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Received May 21, 2014
Accepted July 22, 2014
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Synthesis and characterization of ceramic/carbon nanotubes composite adsorptive membrane for copper ion removal from water
Research Centre for Membrane Separation Processes, Faculty of Chemical Engineering, Iran University of Science and Technology (IUST), Narmak, Tehran, Iran
torajmohammadi@iust.ac.ir
Korean Journal of Chemical Engineering, February 2015, 32(2), 292-298(7), 10.1007/s11814-014-0210-4
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Abstract
We prepared a novel adsorptive membrane by implanting carbon nanotubes (CNTs) in pore channels of ceramic (α-alumina) support via chemical vapor deposition (CVD) method using cyclohexanol and ferrocene as carbon precursor and catalyst, respectively. Optimization of CNTs growth conditions resulted in uniform distribution of the CNTs in the pore channels of the support. The optimized CNTs-ceramic membrane was oxidized with concentrated nitric acid, and chitosan was employed for filling intertube-CNT gaps. The modified CNTs-ceramic membrane was used for copper ion removal from water, and the effects of the modification steps (oxidation and filling intertube-CNT gaps with chitosan) and pH on permeation flux and rejection of the prepared adsorptive membrane were investigated. Moreover, static adsorption was also investigated and Langmuir and Freundlich isotherms and two kinetics models were used to describe adsorption behavior of copper ions by the prepared adsorptive membrane.
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References
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Tofighy MA, Mohammadi T, J. Hazard. Mater., 185, 140 (2011)
Rahman MS, Islam MR, Chem. Eng. J., 149(1-3), 273 (2009)
Beppu MM, Arruda EJ, Vieira RS, Santos NN, J. Membr. Sci., 240(1-2), 227 (2004)
Kang YL, Poon MY, Monash P, Ibrahim S, Saravanan P, Korean J. Chem. Eng., 30(10), 1904 (2013)
Ghaee A, Shariaty-Niassar M, Barzin J, Matsuura T, Chem. Eng. J., 165(1), 46 (2010)
Vieira RS, Guibal E, Silva EA, Beppu MM, Adsorption, 13, 603 (2007)
Salehi E, Madaeni SS, Rajabi L, Vatanpour V, Derakhshan AA, Zinadini S, Ghorabi S, Monfared HA, Sep. Purif. Technol., 89, 309 (2012)
Madaeni SS, Zinadini S, Vatanpour V, Sep. Purif. Technol., 80(1), 155 (2011)
Malkoc E, Nuhoglu Y, J. Hazard. Mater., 135(1-3), 328 (2006)
Kim YH, Lee DG, Moon DK, Byeon SH, Ahn HW, Lee CH, Korean J. Chem. Eng., 31(1), 132 (2014)
Kabay N, Bryjak M, Schlosser S, Kitis M, Avlonitis S, Matejka Z, Al-Mutaz I, Yuksel M, Desalination, 223(1-3), 38 (2008)
Smuleac V, Bachas L, Bhattacharyya D, J. Membr. Sci., 346(2), 310 (2010)
Li YH, Wang S, Luan Z, Ding J, Xu C, Wu D, Carbon, 41, 1057 (2003)
Li YH, Wang SG, Wei JQ, Zhang XF, Xu CL, Luan ZK, Wu DH, Wei BQ, Chem. Phys. Lett., 357(3-4), 263 (2002)
Lu CY, Chiu HS, Chem. Eng. Sci., 61(4), 1138 (2006)
Lu CS, Chiu H, Liu CT, Ind. Eng. Chem. Res., 45(8), 2850 (2006)
Lu CY, Liu CT, J. Chem. Technol. Biotechnol., 81(12), 1932 (2006)
Kandah MI, Meunier JL, J. Hazard. Mater., 146(1-2), 283 (2007)
Pyrzynska K, Anal. Sci., 23, 631 (2007)
Li YH, Wang SG, Zhang XF, Wei JQ, Xu CL, Luan ZK, Wu DH, Mater. Res. Bull., 38(3), 469 (2003)
Peng XJ, Li YH, Luan ZK, Di ZC, Wang HY, Tian BH, Jia ZP, Chem. Phys. Lett., 376(1-2), 154 (2003)
Lu C, Chung YL, Chang KF, Water Res., 39, 1183 (2005)
Pyrzynska K, Sep. Purif. Rev., 37, 375 (2008)
Yang ST, Li JX, Shao DD, Hu J, Wang XK, J. Hazard. Mater., 166(1), 109 (2009)
Salehi E, Madaeni SS, Rajabi L, Derakhshan AA, Daraei S, Vatanpour V, Chem. Eng. J., 215, 791 (2013)
Vieira RS, Beppu MM, Adsorption, 11, 731 (2005)
Beppu MM, Arruda EJ, Vieira RS, Santos NN, J. Membr. Sci., 240(1-2), 227 (2004)
Ghaee A, Shariaty-Niassar M, Barzin J, Matsuura T, Chem. Eng. J., 165(1), 46 (2010)
Vieira RS, Guibal E, Silva EA, Beppu MM, Adsorption, 13, 603 (2007)
Pillai CKS, Paul W, Sharma CP, Prog. Polym. Sci., 34, 641 (2009)
Tofighy MA, Mohammadi T, Desalination, 258(1-3), 182 (2010)
Mohammadi T, Tofighy MA, Pak A, Int. J. Chem. React. Eng., 7, 75 (2009)
Johns IB, McElhill EA, Smith JO, J. Chem. Eng. Data, 7, 277 (1962)
Rao GP, Lu C, Su F, Sep. Purif. Technol., 58(1), 224 (2007)
Chen SM, Shen WM, Wu GZ, Chen DY, Jiang M, Chem. Phys. Lett., 402(4-6), 312 (2005)
Yan YH, Cui J, Chan-Park MB, Wang X, Wu QY, Nanotechnology, 18, 115712 (2007)
Wang JP, Ma XX, Fang GZ, Pan MF, Ye XK, Wang S, J. Hazard. Mater., 186(2-3), 1985 (2011)
Vukovic GD, Marinkovic AD, Colic M, Ristic MD, Aleksic R, Peric-Grujic AA, Uskokovic PS, Chem. Eng. J., 157(1), 238 (2010)
Smith RM, Martell AE, Vol. 4, Plenum, New York (1980)
Tan X, Fang M, Chen C, Yu S, Wang X, Carbon, 46, 1741 (2008)
Jiang MQ, Wang QP, Jin XY, Chen ZL, J. Hazard. Mater., 170(1), 332 (2009)
Di ZC, Ding J, Peng XJ, Li YH, Luan ZK, Liang J, Chemosphere, 62, 861 (2006)
Zou W, Han R, Chen Z, Jinghua Z, Shi J, Colloids Surf., A: Physicochem. Eng. Aspects, 279(1-2), 238 (2006)
Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
Figaro S, Avril JR, Brouers F, Ouensanga A, Gaspard S, J. Hazard. Mater., 161(2-3), 649 (2009)
