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Received September 6, 2014
Accepted December 31, 2014
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Preparation and electrochemical characterization of polyvinylchloride/FeTiO3-co-Fe3O4 nanoparticles mixed matrixion exchange membranes: Investigation of concentration and pH effects
Department of Chemical Engineering, Faculty of Engineering, Arak University, Arak 38156-8-8349, Iran 1Membrane Research Centre, Department of Chemical Engineering, Faculty of Engineering, Razi University, Kermanshah 67149, Iran
Korean Journal of Chemical Engineering, September 2015, 32(9), 1827-1834(8), 10.1007/s11814-015-0002-5
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Abstract
Polyvinyl chloride based/FeTiO3-co-Fe3O4 nanoparticles mixed matrix heterogeneous cation exchange membranes were prepared by solution casting technique. The effect of using filler additives in casting solution and also electrolyte concentration and pH on electrochemical properties of membrane was studied. Membrane potential, transport number and selectivity were improved by using FeTiO3/Fe3O4 nanoparticles in membrane matrix. Utilizing FeTiO3/_x000D_
Fe3O4 nanoparticles in membrane matrix also led to improvement of membrane ionic flux from 2.95*10.5 to 4.15*10.5 (mol/m2·s) obviously. Similar trend was also found for membrane electrical conductivity. Moreover, the transport number, selectivity and membrane electrical conductivity were enhanced by increase of electrolyte concentration. Prepared membranes exhibited higher transport number/selectivity at pH 7 compared to other pH values. Obtained results showed_x000D_
that the membrane electrical resistance decreased initially by increase of electrolyte pH sharply and then began to increase. Membranes exhibited lower selectivity for bivalent ions compared to monovalent type. Modified membranes containing FeTiO3/Fe3O4 nanoparticles showed more appropriate electrochemical properties compared to other prepared membranes.
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References
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Gohil GS, Binsu VV, Shahi VK, J. Membr. Sci., 280(1-2), 210 (2006)
Nagarale RK, Gohil GS, Shahi VK, Adv. Colloid Interface Sci., 119, 97 (2006)
Kariduraganavar MY, Nagarale RK, Kittur AA, Kulkarni SS, Desalination, 197(1-3), 225 (2006)
Zarrinkhameh M, Zendehnam A, Hosseini SM, Korean J. Chem. Eng., 31(7), 1187 (2014)
Shahi VK, Thampy SK, Rangarajan R, J. Membr. Sci., 158(1-2), 77 (1999)
Vyas PV, Ray P, Adhikary SK, Shah BG, Rangarajan R, J. Colloid Interface Sci., 257(1), 127 (2003)
Nagarale RK, Shahi VK, Schubert R, Rangarajan R, Mehnert R, J. Colloid Interface Sci., 270(2), 446 (2004)
Volodina E, Pismenskaya N, Nikonenko V, Larchet C, Pourcelly G, J. Colloid Interface Sci., 285(1), 247 (2005)
M'Bareck CO, Nguyen QT, Alexandre S, Zimmerlin I, J. Membr. Sci., 278(1-2), 10 (2006)
Hwang GJ, Ohya H, Nagai T, J. Membr. Sci., 156(1), 61 (1999)
Xu TW, J. Membr. Sci., 263(1-2), 1 (2005)
Elattar A, Elmidaoui A, Pismenskaia N, Gavach C, Pourcelly G, J. Membr. Sci., 143(1-2), 249 (1998)
Schauer J, Brozova L, J. Membr. Sci., 250(1-2), 151 (2005)
Koter S, Warszawski A, Pol. J. Environ. Stud., 9(1), 45 (2000)
Baker RW, Membrane Technology and Applications, 2nd Ed. England, John Wiley & Sons Ltd. (2004).
Gohil GS, Shahi VK, Rangarajan R, J. Membr. Sci., 240(1-2), 211 (2004)
Shahi VK, Trivedi GS, Thampy SK, Rangarajan R, J. Colloid Interface Sci., 262(2), 566 (2003)
Dlugolecki P, Anet B, Metz SJ, Nijmeijer K, Wessling M, J. Membr. Sci., 346(1), 163 (2010)
Kerres J, Cui W, Disson R, Neubrand W, J. Membr. Sci., 139(2), 211 (1998)
Li XF, Wang Z, Lu H, Zhao CJ, Na H, Zhao C, J. Membr. Sci., 254(1-2), 147 (2005)
Hosseini SM, Madaeni SS, Heidari AR, Amirimehr A, Desalination, 284, 191 (2012)
Balster J, Krupenko O, Punt I, Stamatialis DF, Wessling M, J. Membr. Sci., 263(1-2), 137 (2005)
Sata T, Ion Exchange Membranes: Preparation, Characterization, Modification and Application. Cambridge/United Kingdom: The Royal Society of Chemistry (2004).
Hosseini SM, Madaeni SS, Zendehnam A, Moghadassi AR, Khodabakhshi AR, Sanaeepur H, J. Ind. Eng. Chem., 19(3), 854 (2013)
Nagarale RK, Gohil GS, Shahi VK, Rangarajan R, Colloids Surf. A: Physicochem. Eng. Asp., 251, 133 (2004)
Daraei P, Madaeni SS, Ghaemi N, Salehi E, Khadivi M, Moradian R, Astinchap B, J. Membr. Sci., 415-416, 250 (2012)
S. Wiks E. Industrial Polymers Handbook: Products, Processes, Application, WILEY-VCH Press, Germany (2001).
E MARK J. Polymer Data Handbook, Oxford University Press Inc., New York (1999).
Harper CA, Handbook of plastic and elastomers, New York: McGraw-Hill (1975).
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Fujii T, Yamashita M, Fujimori S, Saitoh Y, Nakamura T, Kobayashi K, Takada J, J. Magn. Magn. Mater., 310, e555 (2007)
Nagarale RK, Shahi VK, Thampy SK, Rangarajan R, React. Funct. Polym., 61(1), 131 (2004)
Tanaka Y, Ion Exchange Membranes: Fundamentals and Applications, Membrane Science and Technology Series Elsevier, Netherlands (2007).
Nagarale RK, Shahi VK, Rangarajan R, J. Membr. Sci., 248(1-2), 37 (2005)
Lide DR, CRC Handbook of Chemistry and Physics, 87th Ed. CRC Press, Boca Raton (2006).
Kang MS, Choi YJ, Choi IJ, Yoon TH, Moon SH, J. Membr. Sci., 216(1-2), 39 (2003)
Powell CE, Qiao GG, J. Membr. Sci., 279(1-2), 1 (2006)
Dlugolecki P, Nymeijer K, Metz S, Wessling M, J. Membr. Sci., 319(1-2), 214 (2008)
