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Received June 3, 2014
Accepted September 27, 2014
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Cyclic CO2 capture characteristics of a pellet derived from sol-gel CaO powder with Ca12Al14O33 support
State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, China 1College of Power Engineering, Chongqing University, Chongqing 400044, China 2School of Mechanical and Mining Engineering, The University of Queensland, St Lucia, QLD 4072, Australia
cluo@hust.edu.cn
Korean Journal of Chemical Engineering, May 2015, 32(5), 934-938(5), 10.1007/s11814-014-0291-0
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Abstract
A novel calcium-based pellet was prepared by extrusion of sol-gel CaO powder and cement with high aluminum-based content. Limestone was used for comparison. The cyclic CO2 capture performance and carbonation kinetics of the sorbents were investigated in a thermogravimetric analyzer (TGA). The changes in phase and microstructure were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Brunauer Emmet Teller (BET) surface area, respectively. The results indicate that the pellet consisted of CaO and Ca12Al14O33 after initial calcination. Limestone reactivity decreased dramatically with the increase in the cycle number, whereas the pellet showed a relatively stable cyclic CO2 capture performance with high reactivity. The CO2 capture capacity of the pellet achieved 0.43 g CO2/g sorbent after 50 cycles at 650 oC and 850 oC for carbonation and calcination, respectively. Moreover, the pellet obtained fast carbonation rates with slight decay after multiple cycles. The porous microstructure of the_x000D_
pellet contributed to the high reactivity of the sorbent during high temperature reactions, and the support material of Ca12Al14O33, enhanced the cyclic durability of the calcium-based sorbents.
Keywords
References
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Chen HC, Zhao CS, Duan LB, Liang C, Liu DJ, Chen XP, Fuel Process. Technol., 92(3), 493 (2011)
Luo C, Zheng Y, Ding N, Wu QL, Bian GA, Zheng CG, Ind. Eng. Chem. Res., 49(22), 11778 (2010)
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Li ZS, Liu Y, Cai NS, Chem. Eng. Sci., 89, 235 (2013)
Luo C, Zheng Y, Ding N, Wu QL, Zheng CG, Chin. Chem. Lett., 22, 615 (2011)
Zhou ZM, Qi Y, Xie MM, Cheng ZM, Yuan WK, Chem. Eng. Sci., 74, 172 (2012)
Wang K, Guo X, Zhao PF, Zheng CG, Appl. Clay. Sci., 50, 41 (2010)
Manovic V, Anthony EJ, Ind. Eng. Chem. Res., 49(15), 6916 (2010)
Li ZS, Cai NS, Huang YY, Han HJ, Energy Fuels, 19(4), 1447 (2005)
Martavaltzi CS, Lemionidou AA, Ind. Eng. Chem. Res., 47(23), 9537 (2008)
Manovic V, Anthony EJ, Ind. Eng. Chem. Res., 48(19), 8906 (2009)
Li ZS, Cai NS, Huang YY, Ind. Eng. Chem. Res., 45(6), 1911 (2006)
Bhatia SK, Perlmutter DD, AIChE J., 29, 79 (1983)
Luo C, Shen QW, Ding N, Feng ZX, Zheng Y, Zheng CG, Chem. Eng. Technol., 35(3), 547 (2012)
Witoon T, Mungcharoen T, Limtrakul J, Appl. Energy, 118, 32 (2014)
