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Received December 4, 2014
Accepted March 13, 2015
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Choline chloride-based deep eutectic solvents as additives for optimizing chromatographic behavior of caffeic acid
Tianjin Key Laboratory of Organic Solar Cells and Photochemical Conversion, Tianjin University of Technology, Tianjin 300384, China
zhutao@tjut.edu.cn
Korean Journal of Chemical Engineering, October 2015, 32(10), 2103-2108(6), 10.1007/s11814-015-0054-6
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Abstract
A series of deep eutectic solvents (DESs) were prepared using glycerol and choline chloride (ChCl), and Fourier transform infrared spectrometer (FT-IR) was used to analyze the spectra of glycerol, choline chloride and DESs based on glycerol and choline chloride. Then DESs were used as the additives of mobile phase to optimize chromatographic behavior of caffeic acid in high performance liquid chromatography (HPLC). A 17-run Box-Behnken design (BBD) was employed to evaluate effect of DESs as additives by analyzing the maximum theoretical plate number. Three factors, reaction temperature (60 oC, 80 oC, 100 oC), molar ratio of glycerol and choline chloride (2 : 1, 3 : 1, 4 : 1, n/n), and volume percent of additives (0.05%, 0.10%, 0.15%, v/v), were investigated in BBD. The optimum experiment condition was that of reaction temperature (80 oC), molar ratio of glycerol and ChCl (3 : 1, n/n), and volume percent of additive (0.10%, v/v). The mean chromatographic theoretical plate number of the caffeic acid this condition was 1567.5, and DESs as additives shorten the retention time and modify the chromatogram shape, proving DESs as additives for effective theoretical plate number and column efficiency in HPLC.
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Varnalis AI, Brennan JG, MacDougall DB, Gilmour SG, J. Food Eng., 61(2), 153 (2004)
Zhu T, Row KH, J. Liq. Chromatogr. Relat. Technol., 34(12), 1036 (2011)
Xu H, Sun LP, Shi YZ, Wu YH, Zhang B, Zhao DQ, Biochem. Eng. J., 39, 66 (2008)
Sun Y, Li T, Yan J, Liu J, Carbohydr. Polym., 80, 242 (2010)
Wu Y, Cui SW, Tan JX, Food. Chem., 105, 1599 (2007)
Zhong K, Wang Q, Carbohydr. Polym., 80, 19 (2010)
Zhu T, Row KH, Sep. Sci. Technol., 48(10), 1510 (2013)
