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Received July 9, 2014
Accepted August 26, 2014
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Acoustically aided coalescence of water droplets and dehydration of crude oil emulsion
1Institute of Sonochemical Engineering, Nanjing University of Technology, Nanjing, P. R. China 2Yangzhou Polytechnic Institute, Yangzhou, Jiangsu, P. R. China
xiewei0304@163.com
Korean Journal of Chemical Engineering, April 2015, 32(4), 643-649(7), 10.1007/s11814-014-0253-6
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Abstract
We studied the use of acoustics for coalescence of water droplets and dehydration of crude oil emulsion. Experimental studies were conducted using acoustic standing waves in a resonant cavity to trap water droplets and enhance oil separation. The focus was on the effect of ultrasound irradiation on crude oil emulsion properties, such as viscosity, water drop radius, shear strength of oil-water interfacial films, and flocculation size of asphaltene. These properties_x000D_
are important to the coalescence of water drops in water-oil (W/O) emulsion in the process of oil separation with ultrasound. Ultrasound irradiation is able to decrease the emulsion stability, which provides a new insight into the acoustics-aided demulsification mechanism. It can be considered as a supplement of traditional acoustics-aided demulsification mechanism (ultrasound-induced motion of water droplets). Furthermore, the effects of ultrasonic parameters_x000D_
such as the type of ultrasonic field, irradiation time, frequency, and acoustic intensity on dewatering the W/O emulsion are discussed. These results provide guidance for setting the optimum conditions for the separation of W/O emulsion with ultrasound. Under the optimum conditions, water content in crude oil emulsion can be decreased from 40% to 3.8%, which satisfies the requirement of dehydration for refinery.
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References
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Check GR, Chem. Eng. Process., 81, 72 (2014)
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Stack LJ, Carney PA, Malone HB, Ultrason. Sonochem., 12, 153 (2005)
Pangu GD, Feke DL, Chem. Eng. Sci., 59(15), 3183 (2004)
Crum LA, J. Acoust. Soc. Am., 50, 157 (1972)
Jiao JJ, He Y, Leong T, Kentish SE, Ashokkumar M, Manasseh R, Lee J, J. Phys. Chem. B, 117(41), 12549 (2013)
Browne C, Tabor RF, Chan DYC, Dagastine RR, Ashokkumar M, Grieser F, Langmuir, 27(19), 12025 (2011)
Zhang J, Li J, Thring RW, Hu X, Song X, J. Hazard. Mater., 203-204, 195 (2012)
Jin YQ, Zheng XY, Chu XL, Chi Y, Yan JH, Cen KF, Ind. Eng. Chem. Res., 51(27), 9213 (2012)
Check GR, Mowla D, Ultrason. Sonochem., 20, 378 (2013)
Nii S, Kikumoto S, Tokuyama H, Ultrason. Sonochem., 16, 145 (2009)
Talor SE, Chem. Ind., 19, 770 (1992)
Sunartio D, Ashokkumar M, Grieser F, J. Am. Chem. Soc., 129(18), 6031 (2007)
Mohammed RA, Bailey AI, Luckham PF, Taylor SE, ColColloids Surf., A: Physicochemical and Engineering Aspects, 80, 237 (1993)
Mclean JD, Kilpatrick PK, J. Colloid Interface Sci., 189(2), 242 (1997)
Aveyard R, Binks BP, Fletcher PDI, Lu JR, J. Colloid Interface Sci., 139, 128 (1990)
Isaacs EE, Huang H, Babchin AJ, Chow RS, Colloids Surf., 46, 177 (1990)
Eley DD, Hey MJ, Symonds JD, Colloids Surf., 32, 87 (1988)
Yosioka K, Kawasima G, Acustica, 5, 167 (1955)
Weiser MAH, Apfel RE, Acustica, 56, 114 (1984)
Zheng X, Apfel RE, J. Acoust. Soc. Am., 97, 2218 (1995)
Crum LA, J. Acoust. Soc. Am., 57, 1363 (1975)
Pangu GD, Feke DL, Ultrasonics, 46, 289 (2007)
Wang J, Dual J, Ultrasonics, 52, 325 (2012)
Mclean JD, Kilpatrick PK, J. Colloid Interface Sci., 189(2), 242 (1997)
Abe Y, Kawaji M, Watanabe T, Exp. Therm. Fluid Sci., 26, 817 (2002)
Xi X, Cegla FB, Lowe M, Thiemann A, Ultrasonics, 51, 1014 (2011)