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Received September 24, 2014
Accepted November 28, 2014
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Abatement of Cr(VI) and As(III) by MnO2 loaded MCM-41 in wastewater treatment
*Key Laboratory of Integrated Regulation and Resources Development of Shallow Lakes, Ministry of Education, Hohai University, Xikang Road #1, Nanjing 210098, China 1College of Environment, Hohai University, Xikang Road #1, Nanjing 210098, China 2Department of Chemistry, Hanshan Normal University, Chaozhou, Guangdong Province, China
Korean Journal of Chemical Engineering, August 2015, 32(8), 1667-1677(11), 10.1007/s11814-014-0352-4
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Abstract
Manganese dioxide (MnO2) loaded MCM-41 (MnO2/MCM-41) was used as adsorbent to remove Cr(VI) and As(III) from aqueous solution. The adsorbent was synthesized and characterized. Effect of pH on the removal of Cr(VI) and As(III) was investigated. The desired pH of aqueous solution was 2 for the removal of Cr(VI) and 4 for the removal of As(III). Besides, the adsorption of As(III) and Cr(VI) can be well described by Langmuir and Freundlich isotherm models, respectively. The kinetic data can be successfully depicted by pseudo-second-order model. Moreover, external and intra-particle diffusion were found to be rate-controlling steps of the adsorption process. Thermodynamic analysis suggested that the adsorption process was spontaneous and endothermic. In a binary system, the presence of Cr(VI) and As(III) slightly reduced the removal efficiency of each other. The desorption study showed 0.1mol/L NaOH liquor held good desorption ability for metal loaded MnO2/MCM-41.
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Ho YS, McKay G, Process Saf. Environ. Protect., 76(2), 183 (1998)
Chen JP, Wu S, Chong KH, Carbon, 41, 1979 (2003)
Behdani FN, Rafsanjani AT, Torab-Mostaedi M, Mohammadpour SMAK, Korean J. Chem. Eng., 30(2), 448 (2013)
Wang H, Yan N, Li Y, Zhou X, Chen J, Yu B, Gong M, Chen Q, J. Mater. Chem., 22, 9230 (2012)
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Sheng PX, Ting YP, Chen JP, Ind. Eng. Chem. Res., 46(8), 2438 (2007)
Roy A, Bhattacharya J, Sep. Purif. Technol., 115, 172 (2013)
