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Received March 15, 2014
Accepted August 24, 2014
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Electrochemical characterization of mixed matrix heterogeneous cation exchange membranes modified by simultaneous using ilmenite-co-iron oxide nanoparticles
Department of Chemical Engineering, Faculty of Engineering, Arak University, Arak 38156-8-8349, Iran 1Membrane Research Centre, Department of Chemical Engineering, Faculty of Engineering, Razi University, Kermanshah 67149, Iran
Korean Journal of Chemical Engineering, March 2015, 32(3), 429-435(7), 10.1007/s11814-014-0247-4
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Abstract
Mixed matrix heterogeneous cation exchange membranes were prepared by solution casting technique. Ilmenite-co-iron oxide nanoparticle was also employed as inorganic filler additive in membrane fabrication. The effect of the used additives on membrane electrochemical properties was studied. Membrane ion exchange capacity, membrane potential, transport number and selectivity all were improved by use of FeTiO3/Fe3O4 nanoparticles in membrane matrix. Utilizing FeTiO3-co-Fe3O4 nanoparticles in the casting solution also led to increase in ionic flux obviously. The modified membranes containing FeTiO3-co-Fe3O4 nanoparticles showed higher transport number, selectivity and ionic flux compared to modified membrane containing ilmenite. Electrodialysis experiment in laboratory scale also showed higher cation removal for modified membrane containing FeTiO3-co-Fe3O4 nanoparticles compared to other modified membranes and pristine ones. Results showed that membrane areal electrical resistance declined sharply by_x000D_
use of FeTiO3-co-Fe3O4 nanoparticles in membrane matrix. Moreover, modified membrane containing ilmenite showed lower electrical resistance compared to others. Results showed that oxidative stability of membranes was decreased slightly by use of FeTiO3/Fe3O4 nanoparticles in membrane matrix. The results revealed that modified membranes in this study are comparable with that of other commercial ones.
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References
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Xu TW, J. Membr. Sci., 263(1-2), 1 (2005)
Baker RW, Membrane Technology and Applications, 2nd Ed., Wiley, England (2004)
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Zendehnam A, Arabzadegan M, Hosseini SM, Robatmili N, Madaeni SS, Korean J. Chem. Eng., 30(6), 1265 (2013)
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Ng LY, Mohammad AW, Leo CP, Hilal N, Desalination, 308, 15 (2013)
Hosseini SM, Madaeni SS, Heidari AR, Amirimehr A, Desalination, 284, 191 (2012)
Fujii T, Yamashita M, Fujimori S, Saitoh Y, Nakamura T, Kobayashi K, Takada J, J. Magn. Magn. Mater., 310, 555 (2007)
Raghavender AT, Hong NH, Lee KJ, Jung MH, Skoko Z, Vasilevskiy M, Cerqueira MF, Samantilleke AP, J. Magn. Magn. Mater., 331, 129 (2013)
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Mark E, J. Polymer Data Handbook, Oxford University Press Inc., New York (1999)
Harper CA, Handbook of plastic and elastomers, New York, McGraw-Hill (1975)
Li XF, Wang Z, Lu H, Zhao CJ, Na H, Zhao C, J. Membr. Sci., 254(1-2), 147 (2005)
Nagarale RK, Gohil GS, Shahi VK, Rangarajan R, Colloids Surf. A, 251, 133 (2004)
Nagarale RK, Shahi VK, Thampy SK, Rangarajan R, React. Funct. Polym., 61(1), 131 (2004)
Nagarale RK, Shahi VK, Rangarajan R, J. Membr. Sci., 248(1-2), 37 (2005)
Lide DR, CRC Handbook of Chemistry and Physics, 87th Ed. Boca Raton, CRC Press (2006)
Kang MS, Choi YJ, Choi IJ, Yoon TH, Moon SH, J. Membr. Sci., 216(1-2), 39 (2003)
Shahi VK, Trivedi GS, Thampy SK, Rangarajan R, J. Colloid Interface Sci., 262(2), 566 (2003)
Kerres J, Cui W, Disson R, Neubrand W, J. Membr. Sci., 139(2), 211 (1998)
Tanaka Y, Ion exchange membranes: Fundamentals and applications, Netherlands: Membrane Science and Technology Series Elsevier (2007)
Sata T, Ion exchange membranes: Preparation, characterization, modification and application, Cambridge/United Kingdom: The Royal Society of Chemistry (2004)
Schauer J, Brozova L, J. Membr. Sci., 250(1-2), 151 (2005)
Powell CE, Qiao GG, J. Membr. Sci., 279(1-2), 1 (2006)
Dlugolecki P, Nymeijer K, Metz S, Wessling M, J. Membr. Sci., 319(1-2), 214 (2008)
