Chinese), 11, 1319 (2004)
Wang W, Jin Y, Su ZH, J. Phys. Chem. B, 113(48), 15742 (2009)
