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Received May 5, 2014
Accepted September 11, 2014
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Preparation of activated carbon from fly ash and its application for CO2 capture
Yahia Abobakor Alhamed1 2†
Sami Ullah Rather1 2†
Ahmad Hasan El-Shazly1 2
Sharif Fakhruz Zaman1 2
Mohammad Abdulrhaman Daous1 2
Abdulrahim Ahmad Al-Zahrani1 2
1Chemical and Materials Engineering Department, King Abdulaziz University, P. O. Box 80204, Jeddah 21589, Saudi Arabia 2Center of Excellence in Environmental Studies, King Abdulaziz University, P.O. Box 80216, Jeddah 21589, Saudi Arabia
rathersami@gmail.com
Korean Journal of Chemical Engineering, April 2015, 32(4), 723-730(8), 10.1007/s11814-014-0273-2
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Abstract
Power and desalination plants are one of the main anthropogenic sources for CO2 generation, which is one of the key elements to cause greenhouse gas effect and thus contribute to the global warming. Fly ash (FA) generated in desalination and power plants was converted into activated carbon (AC) treated with KOH at higher temperature and tested for CO2 capturing efficiency. Morphological characteristics of FA such as BET specific surface area (SSA), pore_x000D_
volume, pore diameter, and pore size distribution (PSD) were performed using N2 adsorption isotherm. CO2 adsorption capacity and adsorption isotherms of CO2 over AC were measured by performing thermogravimetric analysis at different temperatures. BET SSA of 161m2g-1 and adsorption capacity of 26mg CO2/g AC can be obtained by activation at KOH/FA ratio of 5 at 700 oC and activation time of 2 h. Therefore, great potential exists for producing AC from FA, which will have the positive effect of reducing the landfill problem and global warming.
References
Valer MMM, Song C, Soong Y, Environmental challenges and greenhouse gas Control for fossil fuel utilization in the 21st Century, Springer (2003). (2003)
Quere CL, Earth Syst. Sci. Data, 6, 689 (2013)
Daous M, The 20th International conference on solid waste technology and management, Philadelphia, USA (2005). (2005)
Rahman MM, Dalvi AG, Rabbani KA, Al-Sulami S, Mandili F, Khaledi HM, Al-Jowdi B, Evaluation of fuel chemical additives to reduce corrosion and stack emission in SWCC power plants, 4th SWCC Acquired Experience Symposium, Jeddah, Saudi Arabia (2005). (2005)
Wang SB, Wu HW, J. Hazard. Mater., 136(3), 482 (2006)
Adriano DC, Page AL, Elseewi AA, Chang AC, Straughan I, J. Environ. Qual., 9, 333 (1980)
Valer MMM, Song C, Soong Y, Environmental challenges and greenhouse gas Control for fossil fuel utilization in the 21st Century, Springer (2003). (2003)
Quere CL, Earth Syst. Sci. Data, 6, 689 (2013)
Daous M, The 20th International conference on solid waste technology and management, Philadelphia, USA (2005). (2005)
Rahman MM, Dalvi AG, Rabbani KA, Al-Sulami S, Mandili F, Khaledi HM, Al-Jowdi B, Evaluation of fuel chemical additives to reduce corrosion and stack emission in SWCC power plants, 4th SWCC Acquired Experience Symposium, Jeddah, Saudi Arabia (2005). (2005)
Wang SB, Wu HW, J. Hazard. Mater., 136(3), 482 (2006)
Adriano DC, Page AL, Elseewi AA, Chang AC, Straughan I, J. Environ. Qual., 9, 333 (1980)
Paya J, Monzo J, Borrachero MV, Peris E, Lopez EG, Cem. Concr. Res., 27, 1365 (1997)
Weerdt KD, Haha MB, Saout GL, Kjellsen KO, Justnes H, Lothenbach B, Cem. Concr. Res., 41, 279 (2011)
Flatt RJ, Roussel N, Cheeseman CR, J. European Ceram. Soc., 32, 2787 (2012)
Sombatsompop N, Thongsang S, Markpin T, Wimolmala E, J. Appl. Polym. Sci., 93(5), 2119 (2004)
Chindaprasirt P, De Silva P, Sagoe-Crentsil K, Hanjitsuwan S, J. Mater. Sci., 47(12), 4876 (2012)
Vargas DP, Giraldo L, Moreno-Pirajan JC, Int. J. Mol. Sci., 13(7), 8388 (2012)
Alessandro DMD, Smit B, Long JR, Angew. Chem. Int. Ed., 49, 6058 (2010)
Yu CH, Huang CH, Tan CS, Aerosol Air Qual. Res., 12, 745 (2012)
Bansal RC, Donnet JB, Stoeckli F, Deckker M, J. Dispersion Sci. Technol., 11, 323 (1990)
Valix M, Cheung WH, McKay G, Chemosphere, 56, 493 (2004)
Usmani TH, Tahir M, Siddiqui I, Parveen FA, J. Chem. Soc. Pak., 25, 183 (2003)
Caturla F, Sabio MM, Reinoso FR, Carbon, 29, 999 (1991)
Pour AA, Do DD, Carbon, 34, 471 (1996)
Somna K, Jaturapitakkul C, Kajitvichyanukul P, Chindaprasirt P, Fuel, 90(6), 2118 (2011)
Wu FC, Wu PH, Tseng RL, Juang RS, J. Environ. Manage., 91, 1097 (2010)
Tseng RL, Tseng SK, Wu FC, Hu CC, Wang CC, J. Chin. Inst. Chem. Eng., 39(1), 37 (2008)
Rodenas MAL, Juan JJ, Amoros DC, Solano AL, Carbon, 42, 1371 (2004)
Rodenas MAL, Amoros DC, Solano AL, Carbon, 41, 267 (2003)
Stavropoulos GG, Fuel Process. Technol., 86(11), 1165 (2005)
Chunlan L, Shaoping X, Yixiong G, Shuqin L, Changhou L, Carbon, 43, 2295 (2005)
Lowell S, Shields JE, Thomas MA, Thommes M, Characterization of Porous Solids and Powders: Surface Area, Pore Size and Density, Kluwer Academic Publishers, Netherland (2004). (2004)
Yang T, Lua AC, J. Colloid Interface Sci., 267(2), 408 (2003)
Illangomez MJ, Garciagarcia A, Delecea CS, Linaressolano A, Energy Fuels, 10(5), 1108 (1996)
Rouquerol F, Rouquerol J, Sing K, Adsorption by powders and porous solids: Principles methodology and applications, Academic Press, London (1999). (1999)
Yang RT, Gas separation by adsorption process, vol. 1, Imperial College Press, Boston (1997). (1997)
Quere CL, Earth Syst. Sci. Data, 6, 689 (2013)
Daous M, The 20th International conference on solid waste technology and management, Philadelphia, USA (2005). (2005)
Rahman MM, Dalvi AG, Rabbani KA, Al-Sulami S, Mandili F, Khaledi HM, Al-Jowdi B, Evaluation of fuel chemical additives to reduce corrosion and stack emission in SWCC power plants, 4th SWCC Acquired Experience Symposium, Jeddah, Saudi Arabia (2005). (2005)
Wang SB, Wu HW, J. Hazard. Mater., 136(3), 482 (2006)
Adriano DC, Page AL, Elseewi AA, Chang AC, Straughan I, J. Environ. Qual., 9, 333 (1980)
Valer MMM, Song C, Soong Y, Environmental challenges and greenhouse gas Control for fossil fuel utilization in the 21st Century, Springer (2003). (2003)
Quere CL, Earth Syst. Sci. Data, 6, 689 (2013)
Daous M, The 20th International conference on solid waste technology and management, Philadelphia, USA (2005). (2005)
Rahman MM, Dalvi AG, Rabbani KA, Al-Sulami S, Mandili F, Khaledi HM, Al-Jowdi B, Evaluation of fuel chemical additives to reduce corrosion and stack emission in SWCC power plants, 4th SWCC Acquired Experience Symposium, Jeddah, Saudi Arabia (2005). (2005)
Wang SB, Wu HW, J. Hazard. Mater., 136(3), 482 (2006)
Adriano DC, Page AL, Elseewi AA, Chang AC, Straughan I, J. Environ. Qual., 9, 333 (1980)
Paya J, Monzo J, Borrachero MV, Peris E, Lopez EG, Cem. Concr. Res., 27, 1365 (1997)
Weerdt KD, Haha MB, Saout GL, Kjellsen KO, Justnes H, Lothenbach B, Cem. Concr. Res., 41, 279 (2011)
Flatt RJ, Roussel N, Cheeseman CR, J. European Ceram. Soc., 32, 2787 (2012)
Sombatsompop N, Thongsang S, Markpin T, Wimolmala E, J. Appl. Polym. Sci., 93(5), 2119 (2004)
Chindaprasirt P, De Silva P, Sagoe-Crentsil K, Hanjitsuwan S, J. Mater. Sci., 47(12), 4876 (2012)
Vargas DP, Giraldo L, Moreno-Pirajan JC, Int. J. Mol. Sci., 13(7), 8388 (2012)
Alessandro DMD, Smit B, Long JR, Angew. Chem. Int. Ed., 49, 6058 (2010)
Yu CH, Huang CH, Tan CS, Aerosol Air Qual. Res., 12, 745 (2012)
Bansal RC, Donnet JB, Stoeckli F, Deckker M, J. Dispersion Sci. Technol., 11, 323 (1990)
Valix M, Cheung WH, McKay G, Chemosphere, 56, 493 (2004)
Usmani TH, Tahir M, Siddiqui I, Parveen FA, J. Chem. Soc. Pak., 25, 183 (2003)
Caturla F, Sabio MM, Reinoso FR, Carbon, 29, 999 (1991)
Pour AA, Do DD, Carbon, 34, 471 (1996)
Somna K, Jaturapitakkul C, Kajitvichyanukul P, Chindaprasirt P, Fuel, 90(6), 2118 (2011)
Wu FC, Wu PH, Tseng RL, Juang RS, J. Environ. Manage., 91, 1097 (2010)
Tseng RL, Tseng SK, Wu FC, Hu CC, Wang CC, J. Chin. Inst. Chem. Eng., 39(1), 37 (2008)
Rodenas MAL, Juan JJ, Amoros DC, Solano AL, Carbon, 42, 1371 (2004)
Rodenas MAL, Amoros DC, Solano AL, Carbon, 41, 267 (2003)
Stavropoulos GG, Fuel Process. Technol., 86(11), 1165 (2005)
Chunlan L, Shaoping X, Yixiong G, Shuqin L, Changhou L, Carbon, 43, 2295 (2005)
Lowell S, Shields JE, Thomas MA, Thommes M, Characterization of Porous Solids and Powders: Surface Area, Pore Size and Density, Kluwer Academic Publishers, Netherland (2004). (2004)
Yang T, Lua AC, J. Colloid Interface Sci., 267(2), 408 (2003)
Illangomez MJ, Garciagarcia A, Delecea CS, Linaressolano A, Energy Fuels, 10(5), 1108 (1996)
Rouquerol F, Rouquerol J, Sing K, Adsorption by powders and porous solids: Principles methodology and applications, Academic Press, London (1999). (1999)
Yang RT, Gas separation by adsorption process, vol. 1, Imperial College Press, Boston (1997). (1997)
