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Received November 27, 2013
Accepted December 26, 2014
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Double-imprinted potentiometric sensors based on ligand exchange for the determination of dimethoate
Department of Chemistry, Eskişehir Osmangazi University, Eskisehir, Turkey 1Department of Chemistry, Eskisehir Osmangazi University, Eskisehir, Turkey
ebirlik@ogu.edu.tr
Korean Journal of Chemical Engineering, August 2015, 32(8), 1613-1617(5), 10.1007/s11814-014-0386-7
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Abstract
This paper describes a dimethoate imprinted polymeric potentiometric sensor for the determination of dimethoate that was designed by dispersing the dimethoate-imprinted polymer in dibutyl phthalate plasticizer and then embedded in polyvinyl chloride matrix. The method is based on molecularly imprinted polymer (MIP), which can be synthesized by using dimethoate as a template molecule, chitosan-Cd(II), and 3-mercaptopropyl-trimethoxysilane as a functional monomer and TEOS, and ephychlorohydrin as a cross-linking agent. We have studied a method for the selective binding behavior of dimethoate compounds on the surface of imprinted polymers which is prepared using ligand-exchange (LE) (chitosan-Cd(II)) monomer. The MIP-LE-1 and MIP-LE-2 based membranes have shown a detection limit of 4.3×10.6mmolL.1 and 3.5.10.5 mmolL.1, respectively. The sensor has exhibited a response time of 35min for MIP-LE-1 and 120min for MIP-LE-2. They are stable for more than three months.
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Prathish KP, Prasad K, Rao TP, Suryanarayana MVS, Acid Talanta, 71, 1976 (2007)
D’Agostino G, Alberti G, Biesuz R, Pesavento M, Biosens. Bioelectron., 22, 145 (2006)
Zhou Y, Yu B, Levon K, Acid. Biosens. Bioelectron., 20, 1851 (2005)
Zhou Z, Yu B, Levon K, Chem. Mater., 15, 2774 (2003)
Lahav M, Kharitonov AB, Katz O, Kunitake T, Willner I, Anal. Chem., 73, 720 (2001)
Pogorelova SP, Bourenko T, Kharitonov AB, Willner I, The Analyst, 127, 1484 (2002)
Javanbakht M, Eynollahi S, Abdouss M, Ganjali MR, Norouzi CP, Safaraliee L, Electroanalysis, 20, 2023 (2008)
Erdem M, Say R, Ersoz A, Denizli A, Turk H, Appl. Clay Sci., 47, 223 (2010)
Odabasi M, Say R, Denizli A, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 27, 90 (2007)
Umezawa Y, Umezawa K, Sato H, Pure Appl. Chem., 67, 507 (1995)
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Khaleda E, Hassana HNA, Mohamed GG, Ragabc FA, Eldin AA, Talanta, 83, 357 (2010)
Mulchandani P, Mulchandani A, Kaneva I, Chen W, Biosens. Bioelectron., 14, 77 (1999)
