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- In relation to this article, we declare that there is no conflict of interest.
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Received May 30, 2014
Accepted September 1, 2014
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Adsorption behavior of α-tocopheryl succinate and α-tocopheryl polyethylene glycol succinate onto weakly basic anion exchange resins
Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
Korean Journal of Chemical Engineering, March 2015, 32(3), 511-520(10), 10.1007/s11814-014-0259-0
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Abstract
Polyethylene glycol (PEG) esters are important, nontoxic and biodegradable non-ionic surfactants. A key procedure in producing PEG esters is their separation from unreacted or excess acids. We propose an adsorption method using the weakly basic anion exchange resins for the separation of organic acids and PEG esters for the first time. With α-tocopheryl polyethylene glycol succinate (TPGS) and α-tocopheryl succinate (α-TS) as the examples of_x000D_
PEG ester and organic acid, respectively, single-component equilibrium experiments revealed the great potential of this method. Studies on the adsorption equilibrium, thermodynamics and kinetics of α-TS onto a weakly basic anion exchange resin were also carried out. This research is not only important for the production of TPGS, but also instructive for the separation of other PEG-esters from the reaction mixtures.
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Tong WY, Fu XY, Lee SM, Yu J, Liu JW, Wei DZ, Koo YM, Biochem. Eng. J., 18, 89 (2004)
Yoshida H, Takatsuji W, Ind. Eng. Chem. Res., 39(4), 1074 (2000)
Kanazawa N, Urano K, Kokado N, Urushigawa Y, J. Colloid Interface Sci., 271(1), 20 (2004)
Kananpanah S, Dizadji N, Abolghasemi H, Salamatinia B, Korean J. Chem. Eng., 26(5), 1208 (2009)
Ma CH, Yang L, Zu YG, Wang NH, Zhang L, Zhang Y, Chen XQ, Zhao CJ, Chem. Eng. Res. Des., 90(9), 1189 (2012)
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Traber MG, Schiano TD, Steephen AC, Kayden HJ, Shike M, Am. J. Clin. Nutr., 59, 1270 (1994)
Sokol RJ, Heubi JE, Butlersimon N, McClung HJ, Lilly JR, Silverman A, Gastroenterology, 93, 975 (1987)
Collnot EM, Baldes C, Wempe MF, Hyatt J, Navarro L, Edgar KJ, Schaefer UF, Lehr CM, J. Control. Release, 111, 35 (2006)
Chang YZ, Cao YC, Zhang J, Wen YY, Ren QL, J. Pharmaceut. Biomed., 56, 804 (2011)
Mert O, Lai SK, Ensign L, Yang M, Wang YY, Wood J, Hanes J, J. Control. Release, 157, 455 (2012)
Wang JY, Su BG, Xing HB, Yang YW, Ren QL, J. Appl. Polym. Sci., 119(5), 3026 (2011)
Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
Carmo AM, Hundal LS, Thompson ML, Environ. Sci. Technol., 34, 4363 (2000)
Li Q, Yue QY, Su Y, Gao BY, Sun HJ, Chem. Eng. J., 158(3), 489 (2010)
Quinones I, Guiochon G, J. Colloid Interface Sci., 183(1), 57 (1996)
Dabrowski A, Jaroniec M, Acta Chim. Hung., 99, 255 (1979)
Choy KKH, McKay G, Porter JF, Resour. Conserv. Recycl., 27, 57 (1999)
Lin SH, Juang RS, J. Hazard. Mater., 92(3), 315 (2002)
Yousef RI, El-Eswed B, Al-Muhtaseb AH, Chem. Eng. J., 171(3), 1143 (2011)
Ozacar M, Sengil IA, Turkmenler H, Chem. Eng. J., 143(1-3), 32 (2008)
Rudzinski W, Plazinski W, J. Phys. Chem. B, 110(33), 16514 (2006)
Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
Ozacar M, Adsorption, 9, 125 (2003)
Ho YS, McKay G, Resour. Conserv. Recycl., 25, 171 (1999)
Sarkar D, Chattoraj DK, J. Colloid Interface Sci., 157, 219 (1993)
Atun G, Sismanoglu T, J. Environ. Sci. Health Part A, 31, 2055 (1996)
Greluk M, Hubicki Z, J. Hazard. Mater., 172(1), 289 (2009)
