Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received March 4, 2014
Accepted July 1, 2014
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Quaternary Pt2Ru1Fe1M1/C (M=Ni, Mo, or W) catalysts for methanol electro-oxidation reaction
Nuclear Fuel Cycle Process Development Division, Korea Atomic Energy Research Institute, Daedeok-daero 989-111, Yuseong-gu, Daejeon 305-353, Korea 1Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan 2Department of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, IN 46556, USA
minku@kaeri.re.kr
Korean Journal of Chemical Engineering, February 2015, 32(2), 206-215(10), 10.1007/s11814-014-0186-0
Download PDF
Abstract
Quaternary Pt2Ru1Fe1M1/C (M=Ni, Mo, or W) catalysts were investigated for the methanol electro-oxidation reaction (MOR). Electrocatalytic activities of the quaternary catalysts for CO electro-oxidation were studied via CO stripping experiments, and the Pt2Ru1Fe1Ni1/C and Pt2Ru1Fe1W1/C catalysts exhibited lowered on-set potential compared to that of a commercial PtRu/C catalyst. MOR activities of the quaternary catalysts were determined by linear_x000D_
sweep voltammetry (LSV) experiments, and the Pt2Ru1Fe1W1/C catalyst outperformed the commercial PtRu/C catalyst by 170 and 150% for the mass and specific activities, respectively. X-ray photoelectron spectroscopy (XPS) was employed to analyze surface oxidation states of constituent atoms, and it was identified that the structure of the synthesized catalysts are close to a nano-composite of Pt and constituent metal hydroxides and oxides. In addition, the XPS results suggested that the bi-functional mechanism accounts for the improved performance of the Pt2Ru1Fe1Ni1/C and Pt2Ru1 Fe1W1/C catalysts.
Keywords
References
Arico AS, Srinivasan S, Antonucci V, Fuel Cells, 1, 133 (2001)
Watanabe M, Motoo S, J. Electroanal. Chem., 229, 395 (1987)
Markovic NM, Gasteiger HA, Ross PN, Jiang XD, Villegas I, Weaver MJ, Electrochim. Acta, 40(1), 91 (1995)
Chrzanowski W, Wieckowski A, Langmuir, 14(8), 1967 (1998)
Petrii OA, J. Solid State Electrochem., 12, 609 (2008)
Choi JH, Park KW, Kwon BK, Sung YE, J. Electrochem. Soc., 150, 973 (2003)
Wang ZB, Yin GP, Shi PF, Sun YC, Electrochem. Solid-State Lett., 9, 13 (2006)
Liu JY, Cao JY, Huang QH, Li XW, Zou ZQ, Yang H, J. Power Sources, 175(1), 159 (2008)
Ribeiro VA, Correa OV, Neto AO, Linardi M, Spinace EV, Appl. Catal. A: Gen., 372(2), 162 (2010)
Jeon MK, Lee KR, Daimon H, Nakahara A, Woo SI, Catal. Today, 132(1-4), 123 (2008)
Cooper JS, McGinn PJ, J. Power Sources, 163(1), 330 (2006)
Lima A, Coutanceau C, Leger JM, Lamy C, J. Appl. Electrochem., 31(4), 379 (2001)
Umeda M, Ojima H, Mohamedi M, Uchida I, J. Power Sources, 136(1), 10 (2004)
Goetz M, Wendt H, J. Appl. Electrochem., 31(7), 811 (2001)
Roth C, Goetz M, Fuess H, J. Appl. Electrochem., 31(7), 793 (2001)
Antolini E, Appl. Catal. B: Environ., 74(3-4), 324 (2007)
Lamy C, Lima A, LeRhun V, Delime F, Coutanceau C, Leger JM, J. Power Sources, 105(2), 283 (2002)
Demirci UB, J. Power Sources, 173(1), 11 (2007)
Ralph TR, Hogarth MP, Platin. Met. Rev., 46, 3 (2002)
Urian RC, Gulla AF, Mukerjee S, J. Electroanal. Chem., 554, 307 (2003)
Lopes PP, Feitas KS, Ticianelli EA, Electrocatal., 1, 200 (2010)
Ehteshami SMM, Chan SH, Electrochim. Acta, 93, 334 (2013)
Jeon MK, Won JY, Lee KR, Woo SI, Electrochem. Commun., 9, 2163 (2007)
Lee KR, Jeon MK, Woo SI, Appl. Catal. B: Environ., 91(1-2), 428 (2009)
Schmidt TJ, Gasteiger HA, Stab GD, Urban PM, Kolb DM, Behm RJ, J. Electrochem. Soc., 145(7), 2354 (1998)
Antolini E, Cardellini F, J. Alloys Compd., 315, 118 (2001)
Watanabe K, Trans. Jpn. Inst. Met., 29, 80 (1988)
Leroux C, Cadeville MC, Pierron-Bohnes V, Inden G, Hinz F, J. Phys. F: Met. Phys., 18, 2033 (1988)
Raub E, Mahler W, Z. Metallkd., 46, 210 (1955)
Luo HL, J. Less Common Met., 156, 299 (1968)
Rolison DR, Hagans PL, Swider KE, Long JW, Langmuir, 15(3), 774 (1999)
Long JW, Stroud RM, Swider-Lyons KE, Rolison DR, J. Phys. Chem. B, 104(42), 9772 (2000)
Jeon MK, Lee KR, Jeon HJ, Woo SI, J. Appl. Electrochem., 39(9), 1503 (2009)
He CZ, Kunz HR, Fenton JM, J. Electrochem. Soc., 144(3), 970 (1997)
Jeon MK, Daimon H, Lee KR, Nakahara A, Woo SI, Electrochem. Commun., 9, 2692 (2007)
Camara GA, Giz MJ, Paganin VA, Ticianelli EA, J. Electroanal. Chem., 537(1-2), 21 (2002)
Kwok RWM, XPS peak fitting program for WIN95/98 XPSPEAK version 4.1, Department of Chemistry, The Chinese University of Hong Kong, Shatin, Hong Kong (2000)
Watanabe M, Igarashi H, Fujino T, Electrochem., 6, 1194 (1999)
Watanabe M, Zhu YM, Uchida H, J. Phys. Chem. B, 104(8), 1762 (2000)
Jeon MK, Won JY, Woo SI, Electrochem. Solid-State Lett., 10, 23 (2007)
Kennedy BJ, Smith AW, J. Electroanal. Chem., 293, 103 (1990)
Roine A, Outokumpu HSC chemistry for windows, Pori, Finland (2002)
Manoharan R, Goodenough GB, J. Mater. Chem., 2, 875 (1992)
Park KW, Choi JH, Kwon BK, Lee SA, Sung YE, Ha HY, Hong SA, Kim H, Wieckowski A, J. Phys. Chem. B, 106(8), 1869 (2002)
Tsiouvaras N, Pena MA, Fierro JLG, Pastor E, Martinez-Huerta MV, Catal. Today, 158(1-2), 12 (2010)
Ioroi T, Yasuda K, Siroma Z, Fujiwara N, Miyazaki Y, J. Electrochem. Soc., 150, 1225 (2003)
Liu Z, Hu JE, Wang Q, Gaskell K, Frenkel AI, Jackson GS, Eichhorn B, J. Am. Chem. Soc., 131(20), 6924 (2009)
Ma LA, Zhao XA, Si FZ, Liu CP, Liao JH, Liang LA, Xing W, Electrochim. Acta, 55(28), 9105 (2010)
Teliz E, Diaz V, Perez I, Corengia M, Zinola CF, Int. J. Hydrog. Energy, 37(19), 14761 (2012)
Jeon MK, Lee KR, Woo SI, Korean J. Chem. Eng., 26(4), 1028 (2009)
Wang ZB, Zuo PJ, Yin GP, J. Alloys Compd., 479, 395 (2009)
Micoud F, Maillard F, Bonnefont A, Job N, Chatenet M, Phys. Chem. Chem. Phys., 12, 1182 (2010)
Watanabe M, Motoo S, J. Electroanal. Chem., 229, 395 (1987)
Markovic NM, Gasteiger HA, Ross PN, Jiang XD, Villegas I, Weaver MJ, Electrochim. Acta, 40(1), 91 (1995)
Chrzanowski W, Wieckowski A, Langmuir, 14(8), 1967 (1998)
Petrii OA, J. Solid State Electrochem., 12, 609 (2008)
Choi JH, Park KW, Kwon BK, Sung YE, J. Electrochem. Soc., 150, 973 (2003)
Wang ZB, Yin GP, Shi PF, Sun YC, Electrochem. Solid-State Lett., 9, 13 (2006)
Liu JY, Cao JY, Huang QH, Li XW, Zou ZQ, Yang H, J. Power Sources, 175(1), 159 (2008)
Ribeiro VA, Correa OV, Neto AO, Linardi M, Spinace EV, Appl. Catal. A: Gen., 372(2), 162 (2010)
Jeon MK, Lee KR, Daimon H, Nakahara A, Woo SI, Catal. Today, 132(1-4), 123 (2008)
Cooper JS, McGinn PJ, J. Power Sources, 163(1), 330 (2006)
Lima A, Coutanceau C, Leger JM, Lamy C, J. Appl. Electrochem., 31(4), 379 (2001)
Umeda M, Ojima H, Mohamedi M, Uchida I, J. Power Sources, 136(1), 10 (2004)
Goetz M, Wendt H, J. Appl. Electrochem., 31(7), 811 (2001)
Roth C, Goetz M, Fuess H, J. Appl. Electrochem., 31(7), 793 (2001)
Antolini E, Appl. Catal. B: Environ., 74(3-4), 324 (2007)
Lamy C, Lima A, LeRhun V, Delime F, Coutanceau C, Leger JM, J. Power Sources, 105(2), 283 (2002)
Demirci UB, J. Power Sources, 173(1), 11 (2007)
Ralph TR, Hogarth MP, Platin. Met. Rev., 46, 3 (2002)
Urian RC, Gulla AF, Mukerjee S, J. Electroanal. Chem., 554, 307 (2003)
Lopes PP, Feitas KS, Ticianelli EA, Electrocatal., 1, 200 (2010)
Ehteshami SMM, Chan SH, Electrochim. Acta, 93, 334 (2013)
Jeon MK, Won JY, Lee KR, Woo SI, Electrochem. Commun., 9, 2163 (2007)
Lee KR, Jeon MK, Woo SI, Appl. Catal. B: Environ., 91(1-2), 428 (2009)
Schmidt TJ, Gasteiger HA, Stab GD, Urban PM, Kolb DM, Behm RJ, J. Electrochem. Soc., 145(7), 2354 (1998)
Antolini E, Cardellini F, J. Alloys Compd., 315, 118 (2001)
Watanabe K, Trans. Jpn. Inst. Met., 29, 80 (1988)
Leroux C, Cadeville MC, Pierron-Bohnes V, Inden G, Hinz F, J. Phys. F: Met. Phys., 18, 2033 (1988)
Raub E, Mahler W, Z. Metallkd., 46, 210 (1955)
Luo HL, J. Less Common Met., 156, 299 (1968)
Rolison DR, Hagans PL, Swider KE, Long JW, Langmuir, 15(3), 774 (1999)
Long JW, Stroud RM, Swider-Lyons KE, Rolison DR, J. Phys. Chem. B, 104(42), 9772 (2000)
Jeon MK, Lee KR, Jeon HJ, Woo SI, J. Appl. Electrochem., 39(9), 1503 (2009)
He CZ, Kunz HR, Fenton JM, J. Electrochem. Soc., 144(3), 970 (1997)
Jeon MK, Daimon H, Lee KR, Nakahara A, Woo SI, Electrochem. Commun., 9, 2692 (2007)
Camara GA, Giz MJ, Paganin VA, Ticianelli EA, J. Electroanal. Chem., 537(1-2), 21 (2002)
Kwok RWM, XPS peak fitting program for WIN95/98 XPSPEAK version 4.1, Department of Chemistry, The Chinese University of Hong Kong, Shatin, Hong Kong (2000)
Watanabe M, Igarashi H, Fujino T, Electrochem., 6, 1194 (1999)
Watanabe M, Zhu YM, Uchida H, J. Phys. Chem. B, 104(8), 1762 (2000)
Jeon MK, Won JY, Woo SI, Electrochem. Solid-State Lett., 10, 23 (2007)
Kennedy BJ, Smith AW, J. Electroanal. Chem., 293, 103 (1990)
Roine A, Outokumpu HSC chemistry for windows, Pori, Finland (2002)
Manoharan R, Goodenough GB, J. Mater. Chem., 2, 875 (1992)
Park KW, Choi JH, Kwon BK, Lee SA, Sung YE, Ha HY, Hong SA, Kim H, Wieckowski A, J. Phys. Chem. B, 106(8), 1869 (2002)
Tsiouvaras N, Pena MA, Fierro JLG, Pastor E, Martinez-Huerta MV, Catal. Today, 158(1-2), 12 (2010)
Ioroi T, Yasuda K, Siroma Z, Fujiwara N, Miyazaki Y, J. Electrochem. Soc., 150, 1225 (2003)
Liu Z, Hu JE, Wang Q, Gaskell K, Frenkel AI, Jackson GS, Eichhorn B, J. Am. Chem. Soc., 131(20), 6924 (2009)
Ma LA, Zhao XA, Si FZ, Liu CP, Liao JH, Liang LA, Xing W, Electrochim. Acta, 55(28), 9105 (2010)
Teliz E, Diaz V, Perez I, Corengia M, Zinola CF, Int. J. Hydrog. Energy, 37(19), 14761 (2012)
Jeon MK, Lee KR, Woo SI, Korean J. Chem. Eng., 26(4), 1028 (2009)
Wang ZB, Zuo PJ, Yin GP, J. Alloys Compd., 479, 395 (2009)
Micoud F, Maillard F, Bonnefont A, Job N, Chatenet M, Phys. Chem. Chem. Phys., 12, 1182 (2010)
