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Received June 7, 2014
Accepted October 2, 2014
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Evaluation of biomass component effect on kinetic values for biomass pyrolysis using simplex lattice design
Sasiporn Chayaporn1
Panusit Sungsuk1
Sasithorn Sunphorka1
Prapan Kuchonthara1 2
Pornpote Piumsomboon1 2
Benjapon Chalermsinsuwan1 2†
1Fuels Research Center, Department of Chemical Technology, Faculty of Science, Chulalongkorn University, 254 Phayathai Road, Patumwan, Bangkok 10330, Thailand 2Center of Excellence on Petrochemical and Material Technology, Chulalongkorn University, 254 Phayathai Road, Patumwan, Bangkok 10330, Thailand
benjapon.c@chula.ac.th
Korean Journal of Chemical Engineering, June 2015, 32(6), 1081-1093(13), 10.1007/s11814-014-0296-8
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Abstract
Abstract.We evaluated the correlation between the biomass constituents and their kinetic values. To simplify the models and indicate the effect of each constituent, pure biomass components and their mixtures were used as biomass model. The experiments were set up based on simplex-lattice design. The pyrolysis of synthesized biomass was performed by non-isothermal thermogravimetric analyzer. Several kinetic models in the literature, including Kissinger-Akahira-Sunose, Ozawa-Flynn-Wall and analytical method were used to determine kinetic values for each experiment. The generated regression models and predicted kinetic values from those methods were compared. The results obtained from analytical model (for n≠1) showed a good agreement (R2>0.95) with those obtained from experiments. This study also provide contour plots for all cases in order to observe the behavior of biomass pyrolysis at different component ratio.
Keywords
References
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Couhert C, Commandre JM, Salvador S, Fuel, 88(3), 408 (2009)
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Burhenne L, Messmer J, Aicher T, Laborie MP, J. Anal. Appl. Pyrolysis, 101, 177 (2013)
Rao PV, Baral SS, Chem. Eng. J., 172(2-3), 977 (2011)
Liu Q, Zhong Z, Wang S, Luo Z, J. Anal. Appl. Pyrolysis, 90, 213 (2011)
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White JE, Catallo WJ, Legendre BL, J. Anal. Appl. Pyrolysis, 91, 1 (2011)
Kissinger HE, Anal. Chem., 29, 1702 (1957)
Akahira T, Sunose T, Research Report of Chiba Institute of Technology, 16, 22 (1971)
Ozawa T, J. Therm. Anal. Calorim., 2, 301 (1970)
Flynn JH, Thermochim. Acta, 300, 83 (1997)
Doyle CD, Nature, 207, 290 (1965)
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Karaman S, Yilmaz MT, Kayacier A, Food Hydrocolloids, 25, 1319 (2011)
Hashimoto K, Hasegawa I, Hayashi J, Mae K, Fuel, 90(1), 104 (2011)
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Haykiri-Acma H, Yaman S, Kucukbayrak S, Fuel Process. Technol., 91(7), 759 (2010)
