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Received October 12, 2013
Accepted February 10, 2014
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Presulfidation and activation mechanism of Mo/Al2O3 catalyst sulfided by ammonium thiosulfate
State Key laboratory of Coal Conversion Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
lxk@sxicc.ac.cn
Korean Journal of Chemical Engineering, August 2014, 31(8), 1368-1376(9), 10.1007/s11814-014-0053-z
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Abstract
Mo/Al2O3 catalyst was presulfided with (NH4)2S2O3 to elucidate presulfidation and activation mechanism. It is illustrated that the Mo oxide is firstly partially sulfided during presulfidation and then in situ reduced into MoS2-x in activation, and finally sulfided to active state during hydrodesulfurization (HDS). A synergistic effect between the S2- and S6+ ions in (NH4)2S2O3 produces a positive influence on the HDS performance. The S2- ions contribute to the sulfidation_x000D_
of Mo ions, while the S6+ species interact with Al2O3 support, weakening the interaction of active species with support.
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Qian W, Yamada S, Ishihara A, Ichinoseki M, Kabe T, Sekiyu Gakkaishi, 44, 225 (2001)
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Plazenet G, Payen E, Lynch J, Rebours B, J. Phys. Chem. B, 106(28), 7013 (2002)
Berhault G, Mehta A, Pavel AC, Yang JZ, Rendon L, Yacaman MJ, Araiza LC, Moller AD, Chianelli RR, J. Catal., 198(1), 9 (2001)
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Blashka S, Bond G, Ward D, Oil Gas J., 96, 36 (1998)
Ge H, Li X, Wang J, Lu Z, Qin Z, Zhou L, J. Fuel Chem. Technol., 37, 199 (2009)
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Scheffer B, van Oers EM, Arnoldy P, de Beer VJH, Moulijn JA, Appl. Catal., 25, 303 (1986)
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Muijsers JC, Weber T, Vanhardeveld RM, Zandbergen HW, Niemantsverdriet JW, J. Catal., 157(2), 698 (1995)
Guichard B, Roy-Auberger A, Devers E, Legens C, Raybaud P, Catal. Today, 130(1), 97 (2008)
Candia R, Sorensen O, Villadsen J, Topsoe NY, Clausen BS, Topsoe H, Bull. Soc. Chim. Belg., 93, 763 (1984)
Topsoe H, Clausen BS, Appl. Catal., 25, 273 (1986)
Sun MY, Nicosia D, Prins R, Catal. Today, 86(1-4), 173 (2003)
Medici L, Prins R, J. Catal., 163(1), 28 (1996)
Fujikawa T, Kimura H, Kiriyama K, Hagiwara K, Catal. Today, 111(3-4), 188 (2006)
Hayden TF, Dumesic JA, Sherwood RD, Baker RTK, J. Catal., 105, 299 (1987)
Vissers JPR, Scheffer B, de Beer JHJ, Moulijn JA, Prins R, J. Catal., 105, 277 (1987)
van Veen JAR, Gerkema E, van der Kraan AM, Knoester A, Chem. Commun., 1684 (1987)
Louwers SP, Craje MW, Vanderkraan AM, Geantet C, Prins R, J. Catal., 144(2), 579 (1993)
Browne VM, Louwers SPA, Prins R, Catal. Today, 10, 345 (1991)
Usman, Yamamoto T, Kubota T, Okamoto Y, Appl. Catal., 328, 219 (2007)
Yamada S, Qian W, Ishihara A, Wang G, Li L, Kabe T, Sekiyu Gakkaishi, 44, 217 (2001)
Chen CL, Wang CH, Weng HS, Chemosphere, 56, 425 (2004)
