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Received December 15, 2013
Accepted August 12, 2014
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Binary mixtures of cationic surfactants with triton X-100 and the studies of physicochemical parameters of the mixed micelles
Department of Chemistry, Semnan University, P. O. Box 35131-19111, Semnan, Iran 1Department of Chemical Engineering, Faculty of Engineering, Arak University, Arak, Iran
abagheri@profs.semnan.ac.ir, Bagheri.alm@gmail.com
Korean Journal of Chemical Engineering, February 2015, 32(2), 308-315(8), 10.1007/s11814-014-0232-y
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Abstract
The mixtures of alkylpyridinium chloride (CnPC, n=14, 16) and Triton X-100 were studied over the entire mole fractions at 298.15 K. For each mixture, CMC was obtained from surface tension measurements. To estimate the interaction parameter values (β), the calculation of the monomer concentrations and the mole fractions of the individual surfactants in the mixed micelles, the CMC data were used by applying the regular solution theory. The obtained results showed that the increase of the chain length of CnPC led to the stronger preferential incorporation of cationic_x000D_
surfactant in mixed micelle. The large values of |ΔGo| confirmed that mixed micelle of C16PC and Triton X-100 was significantly favorable.
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Holland PM, Rubingh DN, J. Phys. Chem., 87, 1984 (1983)
Bergstrom M, Eriksson JC, Langmuir, 16(18), 7173 (2000)
Bergstrom M, Langmuir, 17(4), 993 (2001)
Olea AF, Gamboa C, J. Colloid Interface Sci., 257(2), 321 (2003)
Rosen MJ, Surfactants and interfacial phenomena, Wiley, New York (1989)
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Rubingh DN, Mittal KL, In Solution Chemistry of Surfactants, 1, 337 (1979)
Holland PM, Adv. Colloid Interface Sci., 26, 111 (1986)
Maeda H, J. Colloid Interface Sci., 172(1), 98 (1995)
Clint JH, J. Chem. Soc. Faraday Trans., 71, 1327 (1975)
Rafati AA, Maleki H, J. Mol. Liq., 135, 128 (2007)
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Slagle AR, PhD Thesis, University of Oklahoma, USA (1998)
Munster A, Statistical Thermodynamics, Springer-Verlag, Berlin (1974)
Holland PM, Modeling mixed surfactant systems, ACS Symposium Series; Chapter 2. American Chemical Society, Washington, DC (1992)
Rosen MJ, Hua XY, J. Colloid Interface Sci., 86, 164 (1982)
Bergstrom M, Eriksson JC, Langmuir, 16(18), 7173 (2000)
Bergstrom M, Langmuir, 17(4), 993 (2001)
Rub MA, Asiri AM, Azum N, Kabir-ud-Din, J. Ind. Eng. Chem., DOI:10.1016/j.jiec.2013.09.027. (2013)
Rub MA, Sheikh MS, Asiri AM, Azum N, Khan A, Khan AAP, Khan SB, Kabir-ud-Din, J. Chem. Thermodyn., 64, 28 (2013)
Rub MA, Asiri AM, Naqvi AZ, Rahman MM, Khan SB, Kabir-ud-Din, J. Mol. Liq., 177, 19 (2013)
Zhou Q, Rosen MJ, Langmuir, 19(11), 4555 (2003)
Otto M, Chemometrics: Statistics and computer application in analytical chemistry, Weinheim, WILEY-VCH (2007)
Sarmoria C, Puvvada S, Blankschtein D, Langmuir, 8, 2690 (1992)
Cox DR, Hinkley DV, Theoretical Statistics, Chapman & Hall, London (1974)
Razavizadeh BM, Mousavi-Khoshdel A, Gharibi H, Behjatmanesh-Ardakani R, Javadian S, Sohrabi B, J. Colloid Interface Sci., 276(1), 197 (2004)
Palepu R, Gharibi H, Bloor DM, Wyn-Jones E, Langmuir, 9, 110 (1993)
Patil RS, Buchavzov N, Careya E, Stubenrauch C, Soft Matter, 4, 840 (2008)
Danov KD, Kralchevska SD, Kralchevsky PA, Ananthapadmanabhan KP, Lips A, Langmuir, 20(13), 5445 (2004)
Ikeda S, Tsunoda M, Maeda H, J. Colloid Interface Sci., 67, 336 (1987)
