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Received August 18, 2013
Accepted February 21, 2014
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Effect of polymer and additive on the structure and property of porous stainless steel hollow fiber
State Key Laboratory of Chemical Engineering, Membrane Science and Engineering R&D Lab., Chemical Engineering Research Center, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China
chemxuzl@ecust.edu.cn
Korean Journal of Chemical Engineering, August 2014, 31(8), 1438-1443(6), 10.1007/s11814-014-0060-0
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Abstract
Porous stainless steel hollow fiber has been widely used due to its high mechanical strength, excellent thermal conductivity and good sealing properties compared with other porous supports. We successfully prepared porous stainless steel hollow fibers using polyacrylonitrile (PAN) as polymer via dry-wet spinning followed by sintering through temperature programming method. The PAN concentration had an obvious impact on the structure and property of porous stainless steel hollow fiber even if it would be burned off during sintering. The results showed that the morphology could be tuned by adjusting the concentration of PAN. With increasing PAN concentration in casting solution for spinning, the viscosity was increased dramatically, resulting in much compact structures with high pure water flux (higher than 3×10^(5) L·m-2·h-1·Pa-1). A more dense structure could be obtained by adding additive polyvinylpyrrolidone (PVP) as viscosity enhancer.
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