Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received May 22, 2014
Accepted January 26, 2015
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Preparation of reusable conductive activated charcoal plate as a new electrode for industrial wastewater treatment
Research Laboratory of Environment Protection Technology, Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran
Korean Journal of Chemical Engineering, October 2015, 32(10), 2014-2023(10), 10.1007/s11814-015-0021-2
Download PDF
Abstract
A conductive activated charcoal plate (ACP) was prepared from a low-cost, abundant, and non-conductive charcoal. The prepared ACP was characterized using N2 adsorption/desorption isotherms, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR) and X-ray diffraction (XRD). Brunauer-Emmett-Teller (BET) surface area of the charcoal and the ACP was 0.58m2 g.1 and 461.67m2 g.1, respectively. The ACP was employed in textile wastewater treatment using electrosorption process. Response surface methodology (RSM) was applied to design the experiments. The decolorization efficiency of 76% at optimum conditions of voltage=450mV, pH=4, and contact time=120 min indicated that the ACP has promising potential to decolorize textile wastewater. Moreover, the results of the kinetic analyses demonstrated that wastewater treatment followed pseudo-first order kinetic model. The ACP electrode could be regenerated and reused effectively at five successive cycles of electrosorption/electrodesorption.
Keywords
References
Hossain MM, Mahmud MI, Parvez MS, Cho HM, Environ. Eng. Res., 18, 157 (2013)
Karthikeyan S, Titus A, Gnanamani A, Mandal AB, Sekaran G, Desalination, 281, 438 (2011)
Aber S, Salari D, Feiz BA, Water Sci. Technol., 63, 1389 (2011)
Mondal MK, Korean J. Chem. Eng., 27(1), 144 (2010)
Shirzad-Siboni M, Jafari SJ, Farrokhi M, Yang JK, Environ. Eng. Res., 18, 247 (2013)
Ban A, Schafer A, Wendt H, J. Appl. Electrochem., 28(3), 227 (1998)
Foo KY, Hameed BH, J. Hazard. Mater., 170(2-3), 552 (2009)
Zhan YK, Nie CY, Li HB, Pan LK, Sun Z, Electrochim. Acta, 56(9), 3164 (2011)
Hou CH, Huang CY, Desalination, 314, 124 (2013)
Huang CC, He JC, Chem. Eng. J., 221, 469 (2013)
Asghar HMA, Hussain SN, Sattar H, Roberts EPL, Brown NW, Korean J. Chem. Eng., 31(5), 834 (2014)
Ayranci E, Conway BE, J. Electroanal. Chem., 513(2), 100 (2001)
Kong Y, Li W, Wang Z, Yao C, Tao Y, Electrochem. Commun., 26, 59 (2013)
Han YH, Quan X, Chen S, Zhao HM, Cui CY, Zhao YZ, Sep. Purif. Technol., 50(3), 365 (2006)
Zhan Y, Nie C, Li H, Pan L, Sun Z, Phys. Status Solidi A-Appl. Res., 9, 55 (2012)
Li H, Lu T, Pan L, Zhang Y, Sun Z, J. Mater. Chem., 19, 6773 (2009)
Farmer JC, Bahowick SM, Harrar JE, Fix DV, Martinelli RE, Vu AK, Carroll KL, Energy Fuels, 11(2), 337 (1997)
Wang G, Qian BQ, Dong Q, Yang JY, Zhao ZB, Qiu JS, Sep. Purif. Technol., 103, 216 (2013)
Association APH, Standard Methods for the Examination of Water and Wastewater, Washington D.C., USA (1989).
Aber S, Sheydaei M, Clean - Soil Air Water, 40, 87 (2012)
Brunauer S, Emmett PH, Teller E, J. Am. Chem. Soc., 60, 309 (1938)
Lippens BC, de Boer JH, J. Catal., 4, 319 (1965)
Barrett EP, Joyner LG, Halenda PP, J. Am. Chem. Soc., 73, 373 (1951)
Mikhail RS, Brunauer S, Bodor EE, J. Colloid Interface Sci., 26, 45 (1968)
Karthikeyan S, Magthalin CJ, Mandal AB, Sekaran G, RSC Advances, 4, 19183 (2014)
Sheydaei M, Aber S, CLEAN - Soil, Air, Water, 41, 890 (2013)
Dey S, Mukherjee S, J. Environ. Sci., 25, 698 (2013)
Murugesan S, Rajiv S, Thanapalan M, Korean J. Chem. Eng., 26(2), 364 (2009)
Chun SY, An SW, Lee SJ, Kim JT, Chang SW, Korean J. Chem. Eng., 31(6), 994 (2014)
Afkhami A, Madrakian T, Karimi Z, J. Hazard. Mater., 144(1-2), 427 (2007)
Aworn A, Thiravetyan P, Nakbanpote W, J. Anal. Appl. Pyrolysis, 82, 279 (2008)
Aber S, Khataee A, Sheydaei M, Bioresour. Technol., 100(24), 6586 (2009)
Shi Q, Zhang J, Zhang C, Li C, Zhang B, Hu W, Xu J, Zhao R, J. Environ. Sci., 22, 91 (2010)
Karthikeyan S, Anandan C, Subramanian J, Sekaran G, RSC Advances, 3, 15044 (2013)
Karthikeyan S, Boopathy R, Gupta VK, Sekaran G, J. Mol. Liq., 177, 402 (2013)
Wang ZM, Kanoh H, Kaneko K, Lu GQ, Do D, Carbon, 40, 1231 (2002)
Vijayakumar G, Yoo CK, Elango KGP, Dharmendirakumar M, Clean, 38, 202 (2010)
Sing KSW, Pure Appl. Chem., 54, 2201 (1982)
Karthikeyan S, Kumar MA, Maharaja P, Partheeban T, Sridevi J, Sekaran G, J. Taiwan Inst. Chem. E., 45, 1739 (2014)
Martin MJ, Artola A, Balaguer MD, Rigola M, Chem. Eng. J., 94(3), 231 (2003)
Runyan WR, Semiconductor Measurements and Instrumentation, McGraw-Hill, New York (1975).
Bansal RC, Goyal M, Activated Carbon Adsorption, CRC Press, Boca Raton, FL (2005).
Karthikeyan S, Sekaran G, Phys. Chem. Chem. Phys., 16, 3924 (2014)
Shahrezaei F, Mansouri Y, Zinatizadeh AAL, Akhbari A, Powder Technol., 221, 203 (2012)
Rong C, Xien H, J. Colloid Interface Sci., 290(1), 190 (2005)
Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
Allen SJ, Gan Q, Matthews R, Johnson PA, J. Colloid Interface Sci., 286(1), 101 (2005)
Chen ZL, Song CY, Sun XW, Guo HF, Zhu GD, Desalination, 267(2-3), 239 (2011)
Karthikeyan S, Titus A, Gnanamani A, Mandal AB, Sekaran G, Desalination, 281, 438 (2011)
Aber S, Salari D, Feiz BA, Water Sci. Technol., 63, 1389 (2011)
Mondal MK, Korean J. Chem. Eng., 27(1), 144 (2010)
Shirzad-Siboni M, Jafari SJ, Farrokhi M, Yang JK, Environ. Eng. Res., 18, 247 (2013)
Ban A, Schafer A, Wendt H, J. Appl. Electrochem., 28(3), 227 (1998)
Foo KY, Hameed BH, J. Hazard. Mater., 170(2-3), 552 (2009)
Zhan YK, Nie CY, Li HB, Pan LK, Sun Z, Electrochim. Acta, 56(9), 3164 (2011)
Hou CH, Huang CY, Desalination, 314, 124 (2013)
Huang CC, He JC, Chem. Eng. J., 221, 469 (2013)
Asghar HMA, Hussain SN, Sattar H, Roberts EPL, Brown NW, Korean J. Chem. Eng., 31(5), 834 (2014)
Ayranci E, Conway BE, J. Electroanal. Chem., 513(2), 100 (2001)
Kong Y, Li W, Wang Z, Yao C, Tao Y, Electrochem. Commun., 26, 59 (2013)
Han YH, Quan X, Chen S, Zhao HM, Cui CY, Zhao YZ, Sep. Purif. Technol., 50(3), 365 (2006)
Zhan Y, Nie C, Li H, Pan L, Sun Z, Phys. Status Solidi A-Appl. Res., 9, 55 (2012)
Li H, Lu T, Pan L, Zhang Y, Sun Z, J. Mater. Chem., 19, 6773 (2009)
Farmer JC, Bahowick SM, Harrar JE, Fix DV, Martinelli RE, Vu AK, Carroll KL, Energy Fuels, 11(2), 337 (1997)
Wang G, Qian BQ, Dong Q, Yang JY, Zhao ZB, Qiu JS, Sep. Purif. Technol., 103, 216 (2013)
Association APH, Standard Methods for the Examination of Water and Wastewater, Washington D.C., USA (1989).
Aber S, Sheydaei M, Clean - Soil Air Water, 40, 87 (2012)
Brunauer S, Emmett PH, Teller E, J. Am. Chem. Soc., 60, 309 (1938)
Lippens BC, de Boer JH, J. Catal., 4, 319 (1965)
Barrett EP, Joyner LG, Halenda PP, J. Am. Chem. Soc., 73, 373 (1951)
Mikhail RS, Brunauer S, Bodor EE, J. Colloid Interface Sci., 26, 45 (1968)
Karthikeyan S, Magthalin CJ, Mandal AB, Sekaran G, RSC Advances, 4, 19183 (2014)
Sheydaei M, Aber S, CLEAN - Soil, Air, Water, 41, 890 (2013)
Dey S, Mukherjee S, J. Environ. Sci., 25, 698 (2013)
Murugesan S, Rajiv S, Thanapalan M, Korean J. Chem. Eng., 26(2), 364 (2009)
Chun SY, An SW, Lee SJ, Kim JT, Chang SW, Korean J. Chem. Eng., 31(6), 994 (2014)
Afkhami A, Madrakian T, Karimi Z, J. Hazard. Mater., 144(1-2), 427 (2007)
Aworn A, Thiravetyan P, Nakbanpote W, J. Anal. Appl. Pyrolysis, 82, 279 (2008)
Aber S, Khataee A, Sheydaei M, Bioresour. Technol., 100(24), 6586 (2009)
Shi Q, Zhang J, Zhang C, Li C, Zhang B, Hu W, Xu J, Zhao R, J. Environ. Sci., 22, 91 (2010)
Karthikeyan S, Anandan C, Subramanian J, Sekaran G, RSC Advances, 3, 15044 (2013)
Karthikeyan S, Boopathy R, Gupta VK, Sekaran G, J. Mol. Liq., 177, 402 (2013)
Wang ZM, Kanoh H, Kaneko K, Lu GQ, Do D, Carbon, 40, 1231 (2002)
Vijayakumar G, Yoo CK, Elango KGP, Dharmendirakumar M, Clean, 38, 202 (2010)
Sing KSW, Pure Appl. Chem., 54, 2201 (1982)
Karthikeyan S, Kumar MA, Maharaja P, Partheeban T, Sridevi J, Sekaran G, J. Taiwan Inst. Chem. E., 45, 1739 (2014)
Martin MJ, Artola A, Balaguer MD, Rigola M, Chem. Eng. J., 94(3), 231 (2003)
Runyan WR, Semiconductor Measurements and Instrumentation, McGraw-Hill, New York (1975).
Bansal RC, Goyal M, Activated Carbon Adsorption, CRC Press, Boca Raton, FL (2005).
Karthikeyan S, Sekaran G, Phys. Chem. Chem. Phys., 16, 3924 (2014)
Shahrezaei F, Mansouri Y, Zinatizadeh AAL, Akhbari A, Powder Technol., 221, 203 (2012)
Rong C, Xien H, J. Colloid Interface Sci., 290(1), 190 (2005)
Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
Allen SJ, Gan Q, Matthews R, Johnson PA, J. Colloid Interface Sci., 286(1), 101 (2005)
Chen ZL, Song CY, Sun XW, Guo HF, Zhu GD, Desalination, 267(2-3), 239 (2011)
