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Received October 21, 2014
Accepted April 18, 2015
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Absorption of carbon dioxide in aqueous solutions of imidazolium ionic liquids with carboxylate anions
Stefan Baj1 2
Tomasz Krawczyk1 3†
Aleksandra Dąbrowska1 3
Agnieszka Siewniak1 3
Aleksander Sobolewski2
1Department of Chemical Organic Technology and Petrochemistry, Faculty of Chemistry, Silesian University of Technology, Krzywoustego 4, 44-100 Gliwice, Poland 2Institute for Chemical Processing of Coal, Zabrze, Poland 3, Poland
Korean Journal of Chemical Engineering, November 2015, 32(11), 2295-2299(5), 10.1007/s11814-015-0082-2
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Abstract
.The solubility of carbon dioxide at atmospheric pressure in aqueous mixtures of 1,3-alkyl substituted imidazolium ionic liquids (ILs) containing carboxylic anions was studied. The ILs showed increased solubility of CO2 with decreasing water concentration. The relationship between the CO2 concentration in solution and the mole fraction of water in the ILs describes a sigmoidal curve. The regression constants of a logistic function were used to quantitatively assess the absorbent capacity and the effect of water on CO2 absorption. ILs containing the most basic anions, such as pivalate, propionate and acetate, had the best properties. It was observed that the impact of water on absorption primarily depended on the cation structure. The best absorption performance was observed for 1,3-dibutylimidazolium pivalate and 1-butyl-3-methyl imidazolium acetate.
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