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In relation to this article, we declare that there is no conflict of interest.
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Received March 1, 2014
Accepted November 13, 2014
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Application of modified Tao-Mason equation of state to refrigerant mixtures

Department of Chemistry, Payame Noor University, P. O. Box 19395-3697, Tehran, Iran 1Department of Chemistry, Shiraz University of Technology, Shiraz 71555-313, Iran 2Department of Chemistry, Shiraz University, Shiraz, Iran, Korea
Korean Journal of Chemical Engineering, July 2015, 32(7), 1361-1368(8), 10.1007/s11814-014-0332-8
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Abstract

In our previous work, we modified the Tao-Mason EOS [1] to predict the volumetric properties of pure refrigerants [2]. In the present study, we have successfully extended the modified Tao-Mason EOS to refrigerant mixtures. The second virial coefficient, B2(T), and the temperature-dependent correction factor α(T) and van der Waals co-volume b(T) were calculated from a two-parameter corresponding-states correlation along with the enthalpy of vaporization and the molar density, both at the normal boiling point. Then the cross parameters B12(T), α12(T), and b12(T), were determined with the help of simple combining rules. The constructed Tao-Mason EOS was employed to predict the densities and vapor pressures of several HFC, hydrocarbons and HFO mixtures. The calculated results were compared with literature data. The overall agreement between our results and literature values is remarkable.

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