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Received December 17, 2013
Accepted March 27, 2014
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Influence of thermally induced, dehydroxylated nanoclay on polymer nanocomposites
1Central Institute of Plastics Engineering and Technology (CIPET), Chennai, India 2Laboratory of Advanced Research in Polymeric Materials (LARPM), CIPET, Bhubaneswar, India
papers.journal@gmail.com
Korean Journal of Chemical Engineering, August 2014, 31(8), 1480-1489(10), 10.1007/s11814-014-0094-3
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Abstract
This work reports a novel approach towards a chemical-free treatment of nanoclay through extensive thermal exposure. Dehydroxylation at high temperature was utilized to enhance the influence of nanoclay on the properties of polymer. The effect of this treatment of nanoclay, on the polymer properties, with reference to Polypropylene (PP) has been investigated. The FTIR spectra revealed the successful removal of water from the intergallery spacing of the nanoclay. The maintained structural configuration of the clay was confirmed using WAXD pattern. The uniform dispersion and exfoliation of thermally treated clay layers inside the polymer matrix was confirmed through enhanced mechanical properties. Improved crystallization properties, thermal stability and flame retardant characteristic were also noticed in the nanocomposites reinforced with thermally dehydroxylated clay. This study revealed that the dehydroxylation approach of modification of nanoclay may provide much enhanced properties of polymer, without involvement_x000D_
of any chemical for modification.
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He XF, Yang J, Zhu LC, Wang B, Sun GP, Lv PF, Phang IY, Liu TX, J. Appl. Polym. Sci., 102(1), 542 (2006)
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Karakassides MA, Gournis D, Petridis D, Clay Min., 34, 438 (1999)
Liu W, Hoa SV, Pugh M, Compos. Sci. Technol., 65, 2364 (2005)
Kusmono, Wildan MW, Ishak ZAM, Int. J. Polym. Sci. (2013)
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Garces J, Moll DJ, Bicerano J, Fibiger R, McLeod DG, Adv. Mater., 12, 1839 (2000)
Manias E, Touny A, Wu L, Strawhecker K, Lu B, Chung TC, Chem. Mater., 13, 3516 (2001)
Olewnik E, Garman K, Czerwinski W, J. Therm. Anal. Calorim., 101, 323 (2012)
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Ma H, Tong L, Xu Z, Fang Z, Nanotechnology, 18, 375602 (2007)
Jash P, Wilkie CA, Polym. Degrad. Stabil., 88, 401 (2005)
Sahoo PK, Samal R, Polym. Degrad. Stabil., 92, 1700 (2007)
