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Received November 3, 2014
Accepted December 9, 2014
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Selective sorption behavior of metal(II) ion-imprinted polymethacrylate microspheres synthesized via precipitation polymerization method
School of Chemical Engineering, Sungkyunkwan University, Suwon, Gyeonggi-do 440-746, Korea
djkim@skku.edu
Korean Journal of Chemical Engineering, May 2015, 32(5), 967-973(7), 10.1007/s11814-014-0374-y
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Abstract
Metal methacrylate complex was synthesized from methacrylic acid and metal carbonate to prepare metal ion-imprinted polymer (MIIP) particles by the precipitation polymerization method. Three types of metal ions, Cu(II), Ni(II), and Pb(II), were used as the template ions in this synthesis. The produced MIIP particles were spherically welldefined with 0.5-2 μm diameter in the order of Cu(II)-MIIP>Ni(II)-MIIP>Pb(II)-MIIP. The imprinted polymers exhibited a much higher adsorption capacity and selectivity toward the target (template) ion than other competitive metal ions. The MIIP particles, Cu(II)-MIIP, Ni(II)-MIIP, and Pb(II)-MIIP, synthesized in this study guaranteed the selective separation of the target metal ion from the mixtures, although their competitive strengths of the adsorption capacity and selectivity were different.
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References
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Lalhruaitluanga H, Jayaram K, Prasad MNV, Kumar KK, J. Hazard. Mater., 175(1-3), 311 (2010)
Akhtar M, Iqbal S, Kausar A, Bhanger MI, Shaheen MA, Colloids Surf., B, 75, 149 (2010)
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Mosbach K, Ramstrom O, Biol. Biotechnol., 14, 163 (1996)
Al-Kindy S, Badıa R, Dıaz-Garcıa ME, Anal. Lett., 35, 1763 (2002)
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Shi Y, Zhang Q, Feng L, Xiong Q, Chen J, Korean J. Chem. Eng., 31(5), 821 (2014)
Dam AH, Kim DJ, J. Appl. Polym. Sci., 108(1), 14 (2008)
Hoai NT, Yoo DK, Kim D, J. Hazard. Mater., 173(1-3), 462 (2010)
Jiang Y, Kim D, Chem. Eng. J., 166(1), 435 (2011)
Fan HT, Fan XL, Li J, Guo MM, Zhang DS, Yan F, Sun T, Ind. Eng. Chem. Res., 51(14), 5216 (2012)
Zhang ML, Zhang ZH, Liu YN, Yang X, Luo LJ, Chen JT, Yao SZ, Chem. Eng. J., 178, 443 (2011)
Chen JH, Li GP, Liu QL, Ni JC, Wu WB, Lin JM, Chem. Eng. J., 165(2), 465 (2010)
Fan HT, Liu JX, Yao H, Zhang ZG, Yan F, Li WX, Ind. Eng. Chem. Res., 53(1), 369 (2014)
Fan HT, Tang Q, Sun Y, Zhang ZG, Li WX, Chem. Eng. J., 258, 146 (2014)
Behbahani M, Bagheri A, Taghizadeh M, Salarian M, Sadeghi O, Adlnasab L, Jalali K, Food Chem., 138, 2050 (2013)
Otero-Romani J, Moreda-Pineiro A, Bermejo-Barrera P, Martin-Esteban A, Talanta, 79, 723 (2009)
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Li ZC, Fan HT, Zhang Y, Chen MX, Yu ZY, Cao XQ, Sun T, Chem. Eng. J., 171(2), 703 (2011)
Hoai NT, Kim D, AIChE J., 52, 3248 (2009)
Jiang Y, Kim D, Polym. Advan. Technol., 24, 747 (2013)
Jiang Y, Kim D, J. Nanosci. Nanotechnol., 14, 8578 (2014)