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Received August 20, 2014
Accepted October 20, 2014
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The role of tetragonal-metal-organic framework-5 loadings with extra ZnO molecule on the gas separation performance of mixed matrix membrane
Department of Chemical Engineering, Faculty of Engineering, Ferdowsi University of Mashhad, Mashhad, Iran 1Department of Chemical Engineering, Faculty of Engineering, Kurdistan University, Kurdistan, Iran
Mehrzad.Arjmandi89@gmail.com
Korean Journal of Chemical Engineering, June 2015, 32(6), 1178-1187(10), 10.1007/s11814-014-0315-9
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Abstract
The effect of more ZnO molecule in tetragonal structure of MOF-5 than cubic structure on the gas permeation properties of T-MOF-5/polyetherimide mixed matrix membranes was investigated. T-MOF-5 was first successfully synthesized and carefully characterized by XRD, FTIR, SEM and N2 adsorption technique at 77 K. Novel T-MOF-5/PEI MMMs were prepared using solution casting method and characterized by FTIR and SEM. The SEM pictures of the MMMs showed that T-MOF-5 nanocrystals changed the morphology of PEI and exhibited acceptable contacts between the filler particles and the polymer chains. Gas permeation properties of these membranes with different TMOF-5 contents were studied for pure H2, CO2, CH4 and N2 gases. Permeation measurement showed that the all gases’ permeability, diffusivity and solubility were increased with T-MOF-5 loading. H2 permeability and the ideal selectivity of H2/CO2 and H2/CH4 in MMM with 25 wt% loading of T-MOF-5 nanocrystals were increased. This behavior was attributed to more ZnO molecule in T-MOF-5 structure. The experimental gas permeations through T-MOF-5/PEI nanocomposite with different filler loadings were fitted on Higuchi model. Good agreement between the experimental data and the predicted gas permeability was obtained.
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Zhang L, Hu YH, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 176, 573 (2011)
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Brunauer S, Emmett PH, Teller E, J. Am. Chem. Soc., 60, 309 (1938)
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Kesting R, Fritzsche AK, Polymeric gas separation membranes, Wiley, New York (1993). (1993)
Higuchi WI, J. Phys. Chem., 62, 649 (1958)
