Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received August 16, 2014
Accepted October 9, 2014
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Experimental investigation and modeling of industrial oily wastewater treatment using modified polyethersulfone ultrafiltration hollow fiber membranes
Research Centre for Membrane Separation Processes (RCMSP), Faculty of Chemical Engineering, Iran University of Science and Technology (IUST), Narmak, Tehran 16846, Iran 1Department of Gas & Chemical Engineering, Petroleum University of Technology (PUT), Ahwaz, Iran 2Polymer Science and Technology Division, Research Institute of Petroleum Industry, West Blvd., Near Azadi Sports Complex, Tehran, Iran
rezabehbahaniput@gmail.com, salahi@iust.ac.ir
Korean Journal of Chemical Engineering, June 2015, 32(6), 1101-1118(18), 10.1007/s11814-014-0310-1
Download PDF
Abstract
Hollow fiber membranes were prepared from polyethersulfone/additives/NMP&DMSO system via phase inversion induced by precipitation in non-solvent coagulation bath. The interaction effects of polyethylene-glycol (PEG), propionic-acid (PA), Tween-20, PEG molecular weight and polyvinyl-pyrrolidone (PVP) on morphology and performance of synthesized membranes were investigated. Taguchi method (L16 orthogonal array) was used initially to plan a minimum number of experiments. 32 membranes were synthesized (with two replications) and their permeation flux and TOC rejection properties to oily wastewater treatment were studied. The obtained results indicated that addition of PA to spinning dope decreases flux while it increases TOC rejection of prepared membranes. Also, the result shows that addition of PVP, Tween-20 and PEG content in spinning dope enhances permeation flux while reducing TOC rejection. The obtained results indicated that the synthesized membranes was effective and suitable for treatment of the oily wastewater to achieve up to 92.6, 98.2, and 98.5% removal of TOC, TSS, and OGC, respectively with a flux of 247.19 L/(m2h). Moreover, Hermia’s models were used for permeation flux decline prediction. Experimental data and models predictions were compared. The results showed that there is reasonable agreement between experimental data and the cake layer model followed by the intermediate blocking model.
Keywords
References
Canizares P, Martinez F, Jimenez C, Saez C, Rodrigo MA, J. Hazard. Mater., 151(1), 44 (2008)
Song KH, Lee KR, Korean J. Chem. Eng., 24(1), 116 (2007)
Salahi A, Mohammadi T, Water Sci. Technol., 63, 1476 (2011)
Li Q, Snoeyink VL, Marinas BJ, Campos C, Water Res., 37, 4863 (2003)
Kim JS, Cai ZX, Benjamin MM, J. Membr. Sci., 310(1-2), 356 (2008)
Madaeni SS, Rahimi M, Abolhasani M, Korean J. Chem. Eng., 27(1), 206 (2010)
Tomaszewska M, Mozia S, Water Res., 36, 4137 (2002)
Oh H, Yu M, Takizawa S, Ohgaki S, Desalination, 192(1-3), 54 (2006)
Kweon JH, Hur HW, Seo GT, Jang TR, Park JH, Choi KY, Kim HS, Desalination, 249(1), 212 (2009)
Ying Z, Ping G, Sep. Purif. Technol., 52(1), 154 (2006)
Matsuim Y, Yuasam A, Ariga K, Water Res., 35, 455 (2001)
Harrelkas F, Azizi A, Yaacoubi A, Benhammou A, Pons MN, Desalination, 235(1-3), 330 (2009)
Suzuki T, Watanabe Y, Ozawa G, Ikeda S, Desalination, 117, 119 (1998)
Shi Q, Su YL, Zhu SP, Li C, Zhao YY, Jiang ZY, J. Membr. Sci., 303(1-2), 204 (2007)
Liu ZM, Xu ZK, Wan LS, Wu J, Ulbricht M, J. Membr. Sci., 249(1-2), 21 (2005)
Ghaffarian V, Mousavi SM, Bahreini M, Jalaei H, J. Ind. Eng. Chem., 20(4), 1359 (2014)
Frommer MA, Messalem RM, Ind. Eng. Chem. Prod. Res. Dev., 12, 328 (1973)
Peng N, Widjojo N, Sukitpaneenit P, Teoh MM, Lipscomb GG, Chung TS, Lai JY, Prog. Polym. Sci, 37, 1401 (2012)
Vogrin N, Stropnik C, Musil V, Brumen M, J. Membr. Sci., 207(1), 139 (2002)
Strathmann H, Kock K, Desalination, 21, 241 (1977)
Kim IC, Lee KH, J. Appl. Polym. Sci., 89(9), 2562 (2003)
Zheng QZ, Wang P, Yang YN, J. Membr. Sci., 279(1-2), 230 (2006)
An TH, Chyu RR, Ming WD, Yih LJ, J. Appl. Polym. Sci., 86, 166 (2002)
Lai JY, Lin FC, Wang CC, Wang DM, J. Membr. Sci., 118(1), 49 (1996)
Kim HJ, Tyagi RK, Fouda AE, Jonasson K, J. Appl. Polym. Sci., 62(4), 621 (1996)
Niu HY, Lang WZ, Liu YX, Guo YJ, Fiber Polym., 14, 1587 (2013)
Chakrabarty B, Ghoshal AK, Purkait AK, J. Membr. Sci., 315(1-2), 36 (2008)
Zhu LP, Xu L, Zhu BK, Feng YX, Xu YY, J. Membr. Sci., 294(1-2), 196 (2007)
Amirilargani M, Mohammadi T, Polym. Adv. Technol., 20, 993 (2009)
Wienk IM, Boom RM, Beerlage MA, Bulte AM, Smolders CA, Strathmann H, J. Membr. Sci., 113(2), 361 (1996)
Idris A, Ismail AF, Noordin MY, Shilton SJ, J. Membr. Sci., 205(1-2), 223 (2002)
Mosqueda-Jimenez DB, Narbaitz RM, Matsuura T, Chowdhury G, Pleizier G, Santerre JP, J. Membr. Sci., 231(1-2), 209 (2004)
Kim IC, Lee KH, J. Membr. Sci., 230(1-2), 183 (2004)
Saljoughi E, Sadrzadeh M, Mohammadi T, J. Membr. Sci., 326(2), 627 (2009)
Amirilargani M, Sadrzadeh M, Mohammadi T, J. Polym. Res., 17, 363 (2010)
Salahi A, Mohammadi T, Nikbakht M, Golshenasa M, Noshadi I, Desal. Wat. Treat., 48, 27 (2012)
Salahi A, Abbasi M, Mohammadi T, Desalination, 251(1-3), 153 (2010)
Abadi SRH, Sebzari MR, Hemati M, Rekabdar F, Mohammadi T, Desalination, 265(1-3), 222 (2011)
APHA-American Public Health Association/American Water Works Association/Water Environment Federation, Standard Methods for the Examination of Water and Wastewater, 2001, 20th Ed., Washington, DC, USA (2001). (2001)
Laninovic V, Desalination, 186(1-3), 39 (2005)
Li JF, Xu ZL, Yang H, Feng CP, Shi JH, J. Appl. Polym. Sci., 107(6), 4100 (2008)
Amirilargani M, Saljoughi E, Mohammadi T, Moghbeli MR, Polym. Eng. Sci., 50(5), 885 (2010)
Rahimpour A, Madaeni SS, Mansourpanah Y, J. Membr. Sci., 296(1-2), 110 (2007)
Madaeni SS, Hoseini S, J. Polym. Res., 16, 591 (2009)
Wang DM, Lin FC, Wu TT, Lai JY, J. Membr. Sci., 142(2), 191 (1998)
Strathmann H, Kock K, Amar P, Baker RW, Desalination, 16, 179 (1975)
Amirilargani M, Saljoughi E, Mohammadi T, J. Appl. Polym. Sci., 115(1), 504 (2010)
Smolders CA, Reuvers AJ, Boom RM, Wienk IM, J. Membr. Sci., 73, 259 (1992)
Rahman NA, Sotani T, Matsuyama H, J. Appl. Polym. Sci., 108(5), 3411 (2008)
Kim JH, Lee KH, J. Membr. Sci., 138(2), 153 (1998)
Sivakumar M, Malaisamy R, Sajitha CJ, Mohan D, Mohan V, Rangarajan R, J. Membr. Sci., 169(2), 215 (2000)
Chakrabarty B, Ghoshal AK, Purkait MK, J. Membr. Sci., 309(1-2), 209 (2008)
Lai JY, Lin FC, Wang CC, Wang DM, J. Membr. Sci., 118(1), 49 (1996)
Chou WL, Yu DG, Yang MC, Jou CH, Sep. Purif. Technol., 57(2), 209 (2007)
Boom RM, Wienk I, Boomgaard TVD, Smolders CA, J. Membr. Sci., 73, 277 (1992)
Saljoughi E, Mohammadi T, Desalination, 249(2), 850 (2009)
Saljoughi E, Amirilargani M, Mohammadi T, J. Appl. Polym. Sci., 111(5), 2537 (2009)
Mohammadi T, Saljoughi E, Desalination, 243(1-3), 1 (2009)
Amirilargani M, Mohammadi T, Sep. Sci. Technol., 44(16), 3854 (2009)
Young TH, Chen LW, J. Membr. Sci., 59, 169 (1991)
Hermia J, Trans. Inst. Chem. Eng., 60, 183 (1982)
Vela MCV, Blanco SA, Garcia JL, Rodriguez EB, Sep. Purif. Technol., 62(3), 489 (2008)
Kumar SM, Roy S, Sep. Sci. Technol., 43(5), 1034 (2008)
Xiaojun C, Choo KH, Environ. Eng. Res., 19, 1 (2014)
Salahi A, Gheshlaghi A, Mohammadi T, Madaeni SS, Desalination, 262(1-3), 235 (2010)
Song KH, Lee KR, Korean J. Chem. Eng., 24(1), 116 (2007)
Salahi A, Mohammadi T, Water Sci. Technol., 63, 1476 (2011)
Li Q, Snoeyink VL, Marinas BJ, Campos C, Water Res., 37, 4863 (2003)
Kim JS, Cai ZX, Benjamin MM, J. Membr. Sci., 310(1-2), 356 (2008)
Madaeni SS, Rahimi M, Abolhasani M, Korean J. Chem. Eng., 27(1), 206 (2010)
Tomaszewska M, Mozia S, Water Res., 36, 4137 (2002)
Oh H, Yu M, Takizawa S, Ohgaki S, Desalination, 192(1-3), 54 (2006)
Kweon JH, Hur HW, Seo GT, Jang TR, Park JH, Choi KY, Kim HS, Desalination, 249(1), 212 (2009)
Ying Z, Ping G, Sep. Purif. Technol., 52(1), 154 (2006)
Matsuim Y, Yuasam A, Ariga K, Water Res., 35, 455 (2001)
Harrelkas F, Azizi A, Yaacoubi A, Benhammou A, Pons MN, Desalination, 235(1-3), 330 (2009)
Suzuki T, Watanabe Y, Ozawa G, Ikeda S, Desalination, 117, 119 (1998)
Shi Q, Su YL, Zhu SP, Li C, Zhao YY, Jiang ZY, J. Membr. Sci., 303(1-2), 204 (2007)
Liu ZM, Xu ZK, Wan LS, Wu J, Ulbricht M, J. Membr. Sci., 249(1-2), 21 (2005)
Ghaffarian V, Mousavi SM, Bahreini M, Jalaei H, J. Ind. Eng. Chem., 20(4), 1359 (2014)
Frommer MA, Messalem RM, Ind. Eng. Chem. Prod. Res. Dev., 12, 328 (1973)
Peng N, Widjojo N, Sukitpaneenit P, Teoh MM, Lipscomb GG, Chung TS, Lai JY, Prog. Polym. Sci, 37, 1401 (2012)
Vogrin N, Stropnik C, Musil V, Brumen M, J. Membr. Sci., 207(1), 139 (2002)
Strathmann H, Kock K, Desalination, 21, 241 (1977)
Kim IC, Lee KH, J. Appl. Polym. Sci., 89(9), 2562 (2003)
Zheng QZ, Wang P, Yang YN, J. Membr. Sci., 279(1-2), 230 (2006)
An TH, Chyu RR, Ming WD, Yih LJ, J. Appl. Polym. Sci., 86, 166 (2002)
Lai JY, Lin FC, Wang CC, Wang DM, J. Membr. Sci., 118(1), 49 (1996)
Kim HJ, Tyagi RK, Fouda AE, Jonasson K, J. Appl. Polym. Sci., 62(4), 621 (1996)
Niu HY, Lang WZ, Liu YX, Guo YJ, Fiber Polym., 14, 1587 (2013)
Chakrabarty B, Ghoshal AK, Purkait AK, J. Membr. Sci., 315(1-2), 36 (2008)
Zhu LP, Xu L, Zhu BK, Feng YX, Xu YY, J. Membr. Sci., 294(1-2), 196 (2007)
Amirilargani M, Mohammadi T, Polym. Adv. Technol., 20, 993 (2009)
Wienk IM, Boom RM, Beerlage MA, Bulte AM, Smolders CA, Strathmann H, J. Membr. Sci., 113(2), 361 (1996)
Idris A, Ismail AF, Noordin MY, Shilton SJ, J. Membr. Sci., 205(1-2), 223 (2002)
Mosqueda-Jimenez DB, Narbaitz RM, Matsuura T, Chowdhury G, Pleizier G, Santerre JP, J. Membr. Sci., 231(1-2), 209 (2004)
Kim IC, Lee KH, J. Membr. Sci., 230(1-2), 183 (2004)
Saljoughi E, Sadrzadeh M, Mohammadi T, J. Membr. Sci., 326(2), 627 (2009)
Amirilargani M, Sadrzadeh M, Mohammadi T, J. Polym. Res., 17, 363 (2010)
Salahi A, Mohammadi T, Nikbakht M, Golshenasa M, Noshadi I, Desal. Wat. Treat., 48, 27 (2012)
Salahi A, Abbasi M, Mohammadi T, Desalination, 251(1-3), 153 (2010)
Abadi SRH, Sebzari MR, Hemati M, Rekabdar F, Mohammadi T, Desalination, 265(1-3), 222 (2011)
APHA-American Public Health Association/American Water Works Association/Water Environment Federation, Standard Methods for the Examination of Water and Wastewater, 2001, 20th Ed., Washington, DC, USA (2001). (2001)
Laninovic V, Desalination, 186(1-3), 39 (2005)
Li JF, Xu ZL, Yang H, Feng CP, Shi JH, J. Appl. Polym. Sci., 107(6), 4100 (2008)
Amirilargani M, Saljoughi E, Mohammadi T, Moghbeli MR, Polym. Eng. Sci., 50(5), 885 (2010)
Rahimpour A, Madaeni SS, Mansourpanah Y, J. Membr. Sci., 296(1-2), 110 (2007)
Madaeni SS, Hoseini S, J. Polym. Res., 16, 591 (2009)
Wang DM, Lin FC, Wu TT, Lai JY, J. Membr. Sci., 142(2), 191 (1998)
Strathmann H, Kock K, Amar P, Baker RW, Desalination, 16, 179 (1975)
Amirilargani M, Saljoughi E, Mohammadi T, J. Appl. Polym. Sci., 115(1), 504 (2010)
Smolders CA, Reuvers AJ, Boom RM, Wienk IM, J. Membr. Sci., 73, 259 (1992)
Rahman NA, Sotani T, Matsuyama H, J. Appl. Polym. Sci., 108(5), 3411 (2008)
Kim JH, Lee KH, J. Membr. Sci., 138(2), 153 (1998)
Sivakumar M, Malaisamy R, Sajitha CJ, Mohan D, Mohan V, Rangarajan R, J. Membr. Sci., 169(2), 215 (2000)
Chakrabarty B, Ghoshal AK, Purkait MK, J. Membr. Sci., 309(1-2), 209 (2008)
Lai JY, Lin FC, Wang CC, Wang DM, J. Membr. Sci., 118(1), 49 (1996)
Chou WL, Yu DG, Yang MC, Jou CH, Sep. Purif. Technol., 57(2), 209 (2007)
Boom RM, Wienk I, Boomgaard TVD, Smolders CA, J. Membr. Sci., 73, 277 (1992)
Saljoughi E, Mohammadi T, Desalination, 249(2), 850 (2009)
Saljoughi E, Amirilargani M, Mohammadi T, J. Appl. Polym. Sci., 111(5), 2537 (2009)
Mohammadi T, Saljoughi E, Desalination, 243(1-3), 1 (2009)
Amirilargani M, Mohammadi T, Sep. Sci. Technol., 44(16), 3854 (2009)
Young TH, Chen LW, J. Membr. Sci., 59, 169 (1991)
Hermia J, Trans. Inst. Chem. Eng., 60, 183 (1982)
Vela MCV, Blanco SA, Garcia JL, Rodriguez EB, Sep. Purif. Technol., 62(3), 489 (2008)
Kumar SM, Roy S, Sep. Sci. Technol., 43(5), 1034 (2008)
Xiaojun C, Choo KH, Environ. Eng. Res., 19, 1 (2014)
Salahi A, Gheshlaghi A, Mohammadi T, Madaeni SS, Desalination, 262(1-3), 235 (2010)
