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Received January 12, 2015
Accepted June 4, 2015
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Copyright © KIChE. All rights reserved.
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Flame retardant coated polyolefin separators for the safety of lithium ion batteries
School of Environmental Science and Engineering, Gwangju Institute of Science and Technology (GIST), 123, Cheomdan-gwagiro (Oryong-dong), Buk-gu, Gwangju 500-712, Korea
shmoon@gist.ac.kr
Korean Journal of Chemical Engineering, January 2016, 33(1), 285-289(5), 10.1007/s11814-015-0119-6
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Abstract
A thermally stable and flame-retardant separator is proposed to improve the safety of lithium ion batteries. The separator is prepared by dip-coating both sides of a conventional tri-layer polyolefin separator with brominated poly(2,6-dimethyl-1,4-phenylene oxide) (BPPO). Significantly reduced thermal shrinkage and flammability are exhibited without decreases in the pore size or porosity of the conventional separator. By using the BPPO-coated separator, an electrochemical half-cell composed of a lithium metal anode and a LiCoO2 cathode are successively tested. The resulting stable cycle performances are demonstrated. It is expected that the BPPO-coated separator can be a capable candidate as a separator for the safe of lithium ion batteries.
References
Cheng Q, Cui ZY, Li JB, Qin SH, Yan F, Li JX, J. Power Sources, 266, 401 (2014)
Choo S, Kim HY, Yoon DY, Choi W, Oh SH, Ju JB, Ko JM, Jang H, Cho WI, Korean J. Chem. Eng., 31(5), 905 (2014)
Wang QS, Ping P, Zhao XJ, Chu GQ, Sun JH, Chen CH, J. Power Sources, 208, 210 (2012)
Rao ZH, Wang SF, Wu MC, Lin ZR, Li FH, Energy Conv. Manag., 65, 92 (2013)
Greco A, Cao DP, Jiang X, Yang H, J. Power Sources, 257, 344 (2014)
Choi JA, Kim SH, Kim DW, J. Power Sources, 195(18), 6192 (2010)
Shi JL, Xia YG, Han SJ, Fang LF, Pan MZ, Xu XX, Liu ZP, J. Power Sources, 273, 389 (2015)
Gwon SJ, Choi JH, Sohn JY, Ihm YE, Nho YC, Nucl. Instrum. Methods Phys. Res. Sect. B-Beam Interact. Mater. Atoms, 267, 3309 (2009)
Woo JJ, Nam SH, Seo SJ, Yun SH, Kim WB, Xu T, Moon SH, Electrochem. Commun., 35, 68 (2013)
Nadjia L, Abdelkader E, Ulrich M, Bekka A, J. Photochem. Photobiol. A-Chem., 275, 96 (2014)
Gunduz G, Kisakurek D, Kayadan S, Polym. Degrad. Stabil., 64, 501 (1999)
Thasan R, Kumarasamy K, Korean J. Chem. Eng., 31(3), 365 (2014)
Lee T, Kim WK, Lee Y, Ryou MH, Lee YM, Macromol. Res., 22(11), 1190 (2014)
Saleem J, Bazargan A, Barford J, McKay G, Polym. Adv. Technol., 25, 1181 (2014)
Park JH, Park W, Kim JH, Ryoo D, Kim HS, Jeong YU, Kim DW, Lee SY, J. Power Sources, 196(16), 7035 (2011)
Jeong HS, Lee SY, J. Power Sources, 196(16), 6716 (2011)
Jeong HS, Hong SC, Lee SY, J. Membr. Sci., 364(1-2), 177 (2010)
Sazhin SV, Harrup MK, Gering KL, J. Power Sources, 196(7), 3433 (2011)
Torabi A, Etsell TH, Sarkar P, Solid State Ion., 192(1), 372 (2011)
Jittavanich K, Clemons CB, Kreider KL, Aljarrah M, Evans E, Young GW, Chem. Eng. Sci., 65(23), 6169 (2010)
Kritzer P, J. Power Sources, 161(2), 1335 (2006)
Angulakshmi N, Stephan AM, Electrochim. Acta, 127, 167 (2014)
Wu D, Fu RQ, Xu TW, Wu L, Yang WH, J. Membr. Sci., 310(1-2), 522 (2008)
Choo S, Kim HY, Yoon DY, Choi W, Oh SH, Ju JB, Ko JM, Jang H, Cho WI, Korean J. Chem. Eng., 31(5), 905 (2014)
Wang QS, Ping P, Zhao XJ, Chu GQ, Sun JH, Chen CH, J. Power Sources, 208, 210 (2012)
Rao ZH, Wang SF, Wu MC, Lin ZR, Li FH, Energy Conv. Manag., 65, 92 (2013)
Greco A, Cao DP, Jiang X, Yang H, J. Power Sources, 257, 344 (2014)
Choi JA, Kim SH, Kim DW, J. Power Sources, 195(18), 6192 (2010)
Shi JL, Xia YG, Han SJ, Fang LF, Pan MZ, Xu XX, Liu ZP, J. Power Sources, 273, 389 (2015)
Gwon SJ, Choi JH, Sohn JY, Ihm YE, Nho YC, Nucl. Instrum. Methods Phys. Res. Sect. B-Beam Interact. Mater. Atoms, 267, 3309 (2009)
Woo JJ, Nam SH, Seo SJ, Yun SH, Kim WB, Xu T, Moon SH, Electrochem. Commun., 35, 68 (2013)
Nadjia L, Abdelkader E, Ulrich M, Bekka A, J. Photochem. Photobiol. A-Chem., 275, 96 (2014)
Gunduz G, Kisakurek D, Kayadan S, Polym. Degrad. Stabil., 64, 501 (1999)
Thasan R, Kumarasamy K, Korean J. Chem. Eng., 31(3), 365 (2014)
Lee T, Kim WK, Lee Y, Ryou MH, Lee YM, Macromol. Res., 22(11), 1190 (2014)
Saleem J, Bazargan A, Barford J, McKay G, Polym. Adv. Technol., 25, 1181 (2014)
Park JH, Park W, Kim JH, Ryoo D, Kim HS, Jeong YU, Kim DW, Lee SY, J. Power Sources, 196(16), 7035 (2011)
Jeong HS, Lee SY, J. Power Sources, 196(16), 6716 (2011)
Jeong HS, Hong SC, Lee SY, J. Membr. Sci., 364(1-2), 177 (2010)
Sazhin SV, Harrup MK, Gering KL, J. Power Sources, 196(7), 3433 (2011)
Torabi A, Etsell TH, Sarkar P, Solid State Ion., 192(1), 372 (2011)
Jittavanich K, Clemons CB, Kreider KL, Aljarrah M, Evans E, Young GW, Chem. Eng. Sci., 65(23), 6169 (2010)
Kritzer P, J. Power Sources, 161(2), 1335 (2006)
Angulakshmi N, Stephan AM, Electrochim. Acta, 127, 167 (2014)
Wu D, Fu RQ, Xu TW, Wu L, Yang WH, J. Membr. Sci., 310(1-2), 522 (2008)
