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Received February 16, 2014
Accepted July 30, 2014
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Kinetics and equilibrium studies on removal of methylene blue and methyl orange by adsorption onto activated carbon prepared from date pits-A comparative study
Laboratory of Physicochemical of Minerals Materials and its Applications, National Centre of Research in Materials Sciences (CNRSM), B.P.73-8020, Soliman, Tunisia
mahmoudikhaled1984@gmail.com
Korean Journal of Chemical Engineering, February 2015, 32(2), 274-283(10), 10.1007/s11814-014-0216-y
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Abstract
The adsorption of Methylene blue and Methyl orange by date pits carbon was carried out by varying parameters such as agitation time, pH and dye concentration. Equilibrium adsorption data followed both Langmuir and Freundlich isotherms. Adsorption followed second-order rate kinetics. The adsorption capacity was found to be 434 and 455mg of methyl orange and methylene blue, respectively, per g of the date pits carbon. Acidic pH is favorable for the_x000D_
adsorption of methyl orange against a basic medium which is favorable for the adsorption of MB. An opposite result was found for the methylene blue adsorption.
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Zollinger H, Color Chemistry, 2nd Ed., VCH, New York (1991)
Greene JC, Baughman GL, Textile Chemist Colourist, 28, 23 (1996)
Phillips DAS, J. Soc. Dyers Colourists, 112, 183 (1996)
Nguyen TA, Juang RS, Chem. Eng. J., 219, 109 (2013)
Bozdogan A, Goknil H, MU. Fen. Billimeri Dergisi. Sayi., 4, 83 (1987)
Brower GR, Reed GD, Economical pre-treatment for colour removal from textile dye wastes, In: Proc. 41st Ind waste conference, Purdue University, West Lafayette, Indiana, 612 (1985)
Majewska-Nowak K, Desalination, 71, 127 (1989)
Ding Z, Min CW, Hui WQ, Water Sci. Technol., 19, 39 (1987)
Easton JR, The dye maker’s view, In: Cooper, P., Colour in dye house effluent, Soc dyers and colorists, Oxford, Alden Press, 6 (1995)
Hassler JW, Purification withActivated Carbon, 2nd Ed., Chem. Publ. Co., Inc., New York, 171 (1963)
Gupta GS, Prasad G, Singh VN, Water Air Soil Pollut., 37, 13 (1988)
Kannan N, Sundaram MM, Dyes Pigm., 51, 25 (2001)
Kannan N, Srinivasan T, Dhandayudhapani P, Environ. Media Publishers, 291. Karad, India (1998)
Pollard SJT, Fowler GD, Sollars CJ, Perry R, Sci. Total Environ., 116, 31 (1992)
Annadurai G, Krishnan MRV, Indian J. Environ. Protec., 16, 444 (1996)
Deo N, Ali M, Indian J. Environ. Protect., 17, 328 (1997)
McKay G, Otterburn MS, Aja JA, Water Air Soil Pollut., 24, 307 (1985)
Danish M, Hashim R, Ibrahim MNM, Sulaiman O, Biomass Bioenerg., 61, 167 (2014)
Cazetta AL, Junior OP, Vargas AMM, da Silva AP, Zou X, Asefa T, Almeida VC, J. Anal. Appl. Pyrol., 101, 53 (2013)
Alslaibi TM, Abustan I, Ahmad MA, Abu Foul A, J. Environ. Chem. Eng., 1, 589 (2013)
Ashour SS, J. Saudi Chem. Soc., 14, 47 (2010)
Banat F, Al-Asheh S, Al-Makhadmeh L, Chem. Eng. Technol., 27(1), 80 (2004)
Hassan AF, Mortada WI, Hassanien MM, Inter. J. Modern Chem., 5, 101 (2013)
Asadullah M, Jahan I, Ahmed MB, Adawiyah P, Malek NH, Rahman MS, J. Ind. Eng. Chem., 20(3), 887 (2014)
Messaoudi R, Abbeddou S, Mansouri A, Calokerinos AC, Kefalas P, Int. J. Food Prop., 16, 1037 (2013)
Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Rouquerol J, Sieminiewska T, Pure Appl. Chem., 57, 603 (1985)
Boehm HP, Chemical Identification of Surface Groups, In: Eley, Pines DD, Weisz H, PB (Ed.), Advances in Catalysis 16, Academic Press, New York, 179 (1966)
Boehm HP, Carbon, 32, 759 (1944)
Papier E, Li S, Donnet JB, Carbon, 25, 243 (1987)
Milongic SK, Antonucci V, Minutoli M, Giordano N, Carbon, 27, 337 (1975)
Kannan N, Indian J. Environ. Protect., 11, 514 (1991)
Cunliffe AM, Williams PT, Environ. Technol., 19, 1177 (1998)
Al-Saidi HM, J. Saudi Chem. Soc., DOI:10.1016/j.jscs.2013.06.002.
Yakout SM, Sharaf El-Deen G, Arabian J. Chem., DOI:10.1016/j.arabjc.2011.12.002.
Gomez-Serrano V, Pastor-Viilegas J, Perez-Florindo A, Duran-Valle C, Valenzueia-Calahorro C, J. Anal. Appl. Pyrol., 36, 71 (1996)
Al-Ghouti MA, Li J, Salamh Y, Al-Laqtah N, Walker G, Ahmad MNM, J. Hazard. Mater., 176(1-3), 510 (2010)
Boehm HP, Chemical Identification of Surface Groups, In: Eley, Pines DD, Weisz H, PB (Ed.), Advances in Catalysis 16, Academic Press, New York, 179 (1966)
El-Hendawy AA, J. Anal. Appl. Pyrol., 75, 159 (2006)
Huang LH, Sun YY, Wang WL, Yue QY, Yang T, Chem. Eng. J., 171(3), 1446 (2011)
Radovic LR, Moreno-Castilla C, Rivera-Utrilla J , Carbon materials as adsorbents in aqueous solutions, In: Radovic, L.R., Ed., Chemistry and physics of carbon, Marcel Dekker, New York, 27, 227 (2001)
Pereira MFR, Soares SF, Orfao JJM, Figueiredo JL, Carbon, 41, 811 (2003)
Faria PCC, Orfao JJM, Pereira MFR, Water Res., 38, 2043 (2004)
Newcombe G, Drikas M, Carbon, 35, 1239 (1997)
Weber WJ, Physico-chemical processes for water quality control, Wiley Interscience, New York, 207 (1972)
Weber WJ, Morris JC, In: Eckenfelder, WW Ed., Advances in water pollution research, Oxford, Pergamon Press (1964)
Hall KR, Eagleton LC, Acrivos A, Vemeulen T, Ind. Eng. Chem. Fund., 5, 212 (1966)
Ozcan AS, Ozcan A, J. Colloid Interface Sci., 276(1), 39 (2004)
Langergren S, Svenska BK, Veternskapsakad Handlingar, 24, 1 (1898)
Ho YS, McKay G, Chem. Eng. J., 70(2), 115 (1998)
Malik PK, J. Hazard. Mater. B., 113, 81 (2004)
Namasivayam C, Kavitha D, Dyes Pigm., 54, 47 (2002)
El-Guendi M, Adsorpt. Sci. Technol., 8, 217 (1991)
Tsai WT, Chang CY, Lin MC, Chien SF, Sun HF, Hsieh MF, Chemosphere, 45, 51 (2001)
Weber TW, Chakkravorti RK, AIChE J., 20, 228 (1974)
Haghseresht F, Lu GQ, Energy Fuels, 12(6), 1100 (1998)
Fytianos K, Voudrias E, Kokkalis E, Chemosphere, 40, 3 (2000)
Adamson AW, Physical Chemistry of Surfaces, 5th Ed. New York, Wiley (1990)
Chen SH, Zhang J, Zhang CL, Yue QY, Li Y, Li C, Desalination, 252(1-3), 149 (2010)
Yao YJ, He B, Xu FF, Chen XF, Chem. Eng. J., 170(1), 82 (2011)
Mahmoudi K, Hamdi N, Kriaa A, Srasra E, Russ. J. Phys. Chem. A, 86, 1294 (2012)
Saha TK, Bhoumik NC, Karmaker S, Ahmed MG, Ichikawa H, Fukumori Y, J. Water Res. Prot., 2, 898 (2010)
Ni ZM, Xia SJ, Wang LG, Xing FF, Pan GX, J. Colloid Interface Sci., 316(2), 284 (2007)
Tan WS, Liang C, Carbon, 47, 1880 (2009)
Deng H, Yang L, Tao GH, Dai JL, J. Hazard. Mater., 166(2-3), 1514 (2009)
Demirbas E, Kobya M, Sulak MT, Bioresour. Technol., 99(13), 5368 (2008)
