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Received August 12, 2014
Accepted January 23, 2015
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A comprehensive study (kinetic, thermodynamic and equilibrium) of arsenic (V) adsorption using KMnO4 modified clinoptilolite
Mohamadreza Massoudinejad
Anvar Asadi1†
Mehdi Vosoughi2
Morteza Gholami3
Babak Kakavandi2
Mohammad Amin Karami3
Department of Environmental Health and Member of Safety Promotion and Injury Prevention Research Center, Shahid Beheshti University of Medical Science, Tehran, Iran 1Department of Environmental Health Engineering, School of Public Health, Student’s Research Committee, Shahid Beheshti University of Medical Sciences, Tehran, Iran 2Department of Environmental Health Engineering, School of Health, Ahvaz, Jundishapur University of Medical Sciences, Ahvaz, Iran 3Department of Environmental Health Engineering, School of Health, Ilam University of Medical Science-Environment Research Center, Isfahan University of Medical Sciences (IUMS), Isfahan, Iran
anvarasadi@sbmu.ac.ir
Korean Journal of Chemical Engineering, October 2015, 32(10), 2078-2086(9), 10.1007/s11814-015-0018-x
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Abstract
The sorption of As(V) on manganese oxide coated zeolite (MOCZ) was investigated through batch study to explore the feasibility of removing arsenic from groundwater. MOCZ was characterized by scanning electron microscopy, XRD, FTIR spectroscopy, and point of zero charge (pHPZC) measurements. The effects of process parameters such as contact time, adsorbent size, temperature and pH were investigated. Arsenic detection was carried out by atomic fluorescence spectrometer. Arsenate adsorption onto MOCZ followed the pseudo-second-order kinetic model with a correlation coefficient more than 0.99. Optimum removal of arsenate occurred within pH range of 6-10. The equilibrium data were analyzed by Langmuir, Freundlich and Dubinin-Radushkevich (D-R) isotherm models. The maximum adsorption capacity calculated from the Langmuir and D-R models was 151 and 152.8 μg g.1, respectively, at 38 oC. The activation energy of adsorption (Ea) was found to be 3.68 kj mol.1, suggesting that the adsorption process may be physical sorption. Thermodynamic parameters: ΔHo, was 1.181 kj mol.1; ΔSo, was .0.29 kj mol.1, while the values of ΔGo were .83.9, .86.7 and 89.8 kj mol.1 at 18, 28 and 38, respectively, suggesting endothermic and spontaneous process and a rise in temperature favoring the adsorption.
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