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Received July 14, 2014
Accepted October 9, 2014
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Single and binary adsorption of Cd (II) and Zn (II) ions from aqueous solutions onto bottom ash
Hatairat Sukpreabprom1
Orn-anong Arqueropanyo1 2†
Wimol Naksata1 2
Ponlayuth Sooksamiti3
Sorapong Janhom1 2
1Department of Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand, Korea 2Materials Science Research Center, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand 3The Office of Primary Industries and Mines Region 3, Chiang Mai 50300, Thailand
orn.arquero@gmail.com
Korean Journal of Chemical Engineering, May 2015, 32(5), 896-902(7), 10.1007/s11814-014-0309-7
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Abstract
Bottom ash, a waste obtained from coal-burning power plant, was used as a low cost adsorbent for the removal of Cd (II) and Zn (II) ions from single and binary systems in batch experiments. The results of adsorption capacity showed that bottom ash could be considered as a potential adsorbent. The uptake of Zn (II) ion was greater than that of Cd (II) ion. For single adsorption, based on the correlation coefficient (R2) values, both Langmuir and Freundlich isotherms suitably described the adsorption equilibrium data in the initial metal ion concentration range of 10-50 mg/L. The multicomponent isotherms, including the extended Langmuir and IAST-Freundlich isotherms, were used to predict the binary adsorption of Cd (II) and Zn (II) ions. Furthermore, the appropriate multicomponent isotherm was investigated by minimizing the average relative error (ARE) function. It should be confirmed that the extended Langmuir isotherm fitted the binary adsorption equilibrium data satisfactorily.
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Anirudhan TS, Suchithra PS, Indian J. Chem. Technol., 17(4), 247 (2010)
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Etci O, Bektas N, Oncel MS, Environ. Earth Sci., 61, 231 (2010)
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