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Received September 9, 2013
Accepted November 6, 2013
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Volumetric, ultrasonic and viscometric studies of binary liquid mixures of N-ethylaniline + chlorobenzene, + Bromobeneze, + 1, 2-dichlorobenzene +1, 3-dichlorobenzene+1, 2, 4-trichlorobenzene at 303.15 and 308.15K
Department of Chemistry, Acharya Nagarjuna University, Guntur-522510, AP, India 1Department of Chemistry, J.K.C. College, Guntur-522006, AP, India
rbchintala@gmail.com
Korean Journal of Chemical Engineering, May 2014, 31(5), 881-895(15), 10.1007/s11814-013-0235-0
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Abstract
We measured densities (ρ), ultrasonic speeds (u) and viscosities (η) for binary binary mixtures of N-ethylaniline (N-EA) with chlorobenzene (CB), bromobenzene (BB), 1,2-dichlorobenzene (1,2-DCB), 1,3-dichlorobenzene (1,3-DCB), and 1,2,4-trichlorobenzene (1,2,4-TCB) and their pure liquids at 303.15 K and 308.15 K. These experimental data were used to calculate the excess volume (VE), deviations in ultrasonic speeds (Δu), deviation in isentropic compressibility_x000D_
(Δκs), deviation in intermolecular free length (ΔLf), deviation in acoustic impedance (ΔZ), deviation in viscosity (Δη) and excess Gibbs free energy of activation of viscous flow (G*E). The variations of these properties with composition of binary mixtures suggest loss of dipolar association, difference in size and shape of the component molecules, dipole-dipole interactions and hydrogen bonding between unlike molecules. The viscosity data were correlated with_x000D_
Grunberg and Nissan, Katti and Chaudhri, and Hind et al. equations and the results were compared with the experimental results. The excess parameters were fitted to the Redlich-Kister polynomial equation using multi parametric nonlinear regression analysis to derive the binary coefficients and to estimate the standard deviation.
References
Gowrisankar M, Venkateswarlu P, Kumar KS, Sivarambabu S, J. Mol. Liq., 173, 172 (2012)
Gowrisankar M, Venkateswarlu P, Kumar KS, Sivarambabu S, J. Soln., Chem., 42(5), 916 (2013)
Manukonda G, Ponneri V, Kasibhatta S, Sakamuri S, Korean J. Chem. Eng., 30(5), 1131 (2013)
Gowrisankar M, Venkateswarlu P, Kumar KS, Sivarambabu S, J. Therm. Anal. Calorim., DOI:10.1007/s10973-013-3312z (2013)
Syamala V, Prabhakar G, Sivakumar K, Venkateswarlu P, Phys. Chem. Liq., 44, 127 (2006)
Syamala V, Kumar KS, Venkateswarlu P, J. Chem. Thermodyn., 38(12), 1553 (2006)
Reddy PM, Kumar KS, Venkatesu P, Fluid Phase Equilib., 310(1-2), 74 (2011)
Riddick JA, Bunger WB, Sakano TK, Organic solvents physical properties and method of purifications, Wiley Interscience, New York, 2 (1986)
Palepu R, Joan O, Campell D, J. Chem. Eng. Data, 30, 355 (1985)
Oswal SL, Pandiyan V, Krishnakumar B, Vasantharani P, Thermochim. Acta, 507, 27 (2010)
Chandersekhar G, Venkatesu P, Rao MVP, Phys. Chem. Liq., 40, 181 (2002)
Bhatia SC, Rani R, Sangwan J, Bhatia R, Int. J. Thermophys., 32, 2039 (2011)
Ali A, Nain AK, Chand D, Lal B, Indian J. Chem., 44, 511 (2005)
Rathnam MJV, Kavitha RB, Sayed RT, Kumar MSS, Eur. Chem. Bull., 2, 434 (2013)
Jaganath, Dixit AP, J. Chem. Eng. Data, 29, 313 (1984)
Reddy DVB, Ramanjaneyulu K, Krishnaiah A, Phys. Chem. Liq., 27, 221 (1988)
Venkateswarlu P, Chowdary NV, Raman GK, Phys. Chem. Liq., 14, 107 (1984)
Nain AK, J. Mol. Liq., 140, 108 (2008)
Kawaizumi F, Ohno M, Miyahara Y, Bull. Chem. Soc. Jpn., 50, 2229 (1977)
Devi US, Samatha K, Visvanantasarma A, J. Pure Appl. Ultrason., 26, 1 (2004)
Fort RJ, Moore WR, Trans Faraday Soc., 6, 2102 (1965)
Fort RJ, Moore WR, Trans. Faraday Soc., 61, 2102 (1965)
Pikkarainan L, J. Chem. Eng. Data, 28, 344 (1983)
Reed TM, Taylor TE, J. Phys. Chem., 63, 58 (1959)
Grunberg L, Nissan AH, Mixture law for viscosity, Nature, 164, 799 (1949)
Katti PK, Chaudhri MH, J. Chem. Eng. Data, 9, 442 (1964)
Hind RK, McLaughlin E, Ubbelohde A, Trans Faraday Soc., 56, 328 (1960)
Kalra KC, Singh KC, Spah DC, J. Ind. Chem. Soc., 69, 138 (1992)
Redlich O, Kister AT, Ind. Eng. Chem., 40, 345 (1948)
Gowrisankar M, Venkateswarlu P, Kumar KS, Sivarambabu S, J. Soln., Chem., 42(5), 916 (2013)
Manukonda G, Ponneri V, Kasibhatta S, Sakamuri S, Korean J. Chem. Eng., 30(5), 1131 (2013)
Gowrisankar M, Venkateswarlu P, Kumar KS, Sivarambabu S, J. Therm. Anal. Calorim., DOI:10.1007/s10973-013-3312z (2013)
Syamala V, Prabhakar G, Sivakumar K, Venkateswarlu P, Phys. Chem. Liq., 44, 127 (2006)
Syamala V, Kumar KS, Venkateswarlu P, J. Chem. Thermodyn., 38(12), 1553 (2006)
Reddy PM, Kumar KS, Venkatesu P, Fluid Phase Equilib., 310(1-2), 74 (2011)
Riddick JA, Bunger WB, Sakano TK, Organic solvents physical properties and method of purifications, Wiley Interscience, New York, 2 (1986)
Palepu R, Joan O, Campell D, J. Chem. Eng. Data, 30, 355 (1985)
Oswal SL, Pandiyan V, Krishnakumar B, Vasantharani P, Thermochim. Acta, 507, 27 (2010)
Chandersekhar G, Venkatesu P, Rao MVP, Phys. Chem. Liq., 40, 181 (2002)
Bhatia SC, Rani R, Sangwan J, Bhatia R, Int. J. Thermophys., 32, 2039 (2011)
Ali A, Nain AK, Chand D, Lal B, Indian J. Chem., 44, 511 (2005)
Rathnam MJV, Kavitha RB, Sayed RT, Kumar MSS, Eur. Chem. Bull., 2, 434 (2013)
Jaganath, Dixit AP, J. Chem. Eng. Data, 29, 313 (1984)
Reddy DVB, Ramanjaneyulu K, Krishnaiah A, Phys. Chem. Liq., 27, 221 (1988)
Venkateswarlu P, Chowdary NV, Raman GK, Phys. Chem. Liq., 14, 107 (1984)
Nain AK, J. Mol. Liq., 140, 108 (2008)
Kawaizumi F, Ohno M, Miyahara Y, Bull. Chem. Soc. Jpn., 50, 2229 (1977)
Devi US, Samatha K, Visvanantasarma A, J. Pure Appl. Ultrason., 26, 1 (2004)
Fort RJ, Moore WR, Trans Faraday Soc., 6, 2102 (1965)
Fort RJ, Moore WR, Trans. Faraday Soc., 61, 2102 (1965)
Pikkarainan L, J. Chem. Eng. Data, 28, 344 (1983)
Reed TM, Taylor TE, J. Phys. Chem., 63, 58 (1959)
Grunberg L, Nissan AH, Mixture law for viscosity, Nature, 164, 799 (1949)
Katti PK, Chaudhri MH, J. Chem. Eng. Data, 9, 442 (1964)
Hind RK, McLaughlin E, Ubbelohde A, Trans Faraday Soc., 56, 328 (1960)
Kalra KC, Singh KC, Spah DC, J. Ind. Chem. Soc., 69, 138 (1992)
Redlich O, Kister AT, Ind. Eng. Chem., 40, 345 (1948)
