Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received September 13, 2014
Accepted November 28, 2014
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Adsorption of malachite green in aqueous solution onto sodium carbonate treated rice husk
Department of Civil Engineering, National Institute of Technology, Silchar, Assam, India
upendra_kumar72@rediffmail.com
Korean Journal of Chemical Engineering, August 2015, 32(8), 1655-1666(12), 10.1007/s11814-014-0351-5
Download PDF
Abstract
The feasibility of using rice husk for removing malachite green (MG) from aqueous solutions has been investigated as a low cost and an eco-friendly adsorbent. The effect of chemical treatment of rice husk by sodium carbonate was investigated through SEM and FTIR. As well, the effect of various factors like rotational speed, pH value of solution, temperature, initial concentration of dye, dose of adsorbent, contact time on the adsorption of MG was examined in batch experiments. Adsorption isotherms, kinetics, mass transfer and rate limiting steps are studied in detail. Adsorption thermodynamic parameters, activation energy and isosteric heat of adsorption were also studied. The adsorption was a spontaneous, endothermic and followed the pseudo-second-order kinetic model. The mechanism of adsorption and the COD aspect in deciding the effectiveness of the biomaterial as an adsorbent for dyes has also to be taken into account.
References
Yang XQ, Zhao XX, Liu CY, Zheng Y, Qian SJ, Process Biochem., 44(10), 1185 (2009)
Kumar PS, Ramalingam S, Senthamarai C, Niranjanaa M, Vijayalakshmi P, Sivanesan S, Desalination, 261(1-2), 52 (2010)
Ahmad R, Kumar R, J. Environ. Manage., 91(4), 1032 (2010)
Ghoreishi SM, Haghighi R, Chem. Eng. J., 95(1-3), 163 (2003)
Rosa D, Kenny IM, Pugkia JM, Santulli DC, Sarasini F, Compos. Sci. Technol., 70, 116 (2010)
Derbyshire F, Jagtoyen M, Andrews R, Rao A, Martin-Gullon I, Grulke E, In Chemistry and Physics of Carbon, Radovic LR, (Ed.), 27, Marcel Dekker, New York, 1 (2001).
Babel S, Kurniawan TA, J. Hazard. Mater., 97(1-3), 219 (2003)
Naiya TK, Bhattacharya AK, Das SK, Environ. Prog., DOI:10.1002/ep.10280 (2009)
Ngah WSW, Hanafiah MAKM, Bioresour. Technol., 99(10), 3935 (2008)
Xin H, Nai-yun G, Qiao-li Z, J. Environ. Sci., 19, 1287 (2007)
Laszlo JA, Dintzis FR, J. Appl. Polym. Sci., 52(4), 531 (1994)
Luduena L, Fasce D, Alvare VA, Stefani PM, Bio Resources, 6(2), 1440 (2011)
Linh L, Eldemerdash U, Mansor N, Uemura Y, Furuya E, Int. J. Biomass Renewables, 1(2), 32 (2012)
Sonawane GH, Shrivastava VS, Desalination, 247, 1430 (2009)
Ghaedi M, Hossainian H, Montazerozohori M, Shokrollahi A, Shojaipour F, Soylak M, Purkait MK, Desalination, 281, 226 (2011)
Daneshvar N, Ayazloo M, Khataee AR, Pourhassan M, Bioresour. Technol., 98(6), 1176 (2007)
Ciobanu G, Harja M, Rusu L, Mocanu AM, Luca C, Korean J. Chem. Eng., 31(6), 1021 (2014)
Han X, Niu X, Ma X, Korean J. Chem. Eng., 29(4), 494 (2012)
Tsai WT, Chen HR, J. Hazard. Mater., 175(1-3), 844 (2010)
Anirudhan TS, Radhakrishnan PG, J. Chem. Thermodyn., 40(4), 702 (2008)
Oxford Dictionary of Chemistry, Daintith J Ed., Oxford University Press (2008).
Chowdhury S, Mishra R, Saha P, Kushwaha P, Desalination, 265(1-3), 159 (2011)
Subbareddy Y, Jeseentharani V, Jayakumar C, Nagaraja KS, Jeyaraj B, J. Environ. Res. Dev., 7, 1A (2012)
Oepen V, Kordel W, Klein W, Chemosphere, 22, 285 (1991)
Dominguez G, Hernandez-Huesca R, Aguilar-Armenta G, J. Mex. Chem. Soc., 54(2), 1161 (2010)
Lyubchik SI, Lyubchik AI, Galushko OL, Colloids Surf. A: Physicochem. Eng. Asp., 242(1-3), 151 (2004)
Kumar PS, Ramalingam S, Senthamarai C, Niranjanaa M, Vijayalakshmi P, Sivanesan S, Desalination, 261(1-2), 52 (2010)
Ahmad R, Kumar R, J. Environ. Manage., 91(4), 1032 (2010)
Ghoreishi SM, Haghighi R, Chem. Eng. J., 95(1-3), 163 (2003)
Rosa D, Kenny IM, Pugkia JM, Santulli DC, Sarasini F, Compos. Sci. Technol., 70, 116 (2010)
Derbyshire F, Jagtoyen M, Andrews R, Rao A, Martin-Gullon I, Grulke E, In Chemistry and Physics of Carbon, Radovic LR, (Ed.), 27, Marcel Dekker, New York, 1 (2001).
Babel S, Kurniawan TA, J. Hazard. Mater., 97(1-3), 219 (2003)
Naiya TK, Bhattacharya AK, Das SK, Environ. Prog., DOI:10.1002/ep.10280 (2009)
Ngah WSW, Hanafiah MAKM, Bioresour. Technol., 99(10), 3935 (2008)
Xin H, Nai-yun G, Qiao-li Z, J. Environ. Sci., 19, 1287 (2007)
Laszlo JA, Dintzis FR, J. Appl. Polym. Sci., 52(4), 531 (1994)
Luduena L, Fasce D, Alvare VA, Stefani PM, Bio Resources, 6(2), 1440 (2011)
Linh L, Eldemerdash U, Mansor N, Uemura Y, Furuya E, Int. J. Biomass Renewables, 1(2), 32 (2012)
Sonawane GH, Shrivastava VS, Desalination, 247, 1430 (2009)
Ghaedi M, Hossainian H, Montazerozohori M, Shokrollahi A, Shojaipour F, Soylak M, Purkait MK, Desalination, 281, 226 (2011)
Daneshvar N, Ayazloo M, Khataee AR, Pourhassan M, Bioresour. Technol., 98(6), 1176 (2007)
Ciobanu G, Harja M, Rusu L, Mocanu AM, Luca C, Korean J. Chem. Eng., 31(6), 1021 (2014)
Han X, Niu X, Ma X, Korean J. Chem. Eng., 29(4), 494 (2012)
Tsai WT, Chen HR, J. Hazard. Mater., 175(1-3), 844 (2010)
Anirudhan TS, Radhakrishnan PG, J. Chem. Thermodyn., 40(4), 702 (2008)
Oxford Dictionary of Chemistry, Daintith J Ed., Oxford University Press (2008).
Chowdhury S, Mishra R, Saha P, Kushwaha P, Desalination, 265(1-3), 159 (2011)
Subbareddy Y, Jeseentharani V, Jayakumar C, Nagaraja KS, Jeyaraj B, J. Environ. Res. Dev., 7, 1A (2012)
Oepen V, Kordel W, Klein W, Chemosphere, 22, 285 (1991)
Dominguez G, Hernandez-Huesca R, Aguilar-Armenta G, J. Mex. Chem. Soc., 54(2), 1161 (2010)
Lyubchik SI, Lyubchik AI, Galushko OL, Colloids Surf. A: Physicochem. Eng. Asp., 242(1-3), 151 (2004)
