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Received February 10, 2015
Accepted April 23, 2015
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Micro- and mesoporous CuBTCs for CO2/CH4 separation
Hyung Chul Yoon
Phani Brahma Somayajulu Rallapalli
Sang Sup Han
Hee Tae Beum
Tae Sung Jung
Dong Woo Cho
Minsu Ko1
Jong-Nam Kim†
Petroleum and Gas Laboratory, Korea Institute of Energy Research, Daejeon 305-343, Korea 1Oil & Gas Process R&D Part, Central Research Institute, Samsung Heavy Industries Co., LTD., Seongnami-si 463-400, Korea
jnkim@kier.re.kr
Korean Journal of Chemical Engineering, December 2015, 32(12), 2501-2506(6), 10.1007/s11814-015-0088-9
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Abstract
Micro- and mesoporous CuBTCs, referred to as micro- and meso-CuBTCs, were synthesized, and tested for their capacity to adsorptively remove CO2 from a binary mixture of CO2-CH4. Physicochemical analyses of the thermally treated Cu-BTCs were performed. The CO2 and CH4 adsorption isotherms for the Cu-BTCs at 25 oC in the pressure range 0-3MPa were experimentally measured and implemented for calculating the CO2/CH4 selectivity as a function of pressure and CO2 concentration using the ideal adsorbed solution theory (IAST). The CH4 adsorption capacity of meso-CuBTC at 3MPa was reduced to 43% of that of micro-CuBTC, whereas the CO2 adsorption capacity of meso-CuBTC at 3MPa was reduced to 27% of that of micro-CuBTCs. Consequently, meso-CuBTC shows a higher CO2/CH4 selectivity compared to micro-CuBTC. It was also found that the selectivity of the CuBTCs could be enhanced by lowering the partial pressure of CO2. This was ascribed to the larger abatement of the adsorption capacity for CH4 than for CO2, resulting from a reduction of the interaction of CH4 with the surface of pores of meso-CuBTC of which the pore size had been augmented.
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Veselovskaya JV, Derevschikov VS, Kardash TY, Stonkus OA, Trubitsina TA, Okunev AG, Int. J. Greenh. Gas Control, 17, 332 (2013)
Sircar S, Golden TC, Rao MB, Carbon, 34, 1 (1996)
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Plaza MG, Pevida C, Arenillas A, Rubiera F, Pis JJ, Fuel, 86(14), 2204 (2007)
Alesi WR, Kitchin JR, Ind. Eng. Chem. Res., 51(19), 6907 (2012)
Maghsoudi H, Soltanieh M, Bozorgzadeh H, Mohamadalizadeh A, Adsorption, 19, 1045 (2013)
Zhang J, Singh R, Webley PA, Microporous Mesoporous Mater., 111, 478 (2008)
Cavenati S, Grande CA, Rodrigues AE, J. Chem. Eng. Data, 49(4), 1095 (2004)
Belmabkhout Y, De Weireld G, Sayari A, Langmuir, 25(23), 13275 (2009)
Franchi RS, Harlick PJE, Sayari A, Ind. Eng. Chem. Res., 44(21), 8007 (2005)
Ma XL, Wang XX, Song CS, J. Am. Chem. Soc., 131(16), 5777 (2009)
Yong Z, Mata V, Rodrigues AE, Sep. Purif. Technol., 26(2-3), 195 (2002)
Kato M, Yoshikawa S, Nakagawa K, J. Mater. Sci. Lett., 21(6), 485 (2002)
Nakagawa K, Ohashi T, J. Electrochem. Soc., 145(4), 1344 (1998)
Chatti R, Bansiwal AK, Thote JA, Kumar V, Jadhav P, Lokhande SK, Biniwale RB, Labhsetwar NK, Rayalu SS, Microporous Mesoporous Mater., 121, 84 (2009)
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Leal O, Bolivar C, Ovalles C, Garcia JJ, Espidel Y, Inorg. Chim. Acta., 240, 183 (1995)
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Mueller U, Schubert M, Teich F, Puetter H, Schierle-Arndt K, Pastre J, J. Mater. Chem., 16, 626 (2006)
Li JR, Kuppler RJ, Zhou HC, Chem. Soc. Rev., 38, 1477 (2009)
Kuppler RJ, Timmons DJ, Fang QR, Li JR, Makal TA, Young MD, Yuan D, Zhao D, Zhuang W, Zhou HC, Coord. Chem. Rev., 253, 3042 (2009)
Bae YS, Farha OK, Spokoyny AM, Mirkin CA, Hupp JT, Snurr RQ, Chem. Commun., 4135 (2008)
Bae YS, Mulfort KL, Frost H, Ryan P, Punnathanam S, Broadbelt LJ, Hupp JT, Snurr RQ, Langmuir, 24(16), 8592 (2008)
Menon VC, Komarneni S, J. Porous Mat., 5, 43 (1998)
Czaja AU, Trukhan N, Muller U, Chem. Soc. Rev., 38, 1284 (2009)
Chui SSY, Lo SMF, Charmant JPH, Orpen AG, Williams ID, Science, 283(5405), 1148 (1999)
Wang QM, Shen D, Bulow M, Lau ML, Deng S, Fitch FR, Lemcoff NO, Semanscin J, Microporous Mesoporous Mater., 55, 217 (2002)
Liang ZJ, Marshall M, Chaffee AL, Energy Fuels, 23, 2785 (2009)
Garcia-Perez E, Gascon J, Morales-Florez V, Castillo JM, Kapteijn F, Calero S, Langmuir, 25(3), 1725 (2009)
Millward AR, Yaghi OM, J. Am. Chem. Soc., 127(51), 17998 (2005)
Farrusseng D, Daniel C, Gaudillere C, Ravon U, Schuurman Y, Mirodatos C, Dubbeldam D, Frost H, Snurr RQ, Langmuir, 25(13), 7383 (2009)
Yazaydın AO, Benin AI, Faheem SA, Jakubczak P, Low JJ, Willis RR, Snurr RQ, Chem. Mater., 21, 1425 (2009)
Cavenati S, Grande CA, Rodrigues AE, Ind. Eng. Chem. Res., 47(16), 6333 (2008)
Senkovska I, Kaskel S, Microporous Mesoporous Mater., 112, 108 (2008)
Chowdhury P, Bikkina C, Meister D, Dreisbach F, Gumma S, Microporous Mesoporous Mater., 117, 406 (2009)
Cheng Y, Kondo A, Noguchi H, Kajiro H, Urita K, Ohba T, Kaneko K, Kanoh H, Langmuir, 25(8), 4510 (2009)
Babarao R, Jiang J, Sandler SI, Langmuir, 25, 5239 (2008)
Yang QY, Zhong CL, J. Phys. Chem. B, 110(36), 17776 (2006)
Martin-Calvo A, Garcia-Perez E, Castillo JM, Calero S, Phys. Chem. Chem. Phys., 10, 7085 (2008)
Krishna R, J. Phys. Chem. C, 113, 19756 (2009)
Keskin S, Liu J, Johnson JK, Sholl DS, Microporous Mesoporous Mater., 125, 101 (2009)
Hamon L, Jolimaitre E, Pirngruber GD, Ind. Eng. Chem. Res., 49(16), 7497 (2010)
Qiu LG, Xu T, Li ZQ, Wang W, Wu Y, Jiang X, Tian XY, Zhang LD, Angew. Chem.-Int. Edit., 47, 9487 (2008)
Chapman KW, Halder GJ, Chupas PJ, J. Am. Chem. Soc., 130(32), 10524 (2008)
Myers AL, Prausnitz JM, AIChE J., 11, 121 (1965)
Krishna R, Long JR, J. Phys. Chem. C, 115, 12941 (2011)
Ryan P, Farha OK, Broadbelt LJ, Snurr RQ, AIChE J., 57(7), 1759 (2011)
Zhang Z, Liu J, Li Z, Li J, J. Chem. Soc.-Dalton Trans., 41, 4232 (2012)
