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Received October 29, 2013
Accepted February 6, 2014
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Electrochemical properties of Co-less layered transition metal oxide as high energy cathode material for Li-ion batteries
Sungho Choo1 2
Hye Yeon Kim1
Dong Young Yoon1
Wonchang Choi1
Si-Hyung Oh1
Jeh Beck Ju3
Jang Myoun Ko4†
Ho Jang2
Won Il Cho1†
1Center for Energy Convergence, Korea Institute of Science and Technology, Seoul 136-791, Korea 2Department of Materials Science and Engineering, Korea University, 145, Anam-ro, Seongbuk-gu, Seoul 136-701, Korea 3Department of Chemical Engineering, Hongik University, Seoul 121-791, Korea 4Department of Chemical and Biological Engineering, Hanbat National University, 125, Yuseong-gu, Daejeon 305-719, Korea
jmko@hanbat.ac.kr
Korean Journal of Chemical Engineering, May 2014, 31(5), 905-910(6), 10.1007/s11814-014-0046-y
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Abstract
High energy nickel manganese cobalt oxide materials (HENMC) are one of the most viable cathode materials for a high energy density lithium ion battery (LIB), but they contain expensive and toxic cobalt (Co). We synthesized Co-free high energy nickel manganese oxide cathode materials (HENM) via a solid state reaction method and a coprecipitation method. Their structural and electrochemical properties were comparatively investigated using X-ray diffraction spectroscopy (XRD), scanning electron microscopy (SEM), inductively coupled plasma (ICP), electron probe micro-analysis (EPMA), particle size analysis (PSA) and electrochemical impedance spectroscopy (EIS). The co-precipitated HENM and the solid state fabricated HENM showed high capacities of 250 mAhg^(-1) and 240 mAhg^(-1), respectively. It suggests that the solid state fabricated method of HENM would be a good candidate for practical application as well as the co-precipitated one.
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References
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