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Received January 3, 2015
Accepted May 16, 2015
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Surface modification of poly(vinylidene fluoride) membrane with hydrophilic and anti-fouling performance via a two-step polymerization
School of Chemical and Environmental Engineering, Shanghai Institute of Technology, 100 Haiquan Road, Shanghai 201418, China 1State Key Laboratory of Chemical Engineering, Membrane Science and Engineering R&D Lab., Chemical Engineering Research Center, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China
chemxuzl@ecust.edu.cn
Korean Journal of Chemical Engineering, December 2015, 32(12), 2492-2500(9), 10.1007/s11814-015-0105-z
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Abstract
The surface modification of poly (vinylidene fluoride) (PVDF) membrane was performed via a two-step polymerization reactions. Poly (acrylic acid) (PAAc) was first grafted onto the membrane surface for the preparation of PVDF-g-PAAc membrane, and then poly (ethylene glycol) 200 (PEG 200) was immobilized on the membrane surface by the esterification reaction for the fabrication of PVDF-g-PEGA membrane. Attenuated total reflectance (ATR) FTIR, X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), and protein adsorption, water flux, water content and dynamic contact angle were conducted to characterize the structures and performance of the resultant PVDF membranes. The experimental results showed that the adsorption of bovine serum albumin (BSA) on the PVDF-g-PEGA membrane decreased about 80% when the grafting ratio reached to 15 wt%, compared with the pristine PVDF membrane. Moreover, the water contact angle of the membrane dropped to 60.5o, while the membrane pore sizes remained little changed.
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