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Received February 26, 2015
Accepted June 26, 2015
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Fe-aminoclay-entrapping electrospun polyacrylonitrile nanofibers (FeAC-PAN NFs) for environmental engineering applications
Jae-Young Lee
Saehae Choi1
Dongsu Song2
Seung Bin Park2
Moon Il Kim3
Go-Woon Lee4
Hyun Uk Lee5†
Young-Chul Lee3†
Korea Railroad Research Institute (KRRI), Railroad Museum Road #176, Uiwang-si, Gyeonggi-do 437-757, Korea 1Sustainable Bioresource Research Center, Korea Research Institute of Bioscience & Biotechnology (KRIBB), Daejeon 305-806, Korea 2Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), 291, Daehak-ro, Yuseong-gu, Daejeon 305-701, Korea 3Department of BioNano Technology, Gachon University, 1342, Seongnamdaero, Sujeong-gu, Seongnam-si, Gyeonggi-do 461-701, Korea 4Quality Management Team, Korea Institute of Energy Research (KIER), 152, Gajeong-ro, Yuseong-gu, Daejeon 305-343, Korea 5Advanced Nano-Surface Research Group, Korea Basic Science Institute (KBSI), Daejeon 305-806, Korea
leeho@kbsi.re.kr
Korean Journal of Chemical Engineering, September 2015, 32(9), 1727-1732(6), 10.1007/s11814-015-0136-5
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Abstract
Electrospun polyacrylonitrile nanofibers (PAN NFs) with entrapped water-soluble Fe-aminoclay (FeAC) [FeAC-PAN NFs] were prepared. Slow dropwise addition of water-soluble FeAC into a PAN solution, less aggregated of FeAC into electrospun PAN NFs was one-pot evolved without FeAC post-decoration onto as-prepared PAN NFs. Taking into consideration both the Fe3+ source in FeAC and the improved surface hydrophilicity, the feasibility of Fentonlike reaction for decolorization of cationic model dye methylene blue (MB) under 6 hrs UV-light irradiation was established. In the case where FeAC-PAN NFs were enhanced by hydrogen peroxide (H2O2) injection, the apparent kinetic reaction rates were increased relative to those for the PAN NFs. Thus, our flexible FeAC-PAN NF mats can be effectively utilized in water/waste treatment and other environmental engineering applications.
Keywords
References
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Vu D, Li ZY, Zhang HN, Wang W, Wang ZJ, Xu XR, Dong B, Wang C, J. Colloid Interface Sci., 367, 429 (2012)
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Zhan S, Zhu D, Ren G, Shen Z, Qiu M, Yang S, Yu H, Li Y, ACS Appl. Mater. Interfaces, 6, 16841 (2014)
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Zhang CL, Yu SH, Chem. Soc. Rev., 43, 4423 (2014)
Ryu WH, Shin JW, Jung JW, Kim ID, J. Mater. Chem., 1, 3239 (2013)
Shin JW, Ryu WH, Park SK, Kim ID, ACS Nano, 7, 7330 (2013)
Park HS, Choi BG, Hong WH, Jang SY, J. Colloid Interface Sci., 406, 24 (2013)
Mann S, Burkett SL, Davis SA, Fowler CE, Mendelson NH, Sims SD, Walsh D, Whilton NT, Chem. Mater., 9, 2300 (1997)
Lee YC, Kim EJ, Ko DA, Yang JW, J. Hazard. Mater., 196, 101 (2011)
Lee YC, Jin ES, Jung SW, Kim YM, Chang KS, Yang JW, Kim SW, Kim YO, Shin HJ, Sci. Rep., 3, 1292 (2013)
Lee YC, Park WK, Yang JW, J. Hazard. Mater., 190(1-3), 652 (2011)
Ruiz-Hitzky E, Aranda P, Darder M, Rytwo G, J. Mater. Chem., 20, 9306 (2010)
Lee YC, Lee HU, Lee M, Kim J, Huh YS, J. Nanosci. Nanotechnol., DOI:10.1166/jnn.2015.11911 (2015)
Persano L, Camposeo A, Teckmen C, Pisignano D, Macromol. Mater. Eng., 298, 504 (2013)
Lee HU, Kang YH, Jeong SY, Koh K, Kim JP, Bae JS, Cho CR, Polym. Degrad. Stabil., 96, 1204 (2011)
Lee YC, Chang SJ, Choi MH, Jeon TJ, Ryu T, Huh YS, Appl. Catal. B: Environ., 142-143, 494 (2013)
Owens DK, Wendt RC, J. Appl. Polym. Sci., 13, 1741 (1969)
Lee HU, Jeong YS, Jeong SY, Park SY, Bae JS, Kim HG, Cho CR, Appl. Surf. Sci., 254(18), 5700 (2008)
Zubir NA, Yacou C, Motuzas J, Zhang X, Costa JCDD, Sci. Rep., 4, 4594 (2014)
Kalal S, Chauhan NPS, Ameta N, Ameta R, Kumar S, Punjabi PB, Korean J. Chem. Eng., 31(12), 2183 (2014)
