Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received August 24, 2014
Accepted March 10, 2015
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Enhanced copper(II) biosorption on SiO2-alginate gel composite: A mechanistic study with surface characterization
Chemistry Department, Faculty of Engineering, Istanbul University, Avcilar 34320, Istanbul, Turkey
Korean Journal of Chemical Engineering, October 2015, 32(10), 2116-2123(8), 10.1007/s11814-015-0051-9
Download PDF
Abstract
A new SiO2-alginate biocomposite was synthesized with improved mechanical properties, showing chelation capability of divalent metal ions, especially Cu(II), through its carboxylic acid ends. The biocomposite was characterized using scanning electron microscopy (SEM), Fourier-transform infrared (FTIR), and X-ray photoelectron spectroscopy (XPS) techniques. The adsorption of copper(II) onto both H- and Ca-forms of sorbent was investigated as a function of pH and contact time, and adsorption data were modeled with the aid of Langmuir and Freundlich isotherms. The release of Ca(II) ions accompanying copper(II) binding was evaluated by selective surface complexation concept involving ion-exchange. The IR spectra gave detailed information on complexation of carbonyl group with copper ions and on the relative contribution of SiO2 involved in copper uptake. The adsorption edge of copper was within the pH range 4.0-5.5, and the sorbent capacity was determined as 1.85 and 1.10mmolg.1 for H- and Ca-forms, respectively.
References
Torres MR, Sousa APA, Silva Filho EAT, Melo DF, Feitosa JPA, de Paulab RCM, Lima MGS, Carbohydr. Res., 342(14), 2067 (2007)
Davis TA, Volesky B, Mucci A, Water Res., 37(18), 4311 (2003)
Yalcin S, Sezer S, Apak R, Environ. Sci. Pollut. Res., 19(8), 3118 (2012)
Chmielewska E, Sabova L, Peterlik L, Wu A, Braz. J. Chem. Eng., 28(1), 63 (2011)
Li Y, Xia B, Zhao Q, Liu F, Zhang P, Du Q, Wang D, Li D, Wang Z, Xia Y, J. Environ. Sci., 23(3), 404 (2011)
Murphy V, Hughes H, McLoughlin P, Water Res., 41(4), 731 (2007)
Lima IS, Airoldi C, Colloids Surf. A: Physicochem. Eng. Asp., 229(1-3), 129 (2003)
Davila-Guzman NE, de J. Cerino-Cordova F, Soto-Regalado E, Soto-Regalado E, Soto-Regalado JR, Diaz-Flores PE, Garza-Gonzalez MT, Loredo-Medrano JA, Clean., 41(6), 557 (2013)
Tam SK, Dusseault J, Polizu S, Menard M, Halle JP, Yahia LH, Biomaterials, 26(34), 6950 (2005)
Serra J, Gonzalez P, Liste S, Serra C, Chiussi S, Leon B, Perez-Amor M, Ylanen HO, Hupa M, J. Non-Cryst. Solids, 332(1-3), 20 (2003)
Figueira MM, Volesky B, Mathieu HJ, Environ. Sci. Technol., 33(11), 1840 (1999)
Chen J, Tendeyong F, Yiacoumi S, Environ. Sci. Technol., 31(5), 1433 (1997)
Wang FC, Zhao JM, Pan F, Zhou HC, Yang XF, Li WS, Liu HZ, Ind. Eng. Chem. Res., 52(9), 3453 (2013)
Choi JW, Yang KS, Kim DJ, Lee CE, Curr. Appl. Phys., 9(3), 694 (2009)
Park HG, Kim TW, Chae MY, Yoo IK, Process Biochem., 42(10), 1371 (2007)
Luna-Lopez JA, Carrillo-Lopez J, Aceves-Mijares M, Morales-Sanchez A, Falcony C, Superficies y Vacio, 22(1), 11 (2009)
Al-Oweini R, El-Rassy H, J. Mol. Struct., 919(1-3), 140 (2009)
Torres E, Mata YN, Blazquez AL, Munoz JA, Gonzalez F, Ballester A, Langmuir, 21(17), 7951 (2005)
Lim SF, Zheng YM, Zou SW, Chen JP, Environ. Sci. Technol., 42(7), 2551 (2008)
Fourest E, Volesky B, Environ. Sci. Technol., 30(1), 277 (1996)
Yalcin S, Clean., 42(3), 251 (2014)
Kleinubing SJ, Vieira RS, Beppu MM, Guibal E, da Silva MGC, Mat. Res, 13(4), 541 (2010)
Broderick E, Lyons H, Pembroke T, Byrne H, Murray B, Hall M, J. Colloid Interface Sci., 298(1), 154 (2006)
Czanderna AW, King DE, Spaulding D, J. Vac. Sci. Technol. A, 9(5), 2607 (1991)
Papageorgiou SK, Katsaros FK, Kouvelos EP, Nolan JW, Le Deit H, Kanellopoulos NK, J. Hazard. Mater., 137(3), 1765 (2006)
Chen JP, Hong LA, Wu SN, Wang L, Langmuir, 18(24), 9413 (2002)
Sheng PX, Ting YP, Chen JP, Hong L, J. Colloid Interface Sci., 275(1), 131 (2004)
Cheng X, Guan H, Su Y, J. Inorg. Organomet. Polym., 10(3), 115 (2000)
Figueira MM, Volesky B, Ciminelli VST, Roddick FA, Water Res., 34(1), 196 (2000)
Haug A, Acta. Chem. Scand., 15(8), 1794 (1961)
Jeon C, Park JY, Yoo YJ, Water Res., 36(7), 1814 (2002)
Rengaraj S, Yeon JW, Kim Y, Jung Y, Ha YK, Kim WH, J. Hazard. Mater., 143(1-2), 469 (2007)
Masel RI, Principles of Adsorption and Reaction on Solid Surfaces, Wiley-Interscience, New York (1996).
Sposito G, Soil Sci. Soc. Am. J., 46(6), 1147 (1982)
Wase J, Foster CF, Biosorbents for Metal Ions, Taylor & Francis Ltd., London, United Kingdom (1997).
Davis TA, Volesky B, Mucci A, Water Res., 37(18), 4311 (2003)
Yalcin S, Sezer S, Apak R, Environ. Sci. Pollut. Res., 19(8), 3118 (2012)
Chmielewska E, Sabova L, Peterlik L, Wu A, Braz. J. Chem. Eng., 28(1), 63 (2011)
Li Y, Xia B, Zhao Q, Liu F, Zhang P, Du Q, Wang D, Li D, Wang Z, Xia Y, J. Environ. Sci., 23(3), 404 (2011)
Murphy V, Hughes H, McLoughlin P, Water Res., 41(4), 731 (2007)
Lima IS, Airoldi C, Colloids Surf. A: Physicochem. Eng. Asp., 229(1-3), 129 (2003)
Davila-Guzman NE, de J. Cerino-Cordova F, Soto-Regalado E, Soto-Regalado E, Soto-Regalado JR, Diaz-Flores PE, Garza-Gonzalez MT, Loredo-Medrano JA, Clean., 41(6), 557 (2013)
Tam SK, Dusseault J, Polizu S, Menard M, Halle JP, Yahia LH, Biomaterials, 26(34), 6950 (2005)
Serra J, Gonzalez P, Liste S, Serra C, Chiussi S, Leon B, Perez-Amor M, Ylanen HO, Hupa M, J. Non-Cryst. Solids, 332(1-3), 20 (2003)
Figueira MM, Volesky B, Mathieu HJ, Environ. Sci. Technol., 33(11), 1840 (1999)
Chen J, Tendeyong F, Yiacoumi S, Environ. Sci. Technol., 31(5), 1433 (1997)
Wang FC, Zhao JM, Pan F, Zhou HC, Yang XF, Li WS, Liu HZ, Ind. Eng. Chem. Res., 52(9), 3453 (2013)
Choi JW, Yang KS, Kim DJ, Lee CE, Curr. Appl. Phys., 9(3), 694 (2009)
Park HG, Kim TW, Chae MY, Yoo IK, Process Biochem., 42(10), 1371 (2007)
Luna-Lopez JA, Carrillo-Lopez J, Aceves-Mijares M, Morales-Sanchez A, Falcony C, Superficies y Vacio, 22(1), 11 (2009)
Al-Oweini R, El-Rassy H, J. Mol. Struct., 919(1-3), 140 (2009)
Torres E, Mata YN, Blazquez AL, Munoz JA, Gonzalez F, Ballester A, Langmuir, 21(17), 7951 (2005)
Lim SF, Zheng YM, Zou SW, Chen JP, Environ. Sci. Technol., 42(7), 2551 (2008)
Fourest E, Volesky B, Environ. Sci. Technol., 30(1), 277 (1996)
Yalcin S, Clean., 42(3), 251 (2014)
Kleinubing SJ, Vieira RS, Beppu MM, Guibal E, da Silva MGC, Mat. Res, 13(4), 541 (2010)
Broderick E, Lyons H, Pembroke T, Byrne H, Murray B, Hall M, J. Colloid Interface Sci., 298(1), 154 (2006)
Czanderna AW, King DE, Spaulding D, J. Vac. Sci. Technol. A, 9(5), 2607 (1991)
Papageorgiou SK, Katsaros FK, Kouvelos EP, Nolan JW, Le Deit H, Kanellopoulos NK, J. Hazard. Mater., 137(3), 1765 (2006)
Chen JP, Hong LA, Wu SN, Wang L, Langmuir, 18(24), 9413 (2002)
Sheng PX, Ting YP, Chen JP, Hong L, J. Colloid Interface Sci., 275(1), 131 (2004)
Cheng X, Guan H, Su Y, J. Inorg. Organomet. Polym., 10(3), 115 (2000)
Figueira MM, Volesky B, Ciminelli VST, Roddick FA, Water Res., 34(1), 196 (2000)
Haug A, Acta. Chem. Scand., 15(8), 1794 (1961)
Jeon C, Park JY, Yoo YJ, Water Res., 36(7), 1814 (2002)
Rengaraj S, Yeon JW, Kim Y, Jung Y, Ha YK, Kim WH, J. Hazard. Mater., 143(1-2), 469 (2007)
Masel RI, Principles of Adsorption and Reaction on Solid Surfaces, Wiley-Interscience, New York (1996).
Sposito G, Soil Sci. Soc. Am. J., 46(6), 1147 (1982)
Wase J, Foster CF, Biosorbents for Metal Ions, Taylor & Francis Ltd., London, United Kingdom (1997).
