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Received December 16, 2013
Accepted August 19, 2014
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Catalytic ozonation of methylene blue in aqueous solution by loading transition metal(Co/Cu/Fe/Mn) on carbon
Key Laboratory of Catalysis and Materials Science of Hubei Province, College of Chemical and Material Science, South-Central University for Nationalities, Wuhan, Hubei Province 430074, P. R. China 1State Key Laboratory of Urban and Regional Ecology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China, Korea
wuguiping75@hotmail.com
Korean Journal of Chemical Engineering, February 2015, 32(2), 268-273(6), 10.1007/s11814-014-0238-5
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Abstract
Activated carbon(AC) was prepared using brewing yeast as a precursor by chemical activation; meanwhile, cobalt, copper, ferrum and manganese supported on activated carbon(Co/AC, Cu/AC, Fe/AC, Mn/AC) were prepared by adsorption-activation method. The characterizations of prepared AC, Co/AC, Cu/AC, Fe/AC, Mn/AC and their performance as ozonation catalysts were tested. The total BET surface areas of prepared AC, Co/AC, Cu/AC, Fe/AC, Mn/AC were found to be 957.7, 789.7, 485.3, 486.1 and 529.8m2/g. Absorption capacities of methylene blue (MB) were determined to 407.77, 206.52, 121.25, 123.01, 170.94mg/g, respectively. The presence of AC was advantageous for TOC reduction of MB compared with UV/O3 system, and metal Co, Cu, Fe, Mn play an important role in the degradation process. The greatest TOC removal efficiency was obtained in the presence of Co/AC.
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Danon A, Stair PC, Weitz E, J. Phys. Chem. C, 115, 11540 (2011)
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Singh SP, Chakradhar RPS, Rao JL, Karmakar B, J. Alloys Compd., 493, 256 (2010)
Yan J, Wei T, Qiao WM, Shao B, Zhao QK, Zhang LJ, Fan ZJ, Electrochim. Acta, 55(23), 6973 (2010)
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Tan IAW, Hameed BH, Ahmad AL, Chem. Eng. J., 127(1-3), 111 (2007)
Chandra TC, Mirna MM, Sudaryanto Y, Ismadji S, Chem. Eng. J., 127(1-3), 121 (2007)
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Reddy KSK, Al Shoaibi A, Srinivasakannan C, New Carbon Mater., 27, 344 (2012)
Foo KY, Hameed BH, Bioresour. Technol., 104, 679 (2012)
Tsai WT, Chang CY, Lin MC, Chien SF, Sun HF, Hsieh MF, Chemosphere, 45, 51 (2001)
Hameed BH, Din ATM, Ahmad AL, J. Hazard. Mater., 141(3), 819 (2007)
Martin MJ, Artola A, Balaguer MD, Rigola M, Chem. Eng. J., 94(3), 231 (2003)
Namasivayam C, Kavitha D, Dyes Pigm., 54, 47 (2002)
Guzman-Perez CA, Soltan J, Robertson J, Sep. Purif. Technol., 79(1), 8 (2011)
Chen YH, Chang CY, Chen CC, Chiu CY, Yu YH, Chiang PC, Chang CF, Ku Y, Ind. Eng. Chem. Res., 43(9), 1932 (2004)
Staehelin J, Hoigne J, Environ. Sci. Technol., 16, 676 (1982)
