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Received May 27, 2013
Accepted February 10, 2014
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Preparation and characterization of nanocomposite heterogeneous cation exchange membranes modified by silver nanoparticles
Thin Film Laboratory, Department of Physic, Faculty of Science, Arak University, Arak 38156-8-8349, Iran 1Department of Chemical Engineering, Faculty of Engineering, Arak University, Arak 38156-8-8349, Iran
a-zendehnam@araku.ac.ir
Korean Journal of Chemical Engineering, July 2014, 31(7), 1187-1193(7), 10.1007/s11814-014-0051-1
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Abstract
We prepared polyvinylchloride based nanocomposite heterogeneous cation exchange membranes by solution casting technique using cation exchange resin powder as functional groups agent and tetrahydrofuran as solvent. Silver nanoparticles were also used as fillers in membrane fabrication. The effect of silver nanoparticles concentration in casting solution on membrane physico/chemical and antibacterial characteristics was studied. The SEM images showed compact structure for the modified membranes. X-ray diffraction results also revealed that membrane crystallinity was clearly changed by increase of nanoparticle concentration. Membrane selectivity and transport number were enhanced initially by increase in nanoparticle content up to 4%wt in prepared membrane, and then showed decreasing trend by more increase_x000D_
in additive concentration from 4 to 8%wt. Selectivity and transport number were enhanced another time by further increase in nanoparticle loading ratio from 8 to 16%wt. Opposite trend was found for the membranes’ average grain size by variation in additive content. Ionic flux was also clearly enhanced by using Ag nanoparticles in membrane matrix. Moreover, modified membranes showed good ability in decrease of Escherichia coli growth rate.
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References
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Hosseini SM, Madaeni SS, Khodabakhshi AR, Sep. Sci. Technol., 45(16), 2308 (2010)
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Kerres J, Cui W, Disson R, Neubrand W, J. Membr. Sci., 139(2), 211 (1998)
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Nagarale RK, Shahi VK, Thampy SK, Rangarajan R, React. Funct. Polym., 61, 131 (2004)
Kang MS, Choi YJ, Choi IJ, Yoon TH, Moon SH, J. Membr. Sci., 216(1-2), 39 (2003)
Lin H, Freeman BD, J. Mol. Struct., 739, 74 (2005)
Amooghin AE, Sanaeepur H, Moghadassi A, Kargari A, Ghanbari D, Mehrabadi ZS, Sep. Sci. Technol., 45(10), 1385 (2010)
Vasilev K, Cook J, Griesser HJ, Expert Review of Medical Devices, 6/5, 553 (2009)
Park SY, Choi J, Environ. Eng. Res., 15(1), 23 (2010)
Sondi I, Salopek-Sondi B, J. Colloid Interface Sci., 275(1), 177 (2004)
Hosseini SM, Madaeni SS, Khodabakhshi AR, Sep. Sci. Technol., 45(16), 2308 (2010)
Xu TW, J. Membr. Sci., 263(1-2), 1 (2005)
Hideo K, Tsuzura K, Shimizu H, Ion exchange membranes, in: K. Dorfner (Ed.), Ion Exchangers, Walter de Gruyter, Berlin (1991)
Strathmann H, Electrodialysis and related processes, in: R.D. Noble, S. A. Stern (Eds.), Membrane Separation Technology-Principles and Applications, Elsevier Science B.V., 214 (1995)
Juda M, McRac WA, J. Am. Chem. Soc., 72, 1044 (1950)
Winger AG, Bodamer GW, Kunin R, J. Electrochem. Soc., 100, 178 (1953)
Pourcelly G, Gavach C, Electrodialysis water splitting-application of electrodialysis with bipolar membranes, in: Kemperman AJB (Ed.), Handbook on Bipolar Membrane Technology, Twente University Press, Enschede, 17 (2000)
Xu TW, Desalination, 140(3), 247 (2001)
Daufin G, Escudier JP, Carrere H, Berot S, Fillaudeau L, Decloux M, Food and Bioproducts Processing, 79, 89 (2001)
Tarvainen T, Svarfvar B, Akerman S, Savolainen J, Karhu M, Paronen P, Jarvinen K, Biomaterials, 20, 2177 (1999)
Kim YH, Moon SH, J. Chem. Technol. Biotechnol., 76(2), 169 (2001)
Saracco G, Annali di Chimica, 93, 817 (2003)
Bazinet L, Lamarche F, Ippersiel D, Trends in Food Sci. Technol., 9, 107 (1998)
Xu T, Resour. Conserv. Recycl., 37, 1 (2002)
Hirose S, Shimizu A, Nose T, J. Appl. Polym. Sci., 23, 3193 (1979)
Hirose S, Yasukawa E, J. Appl. Polym. Sci., 26, 1039 (1981)
Hiroshi O, Kazuhiko R, Tadashi U, J. Membr. Sci., 83, 199 (1993)
Bodzek M, Konieczny K, J. Membr. Sci., 61, 131 (1991)
Varma R, The medical relevance of PVC, Medical Device & Diagnostic Industry, 19 (2007)
Hosseini SM, Madaeni SS, Khodabakhshi AR, Zendehnam A, J. Membr. Sci., 365(1-2), 438 (2010)
Thomassin JM, Kollar J, Caldarella G, Germain A, Jerome R, Detrembleur C, J. Membr. Sci., 303(1-2), 252 (2007)
Hosseini SM, Madaeni SS, Khodabakhshi AR, J. Appl. Polym. Sci., 118(6), 3371 (2010)
Pourjafar S, Rahimpour A, Rahimpour M, J. Ind. Eng. Chem., 18(4), 1398 (2012)
Bellantone M, Coleman NJ, Hench LL, J. Biomed. Mater. Res., 51, 484 (2000)
Jeong SH, Yeo SY, Yi SC, J. Mater. Sci., 40(20), 5407 (2005)
Wang YL, Wan YZ, Dong XH, Cheng GX, Tao HM, Wen TY, Carbon, 36, 1567 (1998)
Shahi VK, Trivedi GS, Thampy SK, Rangarajan R, J. Colloid Interface Sci., 262(2), 566 (2003)
Gohil GS, Shahi VK, Rangarajan R, J. Membr. Sci., 240(1-2), 211 (2004)
Zendehnam A, Arabzadegan M, Hosseini SM, Robatmili N, Madaeni SS, Korean J. Chem. Eng., 30(6), 1265 (2013)
Elshabini A, Barlow FD, Thin film technology Handbook, McGraw-Hill (1997)
Reily DK, Pavia AT, Beatty PG, American J. Medicine, 97/6, 509 (1994)
Sirinivasan A, Karchmer T, Richards A, Song X, Perl TM, Infection Control and Hospital Epidemiology, 27, 38 (2006)
Hosseini SM, Madaeni SS, Khodabakhshi AR, J. Membr. Sci., 362(1-2), 550 (2010)
Li XF, Wang Z, Lu H, Zhao CJ, Na H, Zhao C, J. Membr. Sci., 254(1-2), 147 (2005)
Erertovr L, Physics of thin films, 2nd Ed., Plenum Press (1986)
Shahi VK, Thampy SK, Rangarajan R, J. Membr. Sci., 158(1-2), 77 (1999)
Kerres J, Cui W, Disson R, Neubrand W, J. Membr. Sci., 139(2), 211 (1998)
Lide DR, CRC Handbook of chemistry and physics, CRC Press, 87th Ed., 2006-2007.
Nagarale RK, Shahi VK, Thampy SK, Rangarajan R, React. Funct. Polym., 61, 131 (2004)
Kang MS, Choi YJ, Choi IJ, Yoon TH, Moon SH, J. Membr. Sci., 216(1-2), 39 (2003)
Lin H, Freeman BD, J. Mol. Struct., 739, 74 (2005)
Amooghin AE, Sanaeepur H, Moghadassi A, Kargari A, Ghanbari D, Mehrabadi ZS, Sep. Sci. Technol., 45(10), 1385 (2010)
Vasilev K, Cook J, Griesser HJ, Expert Review of Medical Devices, 6/5, 553 (2009)
Park SY, Choi J, Environ. Eng. Res., 15(1), 23 (2010)
Sondi I, Salopek-Sondi B, J. Colloid Interface Sci., 275(1), 177 (2004)
